Chromatography and the hundred year mystery of inorganic ions at aqueous interfaces: First evidence of the presence of a kosmotrope at the graphite/electrolyte solution interface

Journal of Physical Chemistry C

Volumn 117, Issue 37, 2013, Pages 19002-19009

  Cecchi, Teresa ^a,b  

^a Accademia delle Scienze   (Italy)

^b ITIS Montani   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION EQUILIBRIUM CONSTANTS; ELECTROLYTE SOLUTIONS; ENTROPY OF ADSORPTION; EXPERIMENTAL EVIDENCE; HYDROPHOBIC SURFACES; POROUS GRAPHITIC CARBON; THEORETICAL SPECULATION; THERMODYNAMIC QUANTITIES;

ADSORPTION ISOTHERMS; CARBON; CHROMATOGRAPHY; COMPUTER SIMULATION; EQUILIBRIUM CONSTANTS; POROUS MATERIALS; SURFACE CHEMISTRY;

ADSORPTION;

EID: 84884547662     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp405702r     Document Type: Article

References (39)

1. Adamson, A. W.; Gast, A. P. Physical Chemistry of Surfaces; Wiley: New York, 1997; Ch. III.
2. Onsager, L.; Samaras, N. N. T. The Surface Tension of Debye-Hückel Electrolytes J. Chem. Phys. 1934, 2, 528-536
3. Netz, R. R.; Horinek, D. Progress in Modeling of Ion Effects at the Vapor/Water Interface Annu. Rev. Phys. Chem. 2012, 63, 401-418
4. Petersen, P. B.; Saykally, R. J. Adsorption of Ions to the Surface of Dilute Electrolyte Solutions: The Jones-Ray Effect Revisited J. Am. Chem. Soc. 2005, 127, 15446-15452
5. Wang, R.; Wang, Z.-G. Effects of Ion Solvation on Phase Equilibrium and Interfacial Tension of Liquid Mixtures. J. Chem. Phys. 2011, 135, 014707 (11 pages).
6. Jungwirth, P.; Tobias, D. J. Specific Ion Effects at the Air/water Interface Chem. Rev. 2006, 106, 1259-1281
7. Chang, T.-M.; Dang, L. X. Recent Advances in Molecular Simulations of Ion Solvation at Liquid Interfaces Chem. Rev. 2006, 106, 1305-1322
8. Mundy, C. J.; Kuo, I.-F. First-Principles Approaches to the Structure and Reactivity of Atmospherically Relevant Aqueous Interfaces Chem. Rev. 2006, 106, 1282-1304
9. Boström, M.; Williams, D. R. M.; Ninham, B. W. Surface Tension of Electrolytes: Specific Ion Effects Explained by Dispersion Forces Langmuir 2001, 17, 4475-4478
10. Dos Santos, A. P.; Levin, Y. Surface and Interfacial Tensions of Hofmeister Electrolytes Faraday Discuss. 2013, 160, 75-87
11. Horinek, D.; Herz, A.; Vrbka, L.; Sedlmeier, F.; Mamatkulov, S. I.; Netz, R. R. Specific Ion Adsorption at the Air/Water interface: The Role of Hydrophobic Solvation Chem. Phys. Lett. 2009, 479, 173-183
12. Horinek, D.; Serr, A.; Bonthuis, D. J.; Boström, M.; Kunz, W.; Netz, R. R. Molecular Hydrophobic Attraction and Ion-Specific Effects Studied by Molecular Dynamics Langmuir 2008, 24, 1271-1283
13. Cecchi, T. Ion-Pair Chromatography and Related Techniques; CRC Press: Taylor & Francis Group LLC: FL, 2010; Chs 5, 6, 16.
14. Cecchi, T. Retention Mechanism for Ion-Pair Chromatography with Chaotropic Reagents: from Ion-Pair Chromatography towards a Unified Salt Chromatography Adv. Chromatogr. 2011, 49, 1-35
15. Cecchi, T.; Passamonti, P. Retention Mechanism for Ion-Pair Chromatography with Chaotropic Reagents J. Chromatogr. A. 2009, 1216, 1789-1797
16. J. Chromatogr. A. 2009, 1216, 26 5164. (erratum)
17. TM HPLC Columns Technical Guide; Thermo Electron Corporation: Bellefonte, PA, 2004.
18. Pereira, L. Porous Graphitic Carbon as a Stationary Phase in HPLC: Theory and Applications J. Liquid Chromatogr. Relat. Technol. 2008, 31, 1687-1731
19. Mukhopadhyay, P.; Gupta, R. K. Graphite, Graphene, and their Polymer Nanocomposites; CRC Press: Taylor and Francis Group LLC: FL, 2013.
20. Vazdar, M.; Pluharǒva, E.; Mason, P. E.; Vaćha, R.; Jungwirth, P. Ions at Hydrophobic Aqueous Interfaces: Molecular Dynamics with Effective Polarization J. Phys. Chem. Lett. 2012, 3, 2087-2091
21. Guiochon, G.; Felinger, A.; Shirazi, S.; Katti, A. Fundamentals of Preparative and Nonlinear Chromatography; Elsevier: Amsterdam, 2006; Ch.3.
22. Adeel, Z.; Luthy, R. G. Sorption and Transport Kinetics of a Nonionic Surfactant through an Aquifer Sediment Environ. Sci. Technol. 1995, 29, 1032-1042
23. Otten, D. E.; Shaffer, P. R.; Geissler, P. L.; Saykally, R. J. Elucidating the Mechanism of Selective Ion Adsorption to the Liquid Water Surface Proc. Natl. Acad. Sci. U.S.A. 2012, 109, 701-705
24. Aveyard, R.; Haydon, D. A. An Introduction to the Principles of Surface Chemistry; Cambridge University Press: London, 1973; Ch.3.
25. Cecchi, T. Extended Thermodynamic Approach to Ion-Interaction Chromatography: a thorough Comparison with the Electrostatic Approach and Further Quantitative Validation J. Chromatogr. A 2002, 958, 51-58
26. Pegram, L. M.; Record, M. T., Jr. Hofmeister Salt Effects on Surface Tension Arise from Partitioning of Anions and Cations between Bulk Water and the Air-Water Interface J. Phys. Chem. B 2007, 111, 5411-5417
27. Kathmann, S. M.; Kuo, I. F. W.; Mundy, C. J.; Schenter, G. K. Understanding the Surface Potential of Water J. Phys. Chem. B 2011, 115, 4369-4377
28. Garrett, B. Ions at Air/Water Interface Science 2004, 303, 1146-1147
29. Giles, C. H.; MacEwan, T. H.; Nakhwa, S. N.; Smith, D. Studies in Adsorption. Part XI. A System of Classification of Solution Adsorption Isotherms, and its Use in Diagnosis of Adsorption Mechanisms and in Measurement of Specific Surface Areas of Solids J. Chem. Soc. 1960, 3973-3993
30. Stubblefield, C. B.; Bach, R. O. Solubility of Lithium Fluoride in Water J. Chem. Eng. Data 1972, 17, 491-492
31. Ghosal, S.; Hemminger, J.; Bluhm, H.; Mun, B.; Hebenstreit, E. L. D.; Ketteler, G.; Ogletree, D. F.; Requejo, F. G.; Salmeron, M. Electron Spectroscopy of Aqueous Solution Interfaces Reveals Surface Enhancement of Halides Science 2005, 307, 563-566
32. Jones, J.; Anouti, M.; Caillon-Caravanier, M.; Willmann, P.; Lemordant, D. Lithium Fluoride Dissolution Equilibria in Cyclic Alkylcarbonates and Water J. Mol. Liq. 2010, 153, 146-152
33. Logan, D. L. A First Course in the Finite Element Method; Cengage Learning: Stamford, USA, 2012; Ch. 14.
34. Bockris, J.O'M.; Devanathan, M. A. V.; Müller, K. On the Structure of Charged Interfaces Proc. R. Soc. 1963, A274, 55-79
35. Teschke, O.; Ceotto, G.; de Souza, E. F. Interfacial Water Dielectric-Permittivity-Profile Measurements Using Atomic Force Microscopy. Phys. Rev. 2001, E 64, 011605 (10 pages).
36. Vauge, C. On the Concept of "Image-Force J. Aerosol Sci. 2002, 33, 829-832
37. Gavryushov, S.; Linse, P. Polarization Deficiency and Excess Free Energy of Ion Hydration in Electric Fields J. Phys. Chem. B 2003, 107, 7135-7142
38. Cecchi, T.; Pucciarelli, F.; Passamonti, P. Extended Thermodynamic Approach to Ion Interaction Chromatography Anal. Chem. 2001, 73, 2632-2639
39. Weber, S. G. Theoretical and Experimental Studies of Electrostatic Effects in Reversed Phase Liquid Chromatography Talanta 1989, 36, 99-106