Sequence distribution and cumulative composition of gradient latex particles synthesized by a power-feed technique

Industrial and Engineering Chemistry Research

Volumn 52, Issue 37, 2013, Pages 13466-13476

  Yang, Wenxing ^a   Xie, Delong ^a   Sheng, Xinxin ^a   Zhang, Xinya ^a  

^a SOUTH CHINA UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CONVERSION FUNCTION; DETAILED KINETICS; EMULSION COPOLYMERIZATION; FREE RADICAL COPOLYMERIZATION; METHYL METHACRYLATES; MOLECULAR CHAINS; REACTIVITY RATIO; SEQUENCE DISTRIBUTION;

COPOLYMERIZATION; COPOLYMERS; EMULSIFICATION; EMULSION POLYMERIZATION; ESTERS; FREE RADICALS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

LATEXES;

EID: 84884406077     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie401542d     Document Type: Article

References (55)

1. Althues, H.; Palkovits, R.; Rumplecker, A. Synthesis and Characterization of Transparent Luminescent ZnS: Mn/PMMA Nanocomposites Chem. Mater. 2006, 18, 1068
2. Kitayama, Y.; Yorizane, M.; Kagawa, Y.; Minami, H.; Zetterlund, P. B.; Okubo, M. Preparation of Onion-like Multilayered Particles Comprising Mainly Poly-(iso-butyl methacrylate)-block-polystyrene by Two-step AGET ATRP Polymer 2009, 50, 3182
3. Beginn, U. Gradient Copolymers Colloid Polym. Sci. 2008, 286, 1465
4. Pakula, T.; Matyjaszewski, K. Copolymers with Controlled Distribution of Comonomers Along the Chain, 1. Structure, Thermodynamics and Dynamic Properties of Gradient Copolymers, Computer Simulation Macromol. Theory Simul. 1996, 5, 987
5. Matyjaszewski, K.; Ziegler, M. Gradient Copolymers by Atom Transfer Radical Copolymerization J. Phys. Org. Chem. 2000, 13, 775
6. Qin, S.; Saget, J.; Pyun, J.; Jia, S.; Kowalewaski, T.; Matyjaszewski, K. Regioregular Head-to-Tail Poly(4-alkylquinoline) s: Synthesis, Characterization, Self-Organization, Photophysics, and Electroluminescence of New n-Type Conjugated Polymers Macromolecules 2003, 36, 8969
7. Gray, M. K.; Zhou, H.; Nguyen, S. T.; Torkelson, J. M. Synthesis and Glass Transition Behavior of High Molecular Weight Styrene/4-Acetoxystyene and Styrene/4-Hydroxystyrene Gradient Copolymers Made via Nitroxide-Mediated Controlled Radical Polymerization Macromolecules 2004, 37, 5586
8. Okabe, S.; Seno, K.; Kanaoka, S. Micellization Study on Block and Gradient Copolymer Aqueous Solutions by DLS and SANS Macromolecules 2006, 39, 1592
9. Christopher, L. H.; Wong, J. K.; Torkelson, J. M. Comparison of Critical Micelle Concentrations of Gradient Copolymer and Block Copolymer in Homopolymer:Novel Characterization by Intrinsic Fluorescence Macromolecules 2007, 40, 5631
10. Kim, J.; Mok, M. M.; Sandoval, R. W.; Woo, D. J.; Torkelson, J. M. Uniquely Broad Glass Transition Temperatures of Gradient Copolymers Relative to Random and Block Copolymers Containing Repulsive Comonomers Macromolecules 2006, 39, 6152
11. Wang, R.; Li, W. H.; Lou, Y. W.; Li, B. G.; Shi, A. C.; Zhu, S. P. Phase Behavior of Ternary Homopolymer/Gradient Copolymer Blends Macromolecules 2009, 42, 2275
12. Mok, M. M.; Ellison, C. J.; Torkelson, J. M. Effect of Gradient Sequencing on Copolymer Order-Disorder Transitions: Phase Behavior of Styrene/n-Butyl Acrylate Block and Gradient Copolymers Macromolecules 2011, 44, 6220
13. Zhao, Y.; Lou, Y. W.; Li, B. G.; Zhu, S. P. pH Responsivity and Micelle Formation of Gradient Copolymers of Methacrylic Acid and Methyl Methacrylate in Aqueous Solution Langmuir 2011, 27, 11306
14. Milonaki, Y.; Kaditi, E.; Pispas, S.; Demetzos, C. Facile one-pot/one-step technique for preparation of side-chain functionalized polymers: Combination of SET-RAFT polymerization of azide vinyl monomer and click chemistry J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 1226
15. Wang, L.; Broadbelt, L. J. Explicit Sequence of Styrene/Methyl Methacrylate Gradient Copolymers Synthesized by Forced Gradient Copolymerization with Nitroxide-mediated Controlled Radical Polymerization Macromolecules 2009, 42, 7961
16. Hawker, C. J.; Bosman, A. W.; Harth, E. Metal-Catalyzed Living Radical Polymerization Chem. Rev. 2001, 101, 3689
17. Min, K.; Li, M.; Matyjaszewski, K. Preparation of Gradient Copolymers via ATRP Using a Simultaneous Reverse and Normal Initiation Process. I. Spontaneous Gradient J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 3616
18. Min, K.; Kwon, Oh, J.; Matyjaszewski, K. Preparation of Gradient Copolymers via ATRP in Miniemulsion. II. Forced Gradient J. Polym. Sci., Part A: Polym. Chem. 2007, 45, 1413
19. Wang, R.; Luo, Y. W.; Li, B. G.; Zhu, S. P. Control of Gradient Copolymer Composition in ATRP Using Semibatch Feeding Policy AIChE J. 2007, 53, 174
20. Zhou, Y. N.; Li, J. J.; Luo, Z. H. Synthesis of Gradient Copolymers with Simultaneously Tailor-made Chain Composition Distribution and Glass Transition Temperature by Semibatch ATRP: From Modeling to Application J. Polym. Sci. Part A Polym. Chem. 2012, 50, 3052
21. Lee, S. B.; Russell, A. J.; Matyjaszewski, K. ATRP Synthesis of Amphiphilic Random, Gradient, and Block Copolymers of 2-(Dimethylamino)ethyl Methacrylate and n -Butyl Methacrylate in Aqueous Media Biomacromolecules 2003, 4, 1386
22. Krivorotova, T.; Vareikis, A.; Gromadzki, D.; Netopilík, M.; Makuška, R. Conventional Free-radical and RAFT Polymerization of Poly(ethylene oxide) Containing Macromonomers Eur. Polym. J. 2010, 46, 546
23. Sun, X. Y.; Luo, Y. W.; Wang, R.; Li, B. G.; Zhu, S. P. Semibatch RAFT Polymerization for Producing ST/BA Copolymers with Controlled Gradient Composition Profiles AIChE J. 2008, 54, 1073
24. Sun, X. Y.; Luo, Y. W.; Wang, R.; Li, B. G.; Liu, B.; Zhu, S. P. Programmed Synthesis of Copolymer with Controlled Chain Composition Distribution via Semibatch RAFT Copolymerization Macromolecules 2007, 40, 849
25. Ye, Y.; Schork, F. J. Modeling and Control of Sequence Length Distrbituion for Controlled Radical(RAFT) Copolymerization Ind. Eng. Chem. Res. 2009, 48, 10827
26. Rosen, B. M.; Percec, V. Single-Electron Transfer and Single-Electron Transfer Degenerative Chain Transfer Living Radical Polymerization Chem. Rev. 2009, 109, 5069
27. Percec, V.; Guliashvili, T.; Ladislaw, J. S.; Wistrand, A.; Stjerndahl, A.; Sienkowska, N. J.; Sahoo, S. Ultrafast synthesis of ultrahigh molar mass polymers by metal-catalyzed living radical polymerization of acrylates, methacrylates, and vinyl chloride mediated by SET at 25 degrees C J. Am. Chem. Soc. 2006, 128, 14156
28. Shi, Y.; Qin, X.; Guo, Y.; Xie, M.; Zhang, Y. The Effect of Activation/ Deactivation Processes on the Microcomposition and Microsequence Structure of Controlled/Living Copolymers Macromol. Theory Simul. 2008, 17, 130
29. Wang, R.; Luo, Y. W.; Li, B. G.; Sun, X. Y.; Zhu, S. P. Design and Control of Copolymer Composition Distribution in Living Radical Polymerization Using Semibatch Feeding Policies: a Model Simulation Macromol Theory Simul. 2006, 15, 356
30. Hu, Z.; Zhang, Z. Gradient Polymer Prepared by Complex-Radical Terpolymerizationof Styrene, Maleic Anhydride, and N-Vinyl Pyrrolidone viaγ-RayIrradiation by Use of a RAFT Process: Synthesis, Mechanism, and Characterization Macromolecules 2006, 39, 1384
31. Deng, W.; Zhang, M.; Li, W.; Kan, C. Polar Gradient Latex Particles with Hydrophilic Core and Hydrophobic Shell Prepared via Multistep Emulsion Polymerization Chin. J. Chem. 2011, 29, 853
32. Jasso-Gastinel, C. F.; López-Ureta, L. C.; González-Ortiz, L. J.; Reyes-González, I.; López-Dellamary, T., F. A.; Manero-Brito, O. Synthesis and Characterization of Styrene-butyl Acrylate Polymers, Varying Feed Composition in a Semicontinuous Emulsion Process J. Appl. Polym. Sci. 2007, 103, 3964
33. Çatalgil-Giz, H.; Giz, A.; Alb, A. M.; Öncül Koç, A.; Reed, W. F. Online Monitoring of Composition, Sequence Length, and Molecular Weight Distributions During Free Radical Copolymerization, and Subsequent Determiniation of Reactivity Ratios Macromolecules 2002, 35, 6557
34. Chern, C. S.; Poehlein, G. W. Polymerization in Nonuniform Latex Particles. II. Kinetics of Two-Phase Emulsion Polymerization J. Polym. Sci., Part A: Polym. Chem. 1990, 28, 3055
35. Madruga, E. L. From Classical to Living/controlled Statistical Free-radical Copolymerization Prog. Polym. Sci. 2002, 27, 1879
36. Zhang, X.; Wei, X.; Yang, W.; Li, Y.; Chen, H. Characterization and properties of gradient polyacrylate latex particles by gradient emulsion polymerization J. Coat. Tech. Res. 2012, 9, 765
37. Wang, L.; Broadbelt, L. J. Model-Based Design for Preparing Styrene/Methyl Methacrylate Structural Gradient Copolymers Macromol. Theory Simul. 2011, 20, 191
38. Zhou, Y. N.; Luo, Z. H.; Chen, J. H. Theoretical Modeling Coupled with Experimental Study on the Preparation and Characterization Comparison of Fluorinated Copolymers: Effect of Chain Structure on Copolymer Properties AIChE J. 2013, 10.1002/aic.14057
39. Cho, A. S.; Broadbelt, L. J. Stochastic Modelling of Gradient Copolymer Chemical Composition Distribution and Sequence Length Distribution Molecul. Simul. 2010, 36, 1219
40. Beginn, U. Monomer Addition Programs to Generate Constant Gradient Block Copolymers Polymer 2006, 47, 6880
41. Bassett D, R.; Hoy, K. L. Emulsion Polymers and Emulsion Polymerization ACS Symp. Ser. 1981, 165, 371
42. Santillán, R.; Nieves, E.; Alejandre, C. P.; Gómez- Yañez, C.; del Río, J. M.; Dorantes-Rosales, H.; Navarro-Clemente, M. E.; Corea, M. Synthesis of highly carboxylated latex particles using a power feed process J. Ind. Eng. Chem. 2013, 19, 1257
43. Johnston, J. E.; Bassett, D. R.; MacRury, T. B. Nonuniform Emulsion Polymers Carbon-13 NMR Spectroscopy ACS Symp. Ser. 1981, 165, 389
44. Saldivar, E.; Harmon Ray, W. Control of Semicontinuous Emulsion Copolymerization Reactors AIChE J. 1997, 43, 2021
45. Slomkowski, S.; Alemán, J. V.; Gilbert, R. G.; Hess, M.; Horie, K.; Jones, R. G.; Kubisa, P.; Meisel, I.; Mormann, W.; Penczek, S. S.; Robert, F. T. Terminology of Polymers and Polymerization Processes in Dispersed Systems Pure Appl. Chem. 2011, 83, 2229
46. Johnston, J. E.;; Bassett, D. R.;; Macrury, T. B. Nonuniform Emulsion Polymers Carbon-13 NMR Spectroscopy. In Emulsion Polymers and Emulsion Polymerization; ACS Symposium Series; American Chemical Society: Washington, D.C., 1981; Vol. 165, p 389.
47. Mayo, F. R.; Lewis, F. M. Copolymerization. I. A basis for Comparing the Behavior of Monomers in Copolymerization: the Copolymerization of Styrene and Methyl Methacrylate J. Am. Chem. Soc. 1944, 66, 1594
48. Thickett, S. C.; Gilbert, R. G. Emulsion Polymerization: State of the Art in Kinetics and Mechanisms Polymer 2007, 48, 6965
49. Fineman, M.; Ross, S. D. Linear Method for Determining Monomer Reactivity Ratios in Copolymerization J. Polym. Sci., Part A: Polym. Chem. 1950, 5, 259
50. Kelen, T.; Tüdõs, F. Analysis of the Linear Methods for Determining Copolymerization Reactivity Ratios. I. A New Improved Linear Graphic Method J. Macromol. Sci. Part A: Pure and Appl. Chem. 1975, 9, 1
51. Polic, A. L.; Duever, T. A.; Penlidis, A. Case Studies and Literature Review on the Estimation of Copolymerization Reactivity Ratios J. Polym. Sci., Part A: Polym. Chem. 1998, 36, 813
52. Habibi, A.; Vasheghani-Farahani, E. Bayesian Modeling and Markov Chain Monte Carlo Simulations for a Kinetic Study of Homo- and Co- Polymerization Systems Macromol. Theory Simul. 2007, 16, 269
53. Bondon, A.; Autret, M.; Simonneaux, G. Identification of Modified Natural Porphyrin Isomers: 1H and 13C NMR Assignments by NOESY and Reverse Heteronuclear Shift Correlation Magn. Reson. Chem. 1994, 32, 78
54. Noel, L. F. J.; Maxwell, I. A.; German, A. L. Partial Swelling of Latex Particles by Two Monomers Macromolecules 1993, 26, 2911
55. Aerdts, A. M.; German, A. L.; van der Velden, G. P. M. Derermaination of the Reactivity Ratios, Sequence Distribution and Stereoregularity of Butyl Acrylate-Methyl Methacrylate Copolymers by Means of Proton and Carbon-13 NMR Magn. Reson. Chem. 1994, 32, S80