Chloride ion-pairing with Ru(II) polypyridyl compounds in dichloromethane

Journal of Physical Chemistry A

Volumn 117, Issue 36, 2013, Pages 8883-8894

  Ward, William M ^a   Farnum, Byron H ^a   Siegler, Maxime ^a   Meyer, Gerald J ^a  

^a JOHNS HOPKINS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORIDE CONCENTRATIONS; DICHLOROMETHANE SOLUTIONS; EXCITED STATE LIFETIMES; NONLINEAR STERN-VOLMER; PHOTOPHYSICAL STUDIES; RADIATIVE RATE CONSTANTS; UV-VISIBLE ABSORPTION; X RAY CRYSTAL STRUCTURES;

DICHLOROMETHANE; ENERGY GAP; EQUILIBRIUM CONSTANTS; EXCITED STATES; IONS; LIGANDS; NUCLEAR PHYSICS; RATE CONSTANTS; RUTHENIUM ALLOYS; RUTHENIUM COMPOUNDS;

RUBIDIUM COMPOUNDS;

EID: 84884332721     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/jp404838z     Document Type: Article

References (53)

1. Marcus, Y.; Hefter, G. Ion Pairing Chem. Rev. 2006, 106, 4585-4621
2. Vining, W. J.; Caspar, J. V.; Meyer, T. J. The Influence of Environmental Effects on Excited-State Lifetimes. The Effect of Ion Pairing on Metal-to-Ligand Charge Transfer Excited States J. Phys. Chem. 1985, 89, 1095-1099
3. Macchioni, A. Ion Pairing in Transition-Metal Organometallic Chemistry Chem. Rev. 2005, 105, 2039-2074
4. Sutton, L. R.; Scheloske, M.; Pirner, K. S.; Hirsch, A.; Guldi, D. M.; Gisselbrecht, J.-P. Unexpected Change in Charge Transfer Behavior in a Cobalt(II) Porphyrin-Fullerene Conjugate That Stabilizes Radical Ion Pair States J. Am. Chem. Soc. 2004, 126, 10370-10381
5. McCosar, B. H.; Schanze, K. S. Ion-Pair Charge Transfer Photochemistry in Rhenium(I) Borate Salts Inorg. Chem. 1996, 35, 6800-6808
6. Llewellyn, D. B.; Adamson, D.; Arndtsen, B. A. A Novel Example of Chiral Counteranion Induced Enantioselective Metal Catalysis: The Importance of Ion-Pairing in Copper-Catalyzed Olefin Aziridination and Cyclopropanation Org. Lett. 2000, 2, 4165-4168
7. Abramo, G. P.; Li, L.; Marks, T. J. Polynuclear Catalysis: Enhancement of Enchainment Cooperativity between Different Single-Site Olefin Polymerization Catalysts by Ion Pairing with a Binuclear Cocatalyst J. Am. Chem. Soc. 2002, 124, 13966-13967
8. Brak, K.; Jacobsen, E. N. Asymmetric Ion-Pairing Catalysis Angew. Chem., Int. Ed. 2013, 52, 534-561
9. Choi, M. M. F.; Douglas, A. D.; Murray, R. W. Ion-Pair Chromatographic Separation of Water-Soluble Gold Monolayer-Protected Clusters Anal. Chem. 2006, 78, 2779-2785
10. Yamakawa, N.; Jiang, M.; Key, B.; Grey, C. P. Identifying the Local Structures Formed During Lithiation of the Conversion Material, Iron Fluoride, in a Li Ion Battery: A Solid-State NMR, X-ray Diffraction, and Pair Distribution Function Analysis Study J. Am. Chem. Soc. 2009, 131, 10525-10536
11. Li, K.; Khlyabich, P. P.; Li, L.; Burkhart, B.; Thompson, B. C.; Campbell, J. C. Influence of Exciton Diffusion and Charge-Transfer State Dissociation Efficiency on the Short-Circuit Current Densities in Semi-Random Donor/Acceptor Polymer: Fullerene Solar Cells J. Phys. Chem. C 2013, 117, 6940-6948
12. Clifford, J. N.; Palomares, E.; Nazeeruddin, M. K.; Grätzel, M.; Durrant, J. R. Dye Dependent Regeneration Dynamics in Dye-Sensitized Nanocrystalline Solar Cells: Evidence for the Formation of a Ruthenium Bipyridyl Cation/Iodide Intermediate J. Phys. Chem. C 2007, 111, 6561-6567
13. 3+Cl Inorg. Chem. 1996, 35, 7728-7734
14. Marton, A.; Clark, C. C.; Srinivasan, R.; Freundlich, R. E.; Narducci Sarjeant, A. A.; Meyer, G. J. Static and Dynamic Quenching of Ru(II) Polypyridyl Excited States by Iodide Inorg. Chem. 2006, 45, 362-369
15. Farnum, B. H.; Gardner, J. M.; Marton, A.; Narducci-Sarjeant, A. A.; Meyer, G. J. Influence of Ion Pairing on the Oxidation of Iodide by MLCT Excited States Dalton Trans. 2011, 40, 3830-3838
16. Farnum, B. H.; Jou, J. J.; Meyer, G. J. Visible Light Generation of I-I Bonds by Ru-tris(diimine) Excited States Proc. Natl. Acad. Sci. U.S.A. 2012, 109, 15628-15633
17. 2 Mesoporous Thin Films Langmuir 1999, 15, 731-737
18. Argazzi, R.; Bignozzi, C. A.; Heimer, T. A.; Castellano, F. N.; Meyer, G. J. Enhanced Spectral Sensitivity from Ruthenium(II) Polypyridyl Based Photovoltaic Devices Inorg. Chem. 1994, 33, 5741-5749
19. Van Houten, J.; Watts, R. J. Temperature Dependence of the Photophysical and Photochemical Properties of the Tris(2,2′-bipyridyl)ruthenium(II) Ion in Aqueous Solution J. Am. Chem. Soc. 1976, 98, 4853-4858
20. Macrae, C. F.; Bruno, I. J.; Chisholm, J. A.; Edgington, P. R.; McCabe, P.; Pidcock, E.; Rodriguez-Monge, L.; Taylor, R.; van de Streek, J.; Wood, P. A. Mercury CSD 2.0-New Features for the Visualization and Investigation of Crystal Structures J. Appl. Crystallogr. 2008, 41, 466-470
21. Bondi, A. van der Waals Volumes and Radii J. Phys. Chem. 1964, 68, 441-451
22. Fortin, S.; Beauchamp, A. L. Preparation and Characterization of Oxorhenium(V) Complexes with 2,2′-Biimidazole: The Strong Affinity of Coordinated Biimidazole for Chloride Ions via N-H...Cl- Hydrogen Bonding Inorg. Chem. 2000, 39, 4886-4893
23. Fortin, S.; Beauchamp, A. L. Preparations, Characterizations, and Structures of (Biimidazole)dihalobis(triphenylphosphine)rhenium(III) Salts: A Strong Ion-Pairing and Acid-Base Properties Inorg. Chem. 2001, 40, 105-112
24. Ayme, J.-F.; Beves, J. E.; Leigh, D. A.; McBurney, R. T.; Rissanen, K.; Schultz, D. A Synthetic Molecular Pentafoil Knot Nat. Chem. 2011, 4, 15-20
25. Silverstein, R.; Bassler, G.; Morrill, T. Spectroscopic Identification of Organic Compounds, 4 th ed.; John Wiley and Sons: New York, 1981.
26. Benesi, H. A.; Hildebrand, J. H. A Spectrophotometric Investigation of the Interaction of Iodine with Aromatic Hydrocarbons J. Am. Chem. Soc. 1949, 71, 2703-2707
27. Job, P. Job Plot Ann. Chim. Appl. 1928, 9, 113-203
28. Lakowicz, J. R. Principles of Fluorescence Spectroscopy, 2 nd ed.; Kluwer Academic/Plenum Publishers: New York, 1999.
29. Parker, C. A.; Rees, W. T. Correction of Fluorescence Spectra and Measurement of Fluorescence Quantum Efficiency Analyst 1960, 85, 587-600
30. Crosby, G. A.; Demas, J. N. Measurement of Photoluminescence Quantum Yields. Review J. Phys. Chem. 1971, 75, 991-1024
31. 2 Gels Chem. Mater. 1994, 6, 1041-1048
32. Strickler, S. J.; Berg, R. A. Relationship between Absorption Intensity and Fluorescence Lifetime of Molecules J. Chem. Phys. 1962, 37, 814-822
33. Englman, R.; Jortner, J. The Energy Gap Law for Nonradiative Decay in Large Molecules J. Lumin. 1970, 1-2, 134-142
34. 2+). Solvent Effects J. Am. Chem. Soc. 1983, 105, 5583-5590
35. 2+ Inorg. Chem. 1983, 22, 2444-2453
36. Allen, G. H.; White, R. P.; Rillema, D. P.; Meyer, T. J. Synthetic Control of Excited-State Properties. Tris-Chelate Complexes Containing the Ligands 2,2′-Bipyrazine, 2,2′-Bipyridine, and 2,2′- Bipyrimidine J. Am. Chem. Soc. 1984, 106, 2613-2620
37. Kober, E. M.; Caspar, J. V.; Lumpkin, R. S.; Meyer, T. J. Application of the Energy Gap Law to Excited-State Decay of Osmium(II)-Polypyridine Complexes: Calculation of Relative Nonradiative Decay Rates from Emission Spectral Profiles J. Phys. Chem. 1986, 90, 3722-3734
38. Photochemistry and Photophysics of Coordination Compounds I; Balzani, V.; Campagna, S., Eds.; Springer: Berlin, Germany, 2007; Vol. 280.
39. Caspar, J. V.; Sullivan, B. P.; Kober, E. M.; Meyer, T. J. Application of the Energy Gap Law to the Decay of Charge Transfer Excited States, Solvent Effects Chem. Phys. Lett. 1982, 91, 91-95
40. Durham, B.; Caspar, J. V.; Nagle, J. K.; Meyer, T. J. Photochemistry of Tris(2,2′-bipyridine)ruthenium(2+) Ion J. Am. Chem. Soc. 1982, 104, 4803-4810
41. McCusker, J.; McCusker, C. Synthesis and Spectroscopic Characterization of CN-Substituted Bipyridyl Complexes of Ru(II) Inorg. Chem. 2011, 50, 1656-1669
42. Bargawi, K. R.; Llobet, A.; Meyer, T. J. Synthetic Design of MLCT Excited States. Ligand-Substituted, Mono-2,2′-bipyridine Complexes of Ruthenium(II) J. Am. Chem. Soc. 1988, 110, 7751-7759
43. Van Houten, J.; Watts, R. J. Photochemistry of Tris(2,2′-bipyridyl) ruthenium(II) in Aqueous Solutions Inorg. Chem. 1978, 17, 3381-3385
44. Taylor, R.; Kennard, O. Crystallographic Evidence for the Existence of C-H...O, C-H...N, and C-H...Cl Hydrogen Bonds J. Am. Chem. Soc. 1982, 104, 5063-5070
45. 2+ and Related Complexes Chem. Phys. Lett. 1979, 68, 21-24
46. Mo, H.; Wang, A.; Wilkinson, P. S.; Pochapsky, T. C. Closed-Shell Ion Pairs: Cation and Aggregate Dynamics of Tetraalkylammonium Salts in an Ion-Pairing Solvent J. Am. Chem. Soc. 1997, 119, 11666-11673
47. Fuoss, R. M. Ionic Association. III. The Equilibrium between Ion Pairs and Free Ions J. Am. Chem. Soc. 1958, 80, 5059-5061
48. Powers, M. J.; Meyer, T. J. Medium and Distance Effects in Optical and Thermal Electron Transfer J. Am. Chem. Soc. 1980, 102, 1289-1297
49. Boschloo, G.; Hagfeldt, A. Characteristics of the Iodide/Triiodide Redox Mediator in Dye-Sensitized Solar Cells Acc. Chem. Res. 2009, 42, 1819-1826
50. Rowley, J. G.; Farnum, B. H.; Ardo, S.; Meyer, G. J. Iodide Chemistry in Dye-Sensitized Solar Cells: Making and Breaking I-I Bonds for Solar Energy Conversion J. Phys. Chem. Lett. 2010, 1, 3132-3140
51. II-Isothiocyanate Compounds J. Am. Chem. Soc. 2013, 135, 8331-8341
52. 2 Photoelectrochemical Cells J. Phys. Chem. B 1998, 102, 7577-7581
53. 2 Nanocrystallites: Evidence for a Stark Effect J. Phys. Chem. B 2010, 114, 14596-14604