Synthesis Concepts and Preparation of Silica Monoliths

Monolithic Silicas in Separation Science: Concepts, Syntheses, Characterization, Modeling and Applications, First Edition

Volumn , Issue , 2011, Pages 11-33

  Nakanishi, Kazuki ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84884019297     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9783527633241.ch2     Document Type: Chapter

References (32)

1. Nordberg, M.E. (1944) Properties of some Vycor - brand glasses. J. Am. Ceram. Soc., 27, 299 - 304.
2. Hood, H.P., and Nordberg, M.E. (1940) Method of treating borosilicate glasses. US Patent 2215039.
3. Vogel, W. (1985) Chemistry of Glass, The American Ceramic Society, Inc., Ohio.
4. Cahn, J.W. (1961) On spinodal decomposition. Acta Metall., 9, 795 - 801.
5. Cahn, J.W., and Charles, R.J. (1965) The initial stages of phase separation in glasses. Phys. Chem. Glasses, 6, 181 - 191.
6. Tanaka, H., Yazawa, T., Eguchi, H., Nagasawa, H., Matsuda, N., and Einishi, T. (1984) Precipitation of colloidal silica and pore - size distribution in high silica porous glass. J. Non - Cryst. Solids, 65, 301 - 309.
7. Nakashima, T., Shimizu, M., and Kawano, M. (1987) Articles of porous glass and process for preparing the same. US Patent 4,657,875.
8. Vladisavljevic, G.T., Kobayashi, I., Nakajima, M., Williams, R.A., Shimizu, M., and Nakashima, T. (2007) Shirasu Porous Glass membrane emulsification: characterisation of membrane structure by high - resolution X - ray microtomography and microscopic observation of droplet formation in real time. J. Membr. Sci., 302, 243 - 253.
9. Shoup, R.D. (1976) Controlled pore silica bodies gelled from silica - alkali silicate mixtures, in Colloid and Interface Science, vol. 3 (ed. M. Kerker), Academic Press, New York, pp. 63 - 69.
10. Nakanishi, K., and Soga, N. (1991) Phase separation in gelling silica - organic polymer solution: Systems containing poly[sodium styrenesulfonate]. J. Am. Ceram. Soc., 74, 2518 - 2530.
11. Nakanishi, K. (2006) Sol - gel process of oxides accompanied by phase separation. Bull. Chem. Soc. Jpn., 79, 673 - 691.
12. Tanaka, N., Ishizuka, N., Hosoya, K., Kimata, K., Minakuchi, H., Nakanishi, K., and Soga, N. (1993) Kuromatogurafi, 14, 50 - 51.
13. Minakuchi, H., Nakanishi, K., Soga, N., Ishizuka, N., and Tanaka, N. (1996) Octadecylsililated porous silica rods as separation media for reversed - phase liquid chromatography. Anal. Chem., 68, 3498 - 3501.
14. Minakuchi, H., Nakanishi, K., Soga, N., Ishizuka, N., and Tanaka, N. (1997) Effect of skeleton size on the performance of octadecylsilylated continuous porous silica columns in reversed - phase liquid chromatography. J. Chromatogr. A, 762, 135 - 146.
15. Minakuchi, H., Nakanishi, K., Soga, N., Ishizuka, N., and Tanaka, N. (1998) Effect of domain size on the performance of octadecylsilylated continuous porous silica columns in reversed - phase liquid chromatography. J. Chromatogr. A, 797, 121 - 131.
16. Iler, R.K. (1976) The Chemistry of Silica, John Wiley & Sons, Inc., New York.
17. Unger, K.K. (1979) Porous Silica its Properties and Use as Support in Column Liquid Chromatography, Journal of Chromatography Library, Elsevier, Amsterdam.
18. Takahashi, R., Sato, S., Sodesawa, T., and Azuma, T. (2004) Silica with bimodal pores for solid catalysts prepared from water glass. J. Sol - Gel Sci. Technol., 31, 373 - 376.
19. Brinker, C.J., and Scherer, G.W. (1990) Sol - Gel Science; The Physics and Chemistry of Sol - Gel Processing, Academic Press, New York.
20. Flory, P.J. (1971) Principles of Polymer Chemistry, Cornell University Press, Ithaca, New York.
21. Cahn, J.W. (1965) Phase separation by spinodal decomposition in isotropic systems. J. Chem. Phys., 42, 93 - 99.
22. Hashimoto, T., Itakura, M., and Hasegawa, H. (1986) Late stage spinodal decomposition of a binary polymer mixture. I. Critical test of dynamical scaling on scattering function. J. Chem. Phys., 85, 6118 - 6128.
23. Hashimoto, T., Itakura, M., and Shimidzu, N. (1986) Late stage spinodal decomposition of a binary polymer mixture. II. Scaling analyses on Q m (t) and I m (t). J. Chem. Phys., 85, 6773 - 6786.
24. Tanaka, H., and Nishi, T. (1988) Anomalous phase separation behavior in a binary mixture of poly(vinyl methyl ether) and water under deep quench conditions. Jpn. J. Appl. Phys., 27, L1787 - L1790.
25. Tanaka, H. (2000) Viscoelastic phase separation. J. Phys. Condens. Matter, 12, R207 - R264.
26. Hikmet, R.M., Callister, S., and Keller, A. (1988) Thermoreversible gelation of atactic polystyrene: phase transformation and morphology. Polymer, 29, 1378 - 1388.
27. De Rudder, J., Berghmans, H., and Arnauts, J. (1999) Phase behaviour and structure formation in the system syndiotactic polystyrene/cyclohexanol. Polymer, 40, 5919 - 5928.
28. Nakanishi, K. (1997) Pore structure control of silica gels based on phase separation. J. Porous Mater., 4, 67 - 112.
29. Nakanishi, K., Takahashi, R., Nagakane, T., Kitayama, K., Koheiya, N., Shikata, H., and Soga, N. (2000) Formation of hierarchical pore structure in silica gel. J. Sol - Gel Sci. Technol., 17, 191 - 210.
30. Shintani, Y., Zhou, X., Furuno, M., Minakuchi, H., and Nakanishi, K. (2003) Monolithic silica column for in - tube solid - phase microextraction coupled to high - performance liquid chromatography. J. Chromatogr. A, 985, 351 - 357.
31. Miyazaki, S., Morisato, K., Ishizuka, N., Minakuchi, H., Shintani, Y., Furuno, M., and Nakanishi, K. (2004) Development of a monolithic silica extraction tip for the analysis of proteins. J. Chromatogr. A, 1043, 19 - 25.
32. Ota, S., Miyazaki, S., Matsuoka, H., Morisato, K., Shintani, Y., and Nakanishi, K. (2007) High - throughput protein digestion by trypsin - immobilized monolithic silica with pipette - tip formula. J. Biochem. Biophys. Methods, 70, 57 - 62.