Effects of precipitation aging time on the performance of CuO/ZnO/CeO2-ZrO2 for methanol steam reforming

Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology

Volumn 41, Issue 7, 2013, Pages 883-888

  Zhang, Lei ^a,b,c   Pan, Li Wei ^c   Ni, Chang Jun ^c   Sun, Tian Jun ^c   Wang, Shu Dong ^c   Hu, Yong Kang ^a   Wang, An Jie ^a   Zhao, Sheng Sheng ^c  

^a DALIAN UNIVERSITY OF TECHNOLOGY   (China)

^b LIAONING SHIHUA UNIVERSITY   (China)

^c DALIAN INSTITUTE OF CHEMICAL PHYSICS   (China)

Author keywords

Aging time; CO concentration; Hydrogen; Methanol steam reforming

Indexed keywords

CATALYSTS; CATALYTIC REFORMING; CERIUM COMPOUNDS; COPPER OXIDES; COPRECIPITATION; HYDROGEN PRODUCTION; METHANOL; OXYGEN; STEAM REFORMING;

AGING TIME; CEO 2-ZRO 2; CO CONCENTRATIONS; CU ATOMS; H 2 PRODUCTION; METHANOL-STEAM REFORMING; OXYGEN STORAGE CAPACITY; PERFORMANCE; PRODUCTION RATES; ]+ CATALYST;

COPPER;

EID: 84883782781     PISSN: 2097213X     EISSN: 18725813     Source Type: Journal    
DOI: 10.1016/s1872-5813(13)60038-9     Document Type: Article

References (25)

1. GUNTER M M, RESSLER T, JENTOFT R E, BEMS B. Redox behavior of copper oxide/zinc oxide catalysts in the steam reforming of methanol studied by in situ X-Ray diffraction and absorption spectroscopy [J]. J Catal, 2001, 203(1): 133-149.
2. LINDSTROM B, PETTERSSON L J. Hydrogen generation by steam reforming of methanol over copper-based catalysts for fuel cell applications [J]. Int J Hydrogen Energy, 2001, 26(9): 923-933.
3. SHEN G C, FUJITA S, MATSUMOTO S, TAKEZAWA N. Steam reforming of methanol on binary Cu/ZnO catalysts: Effects of preparation condition upon precursors, surface-structure and catalytic activity [J]. J Mol Catal A: Chem, 1997, 124(1/2): 123-136.
4. LINDSTROM B, PETTERSSON L J, MENON P G. Activity and characterization of Cu/Zn, Cu/Cr and Cu/Zr on γ-alumina for methanol reforming for fuel cell vehicles [J]. Appl Catal A: Gen, 2002, 234(1/2): 111-125.
5. 2 [J]. J Catal, 2005, 234(2): 463-475.
6. FUKNAGA T, RYUMON N, ICHIKUNI N, SHIMAZU S. Characterization of CuMn-spinel catalyst for methanol steam reforming [J]. Catal Commun, 2009, 10(14): 1800-1803.
7. 3 catalysts [J]. Fuel Process Technol, 2003, 83(1/3): 183-192.
8. 3 catalysts [J]. Appl Catal A: Gen, 2009, 358(1): 7-12.
9. 3 [J]. Appl Catal B: Environ, 2009, 90(1/2): 195-204.
10. 2 catalysts [J]. Appl Catal B: Environ, 2009, 91(1/2): 524-532.
11. 2 catalysts [J]. Int J Hydrogen Energy, 2009, 34(18): 7648-7655.
12. 2 over nonreduced Zr-containing CuO/ZnO catalysts [J]. J Catal, 2004, 223(2): 340-351.
13. 3 [J]. J Catal, 2003, 219(2): 389-403.
14. 3 catalysts [J]. J Mol Catal A: Chem, 2003, 194(1/2): 99-105.
15. 2-promoted CuO/ZnO catalyst for methanol steam reforming [J]. Int J Hydrogen Energy, 2013, 38(11): 4397-4406.
16. 0.1 catalysts (RE=La, Pr, Nd, Sm, Eu, Gd, Tb) [J]. Catal Commun, 2009, 10(8): 1192-1195.
17. 2 solid-solutions as highly efficient oxygen exchangers: Dependence of the reduction behavior and the oxygen storage capacity on the structural-properties [J]. J Catal, 1995, 151(1): 168-177.
18. 2 production for fuel cells [J]. Catal Today, 2002, 77(1/2): 89-98.
19. WALLER D, STIRLING D, STONE F S, SPENCER M S. Copper-zinc oxide catalysts-activity in relation to precursor structure and morphology [J]. Faraday Discuss Chem Soc, 1989, 87(0): 107-120.
20. TAYLOR S H, HUTCHINGS G J, MIRZAEI A A. The preparation and activity of copper zinc oxide catalysts for ambient temperature carbon monoxide oxidation [J]. Catal Today, 2003, 84(3/4): 1173-1374.
21. 2 catalyst for the steam reforming of methanol [J]. J Catal, 2005, 233(2): 297-307.
22. CHINCHEN G C, HAY C M, VANDERVELL H D, WAUGH K C. The measurement of copper surface areas by reactive frontal chromatography [J]. J Catal, 1987, 103(1): 79-86.
23. SHIMOLAWABE H, ASAKAWA H, TAKEZAWA N. Characterization of copper/zirconia catalysts prepared by an impregnation method [J]. Appl Catal, 1990, 59(1): 45-58.
24. BREEN J P, ROSS J R H. Methanol reforming for fuel-cell applications: Development of zirconia-containing Cu-Zn-Al catalysts [J]. Catal Today, 1999, 51(3/4): 521-533.
25. TAKAHASHI K, TAKEZAWA N, KOBAYASHI H. The mechanism of steam reforming of methanol over a copper-silica catalyst [J]. Appl Catal, 1982, 2(6): 363-366.