The inhibition of acrylic acid and acrylate ester polymerisation in a heterogeneously catalysed pilot-scale reactive distillation column

Chemical Engineering Science

Volumn 88, Issue , 2013, Pages 95-107

  Niesbach, A ^a   Daniels, J ^a   Schroter B ^a   Lutze, P ^a   Gorak A ^a,b  

^a TU DORTMUND UNIVERSITY   (Germany)

^b LODZ UNIVERSITY OF TECHNOLOGY   (Poland)

Author keywords

Butyl acrylate; Catalytic distillation; Distillation; Hydroquinone monomethyl ether; Phenothiazine; Polymerisation

Indexed keywords

ACRYLIC MONOMERS; CARBOXYLIC ACIDS; DISTILLATION; ESTERIFICATION; ESTERS; ETHERS; INSECTICIDES; PHENOLS; POLYMERIZATION; POLYMERS;

ACRYLIC ACIDS; BUTYL ACRYLATES; CATALYTIC DISTILLATION; COMPLEX THERMODYNAMICS; COST-INTENSIVE; CURRENT PRODUCTION; ESTERIFICATION REACTIONS; EXPERIMENTAL INVESTIGATIONS; GAS PHASE COMPOSITION; LIQUID-LIQUID SEPARATION; MONOMETHYL ETHERS; N-BUTANOL; N-BUTYL ACRYLATE; PHENOTHIAZINE; PILOT SCALE; PROCESS INTENSIFICATION; REACTIVE DISTILLATION COLUMNS; REACTIVE DISTILLATIONS; THEORETICAL INVESTIGATIONS;

DISTILLATION COLUMNS;

EID: 84883491196     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2012.10.029     Document Type: Article

References (31)

1. Becker, H., 2003. Polymerisationsinhibierung von (Meth-)Acrylaten. Stabilisator und Sauerstoffverbrauch. Dissertation, Darmstadt.
2. Behrens, M., 2006. Hydrodynamics and Mass Transfer of Modular Catalytic Structured Packings. Dissertation, Enschede.
3. Borzo M., Heubeck J.C., Potenza J.A., Wagner B.E. Reactions of phenothiazine radical cations on ion-exchange resin surfaces. An ESR flow study. J. Colloid Interface Sci. 1984, 97:428-434.
4. Brand, R., 2011. Reaktionstechnische Studien zum Einfluss von Wasser auf die Stabilität von Acrylsäure. Dissertation, Darmstadt.
5. Cytec Industries Inc., 2003. PTZ Phenothiazine. A Stabilizer for a Variety of Chemical Applications, West Patterson.
6. Elias H.-G. Makromoleküle 2003, Wiley-VCH, Weinheim. sixth ed.
7. Glauser, J., Blagoev, M., Fujita, K., 2007. CEH Marketing Research Report: Acrylic Acid and Esters.
8. Górak A., Stankiewicz A. Intensified reaction and separation systems. Annu. Rev. Chem. Biomol. 2011, 2:431-451.
9. Hiwale R.S., Bhate N.V., Mahajan Y.S., Mahajani S.M. Industrial applications of reactive distillation: recent trends. Int. J. Chem. Reactor Eng. 2004, 2.
10. IFA. Institut für Arbeitsschutz der deutschen gesetzlichen Unfallversicherung. GESTIS-database on hazardous substances,. (Accessed 13 April, 2012). http://www.dguv.de/ifa/de/gestis/stoffdb/index.jsp.
11. I.H.S. Inc., 2011. Acrylic Acid, Acrylate Esters and Superabsorbent Polymers.
12. Keller, T., Tretjak, S., Lacroix, C., Hoffmann, A., Górak, A., 2010. Process intensification of n-butyl acrylate synthesis using catalytic distillation-a theoretical study. In: 19th International Congress of Chemical and Process Engineering. CHISA 2010, Prague.
13. Kirch L.S., Kargol J.A., Magee J.W., Stuper W.S. Stability of acrylic monomers. Plant/Oper. Progr. 1988, 7:270-274.
14. Kister H.Z. Distillation Design 1992, McGraw-Hill, New York.
15. Levy L.B. Inhibition of acrylic acid polymerization by phenothiazine and p-methoxyphenol. J. Polym. Sci. A-Polym. Chem. 1985, 23:1505-1515.
16. Levy L.B. Inhibition of acrylic acid polymerization by phenothiazine and p-Methoxyphenol. II. Catalytic inhibition by phenothiazine. J. Polym. Sci., Part A: Polym. Chem. 1992, 30:569-576.
17. Logutov, V.I., Danov, S.M., Chubarov, G.A., Tomashchuk, V.I., 1983. Liquid-Liquid equilibria in certain systems containing acrylic acid and butyl acrylate. Zhurnal Prikladnoi Khimii, vol 56.
18. Lovell, P.A., El-Aasser, M.S., 1997. Emulsion Polymerization and Emulsion Polymers. John Wiley & Sons, New York.
19. Mosnáček J., Nicolaÿ R., Kar K.K., Fruchey S.O., Cloeter M.D., Harner R.S., Matyjaszewski K. Efficient polymerization inhibition systems for acrylic acid distillation: new liquid-phase inhibitors. Ind. Eng. Chem. Res. 2012, 51:3910-3915.
20. Nexant Inc., 2006. PERP Program-Acrylic Acid.
21. 2 concentration on methacrylic acid stability. Plant/Oper. Progr. 1991, 10:171-183.
22. Ohara T., Sato T., Shimizu N., Prescher G., Schwind H., Weiberg O., Marten K., Greim H. Acrylic acid and derivatives. In: Ullmann's Encyclopedia of Industrial Chemistry 2000, Wiley-VCH, Weinheim, Germany.
23. Rohm and Haas Company, 2005. AMBERLYST Polymeric Catalysts.
24. Sangster Research Laboratories. LOGKOW-A databank of evaluated octanol-water partition coefficients,. (Accessed 13 April, 2012). http://logkow.cisti.nrc.ca/logkow/index.jsp.
25. Schulze S., Vogel H. Aspects of the safe storage of acrylic monomers: kinetics of the oxygen consumption. Chem. Eng. Technol. 1998, 21:829-837.
26. Schwarzer S., Hoffmann U. Experimental reaction equilibrium and kinetics of the liquid-phase butyl acrylate synthesis applied to reactive distillation simulations. Chem. Eng. Technol. 2002, 25:975-980.
27. Staudinger H., Urech E. Über die poly-acrylsäure und poly-acrylsäureester. Helv. Chim. Acta 1929, 12. 1107 ff.
28. Status and Future Directions 2003, Wiley-VCH, Weinheim. K. Sundmacher, A. Kienle (Eds.).
29. Susan L. Bell, 2003. Acrylic Acids and Esters. Report no. 6D, California.
30. Taurand G. Phenothiazine and derivatives. In: Ullmann's Encyclopedia of Industrial Chemistry 2000, Wiley-VCH, Weinheim, Germany.
31. Zeng K.-L., Kuo C.-L., Chien I.-L. Design and control of butyl acrylate reactive distillation column system. Chem. Eng. Sci. 2006, 4417-4431.