Direct determination of absolute molecular stereochemistry in gas phase by coulomb explosion imaging

Science

Volumn 341, Issue 6150, 2013, Pages 1096-1100

  Pitzer, Martin ^a   Kunitski, Maksim ^a   Johnson, Allan S ^a,b   Jahnke, Till ^a   Sann, Hendrik ^a   Sturm, Felix ^a   Schmidt, Lothar Ph H ^a   Schmidt Böcking, Horst ^a   Dörner, Reinhard ^a   Stohner, Jürgen ^c   Kiedrowski, Julia ^d   Reggelin, Michael ^d   Marquardt, Sebastian ^d   Schießer, Alexander ^d   Berger, Robert ^d   Schöffler, Markus S ^a  

^a GOETHE UNIVERSITY   (Germany)

^b UNIVERSITY OF OTTAWA   (Canada)

^c ZURICH UNIVERSITY OF APPLIED SCIENCES   (Switzerland)

^d DARMSTADT UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

BROMODICHLOROMETHANE; CHLORINE; FLUORINE; FLUOROMETHANE; SACCHARIC ACID;

CRYSTALLINITY; DISPERSION; GAS PHASE REACTION; IONIZATION; MASS SPECTROMETRY; METHANE; MOLECULAR ANALYSIS; STEREO IMAGE; X-RAY DIFFRACTION;

AQUEOUS SOLUTION; ARTICLE; CHIRALITY; COULOMB EXPLOSION IMAGING; CRYSTAL STRUCTURE; ENANTIOMER; FEMTOSECOND LASER; GAS; IONIZATION; LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; MOLECULAR DYNAMICS; MOLECULAR IMAGING; MOLECULAR MECHANICS; MOLECULE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OPTICAL ROTATION; PRIORITY JOURNAL; STATIC ELECTRICITY; STEREOCHEMISTRY; X RAY DIFFRACTION;

EID: 84883469699     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1240362     Document Type: Article

References (24)

1. R. Berger, in Relativistic Electronic Structure Theory, Part 2: Applications, P. Schwerdtfeger, Ed. (Elsevier, Netherlands, 2004), pp. 188-288.
2. C. Daussy et al., Phys. Rev. Lett. 83, 1554-1557 (1999).
3. M. Quack, J. Stohner, M. Willeke, Annu. Rev. Phys. Chem. 59, 741-769 (2008).
4. L. Pasteur, in Leçons de Chimie Professées en 1860 par MM. Pasteur, Cahours, Wurtz, Berthelot, Sainte-Claire Devile, Barral et Dumas (Hachette, Paris, 1861), pp. 1-48.
5. J. H. van't Hoff, Arch. Néerl. Sci. Exactes Nat. (French transl.) 9, 445-454 (1874).
6. J.-A. Le Bel, Bull. Soc. Chir. Paris T22, 337-347 (1874).
7. R. S. Cahn, C. Ingold, V. Prelog, Angew. Chem. Int. Ed. Engl. 5, 385-415 (1966).
8. J. M. Bijvoet, A. F. Peerdeman, A. J. van Bommel, Nature 168, 271-272 (1951).
9. Z. Vager, R. Naaman, E. P. Kanter, Science 244, 426-431 (1989).
10. T. Kitamura, T. Nishide, H. Shiromaru, Y. Achiba, N. Kobayashi, J. Chem. Phys. 115, 5 (2001).
11. E. Fischer, Ber. Dtsch. Chem. Ges. 24, 2683-2687 (1891).
12. F. W. Lichtenthaler, Angew. Chem. Int. Ed. Engl. 31, 1541-1556 (1992).
13. Y. Inokuma et al., Nature 495, 461-466 (2013).
14. A. D. Buckingham, Chem. Phys. Lett. 398, 1-5 (2004).
15. R. Berger et al., Angew. Chem. Int. Ed. 51, 8388-8391 (2012).
16. C. Lux et al., Angew. Chem. Int. Ed. 51, 5001-5005 (2012).
17. D. Patterson, J. M. Doyle, Phys. Rev. Lett. 111, 023008 (2013).
18. J. L. Hansen et al., J. Chem. Phys. 136, 204310 (2012).
19. J. Gagnon, K. F. Lee, D. M. Rayner, P. B. Corkum, V. R. Bhardwaj, J. Phys. B 41, 215104 (2008).
20. B. Wales et al., Nucl. Instrum. Methods Phys. Res. A 667, 11-15 (2012).
21. J. Hine, A. M. Dowell, J. E. Singley, J. Am. Chem. Soc. 78, 479-482 (1956).
22. J. Ullrich et al., Rep. Prog. Phys. 66, 1463-1545 (2003).
23. O. Jagutzki et al., IEEE Trans. Nucl. Sci. 49, 2477-2483 (2002).
24. Further details on the measurement principle, with six additional figures and four movies, are available in the supplementary materials on Science Online.