Nanographene and graphene edges: Electronic structure and nanofabrication

Accounts of Chemical Research

Volumn 46, Issue 10, 2013, Pages 2202-2210

  Fujii, Shintaro ^a   Enoki, Toshiaki ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84883225909     PISSN: 00014842     EISSN: 15204898     Source Type: Journal    
DOI: 10.1021/ar300120y     Document Type: Article

References (46)

1. Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A. Electric Field Effect in Atomically Thin Carbon Films Science 2004, 306, 666-669
2. Novoselov, K. S.; Jiang, Z.; Zhang, Y.; Morozov, S. V.; Stromer, H. L.; Zeitler, U.; Maan, J. C.; Boebinger, G. S.; Kim, P.; Geim, A. K. Room-Temperature Quantum Hall Effect in Graphene Science 2007, 315, 1379
3. Beenakker, C. W. J. Andreev reflection and Klein tunneling in graphene Rev. Mod. Phys. 2008, 80, 1337-1354
4. Geim, A. K.; Novoselov, K. S. The rise of graphene Nat. Mater. 2007, 6, 183-191
5. Clar, E. The Aromatic Sextet; Wiley: London, 1972.
6. Müllen, K.; Rabe, J. P. Nanographenes as Active Components of Single-Molecule Electronics and How a Scanning Tunneling Microscope Puts Them To Work Acc. Chem. Res. 2008, 41, 511-520
7. Niyogi, S.; Hamon, M. A.; Hu, H.; Zhao, B.; Bhowmik, P.; Sen, R.; Itkis, M. E.; Haddon, R. C. Chemistry of Single-Walled Carbon Nanotubes Acc. Chem. Res. 2002, 35, 1105-1113
8. Enoki, T; Kobayashi, Y. Magnetic nanographite: Approach to molecular magnetism J. Mater. Chem. 2005, 15, 3999-4002
9. Loh, K. P.; Bao, Q.; Ang, P. K.; Yang, J. The chemistry of graphene J. Mater. Chem. 2010, 20, 2277-2289
10. Rao, C. N. R.; Sood, A. K.; Subrahmanyam, K. S.; Govindaraj, A. Graphene: The New Two-Dimensional Nanomaterial Angew. Chem., Int. Ed. 2009, 48, 7752-7777
11. Dreyer, D. R.; Park, S.; Bielawski, C. W.; Ruoff, R. S. The chemistry of graphene oxide Chem. Soc. Rev. 2010, 39, 228-240
12. Sinitskii, A.; Tour, J. M. Chemical Approaches to Produce Graphene Oxide and Related Materials. In Graphene Nanoelectronics: From Materials to Circuits; Murali, R., Ed.; Springer: New York, 2012; DOI: http://dx.doi.org/ 10.1007/978-1-4614-0548-1-8.
13. Sakai, K.; Takai, K.; Fukui, K.; Nakanishi, T.; Enoki, T. Honeycomb superperiodic pattern and its fine structure near the armchair edge of graphene observed by low-temperature scanning tunneling microscopy Phys. Rev. B 2010, 81, 235417
14. Sasaki, K.; Wakabayashi, K.; Enoki, T. Berry's phase for standing waves near graphene edge New J. Phys. 2010, 12, 083023
15. Sasaki, K.; Wakabayashi, K.; Enoki, T. Electron Wave Function in Armchair Graphene J. Phys. Soc. Jpn. 2011, 80, 044710
16. Fujii, S.; Enoki, T. Clar aromatic sextet and π electron distribution in nanographene Angew. Chem., Int. Ed. 2012, 51, 7236-7241
17. Fujita, M.; Wakabayashi, K.; Nakada, K.; Kusakabe, K. Peculiar localized state at zigzag graphite edge J. Phys. Soc. Jpn. 1996, 65, 1920-1923
18. Nakada, K.; Fujita, M.; Dresselhaus, G.; Dresselhaus, M. S. Edge state in graphene ribbons: nanometer size effect and edge shape dependence Phys. Rev. B 1996, 54, 17954-17961
19. Kobayashi, Y.; Fukui, K.; Enoki, T.; Kusakabe, K.; Kaburagi, Y. Observation of zigzag and armchair edges of graphite using scanning tunneling microscopy and spectroscopy Phys. Rev. B 2005, 71, 193406
20. Kobayashi, Y.; Fukui, K.; Enoki, T.; Kusakabe, K. Edge state on hydrogen-terminated graphite edges investigated by scanning tunneling microscopy Phys. Rev. B 2006, 73, 125415
21. Enoki, T.; Kobayashi, Y.; Fukui, K. Electronic structures of graphene edges and nanographene Int. Rev. Phys. Chem. 2007, 26, 609-645
22. Niimi, Y.; Matsui, T.; Kambara, H.; Tagami, K.; Tsukada, M.; Fukuyama, H. Scanning tunneling microscopy and spectroscopy studies of graphite edges Appl. Surf. Sci. 2005, 241, 43-48
23. Niimi, Y.; Matsui, T.; Kambara, H.; Tagami, K.; Tsukada, M.; Fukuyama, H. Scanning tunneling microscopy and spectroscopy of the electronic local density of states of graphite surfaces near monoatomic step edges Phys. Rev. B 2006, 73, 085421
24. Fujii., S.; Enoki, T. Cutting of oxidized graphene into nanosized pieces J. Am. Chem. Soc. 2010, 132, 10034-10041
25. Wallace, P. R. The Band Theory of Graphite Phys. Rev. 1947, 71, 622-634
26. Ando, T. Theory of Electronic States and Transport in Carbon Nanotubes J. Phys. Soc. Jpn. 2005, 74, 777-817
27. Krygowski, T. M.; Cyrańsk, M. K. Structural aspect of aromaticity Chem. Rev. 2001, 101, 1385-1419
28. Randić, M. Aromaticity of polycyclic conjugated hydrocarbons Chem. Rev. 2003, 103, 3449-3605
29. Cançado, L. G.; Pimenta, M. A.; Neves, B. R. A.; Medeiros-Ribeiro, G.; Enoki, T.; Kobayashi, Y.; Takai, K.; Fukui, K.; Dresselhaus, M. S.; Saito, R.; Jorio, A. Anisotropy of the Raman spectra of nanographite ribbons Phys. Rev. Lett. 2004, 93, 047403
30. Sasaki, K.; Saito, R.; Wakabayashi, K.; Enoki, T. Identifying the orientation of edge of graphene using G band Raman spectra J. Phys. Soc. Jpn. 2010, 79, 044603
31. Dresselhaus, G.; Dresselhaus, M. S. Spin-Orbit Interaction in Graphite Phys. Rev. 1965, 140, A401
32. Stein, S. E.; Brown, R. L. π-Electron properties of large condensed polyaromatic hydrocarbons J. Am. Chem. Soc. 1987, 109, 3721-3729
33. Stein, S. E. Thermal Reactions and properties of polycyclic aromatic hydrocarbons Acc. Chem. Res. 1991, 24, 350-356
34. Tanaka, K.; Yamashita, S.; Yamabe, H.; Yamabe, T. Electronic properties of one-dimensional graphite family Synth. Met. 1987, 17, 143-148
35. Nakanishi, T.; Ando, T. Conductance between two scanning-tunneling- microscopy probes in carbon nanotubes J. Phys. Soc. Jpn. 2008, 77, 024703
36. Wassmann, T.; Seitsonen, A. P.; Saitta, A. M.; Lazzeri, M.; Mauri, F. Clar's theory, π-electron distribution, and geometry of graphene nanoribbons J. Am. Chem. Soc. 2010, 132, 3440-3451
37. Gutman, I.; Tomović, Ž.; Müllen, K.; Rabe, J. P. On the distribution of π-electrons in large polycyclic aromatic hydrocarbon Chem. Phys. Lett. 2004, 397, 412-416
38. Nakasuji, K.; Kubo, T. Multi-stage amphoteric redox hydrocarbons based on a phenalenyl radical Bull. Chem. Soc. Jpn. 2004, 77, 1791-1801
39. Wassmann, T.; Seitsonen, A. P.; Saitta, A. M.; Lazzeri, M.; Mauri, F. Structure, stability, edge states, and aromaticity of graphene ribbons Phys. Rev. Lett. 2008, 101, 096402-1-4
40. Sasaki, K.; Murakami, S.; Saito, R. Stabilization mechanism of edge states in graphene Appl. Phys. Lett. 2006, 88, 113110
41. Sasaki, K.; Shimomura, Y.; Takane, Y.; Wakabayashi, K. Hamiltonian Decomposition for Bulk and Surface States Phys. Rev. Lett. 2009, 102, 146806
42. Boukhvalov, D. W.; Katsnelson, M. I.; Lichtenstein, A. I. Hydrogen on graphene: Electronic structure, total energy, structural distortions and magnetism from first-principles calculations Phys. Rev. B 2008, 77, 035427
43. Balog, R.; Jørgensen, B.; Wells, J.; Lægsgaard, E.; Hofmann, P.; Besenbacher, F.; Hornekær, L. Atomic Hydrogen Adsorbate Structures on Graphene J. Am. Chem. Soc. 2009, 131, 8744-8745
44. Lomeda, J. R.; Doyle, C. D.; Kosynkin, D. V.; Hwang, W.-F.; Tour, J. M. Diazonium Functionalization of Surfactant-Wrapped Chemically Converted Graphene Sheets J. Am. Chem. Soc. 2008, 130, 16201-16206
45. Bekyarova, E.; Itkis, M. E.; Ramesh, P.; Berger, C.; Sprinkle, M.; de Heer, W. A.; Haddon, R. C. Chemical Modification of Epitaxial Graphene: Spontaneous Grafting of Aryl Groups J. Am. Chem. Soc. 2009, 131, 1336-1337
46. Li, J.-L.; Kudin, K. N.; McAllister, M. J.; Prud'homme, R. K.; Aksay, I. A.; Car, R. Oxygen-driven unzipping of graphitic materials Phys. Rev. Lett. 2006, 96, 176101 Technology Technology