Flammability and Thermal Stability in Clay/Polyesters Nano-Biocomposites

Green Energy and Technology

Volumn 50, Issue , 2012, Pages 265-285

  Bocchini, Sergio ^a   Camino, Giovanni ^a  

^a POLITECNICO DI TORINO   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

BIOPOLYMERS; COMPOSITE MATERIALS; FIRES; NANOCOMPOSITES; PLASTIC BOTTLES; SILICATES;

BIO-POLYESTERS; COMMERCIAL PLASTICS; FIRE BEHAVIOUR; FIRE RETARDANCY; FIRE RETARDED; FLAME RETARDANT PROPERTIES; NANO-BIOCOMPOSITES; RENEWABLE RESOURCE;

POLYESTERS;

EID: 84883159558     PISSN: 18653529     EISSN: 18653537     Source Type: Book Series    
DOI: 10.1007/978-1-4471-4108-2_10     Document Type: Article

References (73)

1. Shen L, Haufe J, Patel MK (2009) Product overview and market projection of emerging biobased plastics (PROBIP 2009). Commissioned by European Polysaccharide Network of Excellence (EPNOE) and European Bioplastics. Group Science, Technology and Society (STS), Copernicus Institute for Sustainable Development and Innovation, Utrecht University Utrecht, the Netherlands, June 2009. Report No: NWS-E-2009-32
2. Horrocks AR, Price D (2001) Fire retardant materials. CRC Press, Boston
3. Vaia RA, Ishii H, Giannelis EP (1993) Synthesis and properties of two-dimensional nanostructures by direct intercalation of polymer melts in layered silicates. Chem Mater 5(12):1694-1696
4. Zanetti M, Camino G, Mülhaupt R (2001) Combustion behaviour of EVA/fluorohectorite nanocomposites. Polym Degrad Stab 74(3):413-417
5. Brindely GW, Brown G (1980) Crystal structure of clay minerals and their X-ray identification. Mineralogical Society, London
6. Solomon DH, Hawthorne DG (1991) Chemistry of pigments and fillers. Krieger, Malabar
7. Sposito G, Skipper NT, Sutton R, Park SH, Soper AK, Greathouse JA (1999) Surface geochemistry of the clay minerals. Proc Natl Acad Sci USA 96:3358-3364
8. Sherman JD (1996) Synthetic zeolites and other microporous oxide molecular sieves. Proc Natl Acad Sci USA 96:3471-3478
9. Bocchini S, Fukushima K, Di Blasio A, Fina A, Frache A, Geobaldo F (2010) Polylactic acid and Polylactic acid-based nanocomposites photooxidation. Biomacromolecules 11(8): 2919-2926
10. Xie W, Gao Z, Pan W, Hunter D, Singh A, Vaia R (2001) Thermal degradation chemistry of alkyl quaternary ammonium montmorillonite. Chem Mater 13(9):2979-2990
11. Bellucci F, Camino G, Frache A, Sarra A (2007) Catalytic charring-volatilization competition in organoclay nanocomposites. Polym Degrad Stab 92(3):425-436 Figure 1 in
12. Akelah A, Moet A (1996) Polymer-clay nanocomposites: free-radical grafting of polystyrene on to organophilic montmorillonite interlayers. J Mater Sci 31(13):3589-3596
13. Agag T, Takeichi T (2000) Polybenzoxazine-montmorillonite hybrid nanocomposites: synthesis and characterization. Polymer 41(19):7083-7090
14. Chen TK, Tien YI, Wie KH (2000) Synthesis and characterization of novel segmented polyurethane/clay nanocomposites. Polymer 41(4):1345-1353
15. Cho JW, Paul DR (2001) Nylon 6 nanocomposites by melt compounding. Polymer 42(3):1083-1094
16. Bellucci F, Camino G, Frache A, Sarra A (2007) Catalytic charring-volatilization competition in organoclay nanocomposites. Polym Degrad Stab 92(3):425-436 Arranged from Figure 8 in
17. Bellucci F, Camino G, Frache A, Sarra A (2007) Catalytic charring-volatilization competition in organoclay nanocomposites. Polym Degrad Stab 92(3):425-436
18. Davis RD, Gilman JW, Sutto TE, Callahan JH, Trulove PC, De Long HC (2004) Improved thermal stability of organically modified layered silicates clays. Clay Miner 52(2):171-179
19. Bellucci F, Camino G, Frache A, Ristori V, Sorrentino L, Iannace S, Bian X, Guardasole M, Vaccaro S (2006) Effect of organoclay impurities on mechanical properties of EVA-layered silicate nanocomposites e-Polymers n_14
20. Bellucci F, Camino G, Frache A, Sarra A (2007) Catalytic charring-volatilization competition in organoclay nanocomposites. Polym Degrad Stab 92(3):425-436 Arranged from Figure 9
21. Bellucci F, Camino G, Frache A, Sarra A (2007) Catalytic charring-volatilization competition in organoclay nanocomposites. Polym Degrad Stab 92(3):425-436 Scheme 1 in
22. Park SJ, Seo DI, Lee JR (2002) Surface modification of montmorillonite on surface Acidbase characteristics of clay and thermal stability of epoxy/clay nanocomposites. J Coll InterfSci 251(1):160-165
23. Gilman JW, Kashiwagi T (1997) Nanocomposites: a revolutionary new flame retardant approach. SAMPE J 33:40-46
24. Kashiwagi T, Gilman JW, Nyden MR, Lomakin SM (1998) Polymer combustion and new flame retardants. In: Le Bras M, Camino G, Bourbigot S, Delobel R (eds.) Fire retardancy of polymers: the use of intumescence, The Royal Society of Chemistry, Cambridge
25. Gilman JW, Kashiwagi T, Giannelis EP, Manias E, Lomakin S, Lichtenhan JD, Jones P (1998) Nanocomposites: radiative gasification and vinyl polymer flammability. In: Le Bras M, Camino G, Bourbigot S, Delobel R (eds.) Fire retardancy of polymers: the use of intumescence, The Royal Society of Chemistry, Cambridge
26. Kashiwagi T, Harris RH, Zhang X, Briber RM, Cipriano BH, Raghavan SR, Awad WH, Shields JR (2004) Flame retardant mechanism of polyamide 6-clay nanocomposites. Polymer 45(3):881-891
27. Lewin M (2003) Some comments on the modes of action of nanocomposites in the flame retardancy of polymers. Fire Mater 27(1):1-7
28. Pastore HO, Frache A, Boccaleri E, Marchese L, Camino G (2004) Heat induced structure modifications in polymer-layered silicate nanocomposites. Macromol Mater Eng 289(9): 783-786
29. Wang J, Du J, Zhu J, Wilkie CA (2002) An XPS study of the thermal degradation and flame retardant mechanism of polystyrene-clay nanocomposites. Polym Degrad Stab 77(2): 249-252
30. Tang Y, Lewin M, Pearce EM (2006) Effects of annealing on the migration behavior of PA6/ Clay nanocomposites. Macromol Rapid Comm 27(18):1545-1549
31. Hao J, Lewin M, Wilkie CA, Wang J (2006) Additional evidence for the migration of clay upon heating of clay/polypropylene nanocomposites from X-ray photoelectron spectroscopy (XPS). Polym Degrad Stab 91(10):2482-2485
32. Tang Y, Lewin M (2007) Maleated polypropylene OMMT nanocomposite: annealing, structural changes, exfoliated and migration. Polym Degrad Stab 92(1):53-60
33. Lewin M, Tang Y (2008) Oxidation-migration cycle in polypropylene-based nanocomposites. Macromolecules 41(1):13-17
34. Frache A, Monticelli O, Ceccia S, Brucellaria A, Casale A (2008) Preparation of nanocomposites based on PP and PA6 by direct injection moulding. Polym Eng Sci 48(12): 2373-2381
35. Ceccia S, Bellucci F, Monticelli O, Frache A, Traverso G, Casale A (2010) The effect of annealing conditions on the intercalation and exfoliation of layered silicates in polymer nanocomposites. J Polym Sci Pol Phys 48(23):2476-2483
36. Mcneill IC, Leiper HA (1985) Degradation studies of some polyesters and polycarbonates 1 polylactide: general features of the degradation under programmed heating conditions. Polym Degrad Stab 11(3):267-285
37. Mcneill IC, Leiper HA (1985) Degradation studies of some polyesters and polycarbonates 2 polylactide: degradation under isothermal conditions, thermal degradation mechanism and photolysis of the polymer. Polym Degrad Stab 11(4):309-326
38. Wachsen O, Reachert KH, Kruger RP, Much H, Schulz G (1997) Thermal decomposition of biodegradable polyesters-III studies on the mechanisms of thermal degradation of oligo-Llactide using SEC LACCC and MALDI-TOF-MS. Polym Degrad Stab 55(2):225-231
39. Fan YJ, Nishida H, Hoshihara S, Shirai Y, Tokiwa Y, Endo T (2003) Pyrolysis kinetics of poly(L-lactide) with carboxyl and calcium salt end structures. Polym Degrad Stab 79(3): 547-562
40. Liu X, Zou Y, Li W, Cao G, Chen W (2006) Kinetics of thermo-oxidative and thermal degradation of poly(D, L-lactide) (PDLLA) at processing temperature. Polym Degrad Stab 91(12):3259-3265
41. Kopinke FD, Mackenzie K (1997) Mechanistic aspects of the thermal degradation of poly(lactic acid) and poly(b-hydroxybutyric acid). J Anal Appl Pyrol 40-41:43-53
42. Kopinke FD, Remmler M, Mackenzie K, Moder M, Wachsen O (1996) Thermal decomposition of biodegradable polyesters-II Poly(lactic acid). Polym Degrad Stab 53(3): 329-342
43. Gogolewski S, Jovanovic M, Perren S, Dillon J, Hughes M (1993) The effect of melt-processing on the degradation of selected polyhydroxyacids: polylactides, polyhydroxybutyrate, and polyhydroxybutyrate-co-valerates. Polym Degrad Stab 40(3):313-322
44. Jamshidi K, Hyon S, Ikada Y (1988) Thermal characterization of polylactides. Polymer 29(12):2229-2234
45. Cam D, Marucci M (1997) Influence of residual monomers and metals on poly (L-lactide) thermal stability. Polymer 38(8):1879-1884
46. Bensons SW, Nangia PS (1979) Some unresolved problems in oxidation and combustion. Accounts Chem Res 12(7):223-228
47. Gupta MC, Deshmukh VG (1982) Thermal oxidative degradation of poly-lactic acid Part I: activation energy of thermal degradation in air. Coll Polym Sci 260(3):308-311
48. Gupta MC, Deshmukh VG (1982) Thermal oxidative degradation of poly-lactic acid Part II: molecular weight and electronic spectra during isothermal heating. Coll Polym Sci 260(5): 514-517
49. Pluta M, Galeski A, Alexandre M, Paul MA, Dubois P (2002) Polylactide/montmorillonite nanocomposites and microcomposites prepared by melt blending: structure and some physical properties. J Appl Polym Sci 86(6):1497-1506
50. Paul MA, Alexandre M, Degee P, Henrist C, Rulmont A, Dubois P (2003) New nanocomposite materials based on plasticized poly(L-lactide) and organo-modified montmorillonites: thermal and morphological study. Polymer 44(2):443-450
51. Marras S, Zuburtikudis I, Panayiotou C (2007) Nanostructure vs. microstructure: morphological and thermomechanical characterization of poly(L-lactic acid)/layered silicate hybrids. Eur Polym J 43(6):2191-2206
52. Chen G, Yoon J (2005) Morphology and thermal properties of poly(L-lactide)/poly (butylene succinate-co-butylene adipate) compounded with twice functionalized clay. J Polym Sci Polym Phys 43(5):478-487
53. Zhou Q, Xanthos M (2009) Nanosize and microsize clay effects on the kinetics of the thermal degradation of polylactides. Polym Degr Stab 94(3):327-338
54. Okamoto K, Toshima K, Matsumura S (2005) Degradation of poly(lactic acid) into repolymerizable oligomer using montmorillonite K10 for chemical recycling. Macromol Biosci 5(9):813-820
55. Fukushima K, Murariu M, Camino G, Dubois P (2010) Effect of expanded graphite/layeredsilicate clay on thermal, mechanical and fire retardant properties of poly(lactic acid). Poly Degr Stab 95(6):1063-1076
56. Chang J, An Y, Sur G (2003) Poly(lactic acid) nanocomposites with various organoclays I Thermomechanical properties, morphology and gas permeability. J Polym Sci Polym Phys 41(1):94-103
57. Lee JW, Lim YT, Park OO (2000) Thermal characteristics of organoclay and their effects upon the formation of polypropylene/organoclay nanocomposites. Polym Bull 45(2):191-198
58. ISO standard 5660 (2002)
59. ASTM standard E 1354 (2003)
60. Bourbigot S, Duquesne S (2007) Fire retardant polymers: recent developments and opportunities. J Mater Chem 17(22):2283-2300
61. Bartholmai MM, Schartel B (2004) Layered silicate polymer nanocomposites: new approach or illusion for fire retardancy? Investigations of the potentials and the tasks using a model system. Polym Adv Technol 15(7):355-364
62. Bourbigot S, Fontaine G (2010) Flame retardancy of polylactide: an overview. Polym Chem 1(9):1413-1422
63. Zanetti M, Kashiwagi T, Falqui L, Camino G (2002) Cone calorimeter combustion and gasification studies of polymer layered silicate nanocomposites. Chem Mat 14(2):881-887
64. Gilman JW, Jackson CL, Morgan AB, Harris R, Manias E, Giannelis EP, Wuthenow M, Hilton D, Phillips SH (2000) Flammability properties of polymer-layered-silicate nanocomposites polypropylene and polystyrene nanocomposites. Chem Mat 12(7): 1866-1873
65. Bocchini S, Frache A, Camino G, Costantini E, Ferrara G, Fatinel F (2006) Poly-1-Butene/ Clay nanocomposite effect of compatibilisers on thermal and fire retardant properties. Polym Adv Technol 17(4):246-254
66. Bourbigot S, Fontaine G, Bellayer S, Delobel R (2008) Processing and nanodispersion: A quantitative approach for polylactide nanocomposites. Polym Test 27(1):2-10
67. Bourbigot S, Fontaine G, Duquesne S, Delobel R (2008) PLA nanocomposites: quantification of clay nanodispersion and reaction to fire. Int J Nanotechnol 5(6/7/8):683-692
68. Murariu M, Bonnaud L, Yoann P, Fontaine G, Bourbigot S, Dubois P (2010) New trends in polylactide (PLA)-based materials: "Green" PLA-Calcium sulfate (nano) composites tailored with flame retardant properties. Polym Degrad Stab 95(3):374-381
69. Solarski S, Mahjoubi F, Ferreira M, Devaux E, Bachelet P, Bourbigot S, Delobel R, Coszach P, Murariu M, Da Silva FA, Alexandre M, Degee P, Dubois P (2007) Plasticized Polylactide/ clay nanocomposite textile: thermal, mechanical, shrinkage and fire properties. J Mater Sci 42(13):5105-5117
70. Murariu M, Da Silva Ferreira A, Bonnaud L, Dubois P (2009) Calcium sulfate as highperformance filler for polylactide (PLA) or how to recycle gypsum as by-product of lactic acid fermentation process. Compos Interf 16(2-3):65-84
71. Fontaine G, Bourbigot S (2009) Intumescent polylactide: A nonflammable material. J Appl Polym Sci 113(6):3860-3865
72. Bourbigot S, Le Bras M, Delobel R, Decressain R, Amoureux JP (1996) Synergistic effect of zeolite in an intumescence process: study of the carbonaceous structures using solid-state NMR. J Chem Soc Faraday T 92(1):149-158
73. Bourbigot S, Le Bras M, Dabrowski F, Gilman JW, Kashiwagi T (2000) PA-6 clay nanocomposite hybrid as char forming agent in intumescent formulations. Fire Mater 24(4):201-208