High performance of polyoxometalate/PtPd nanoparticles/carbon nanotubes electrocatalysts for the methanol electrooxidation

International Journal of Hydrogen Energy

Volumn 38, Issue 25, 2013, Pages 11074-11079

  Hong, Liji ^a   Gui, Yanghai ^b   Lu, Juan ^a   Hu, Jianguo ^a   Yuan, Junhua ^a   Niu, Li ^c  

^a ZHEJIANG NORMAL UNIVERSITY   (China)

^b ZHENGZHOU UNIVERSITY OF LIGHT INDUSTRY   (China)

^c CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

Author keywords

Carbon nanotube; Electrocatalyst; Fuel cells; Methanol oxidation; Polyoxometalates; PtPd

Indexed keywords

CARBON; CARBON NANOTUBES; CATALYST SUPPORTS; CATALYSTS; ELECTROCATALYSIS; ELECTROCATALYSTS; ELECTROOXIDATION; FUEL CELLS; METHANOL; NANOPARTICLES; NANOTUBES; OXIDATION; OXIDES; PLATINUM; STRIPPING (REMOVAL); SYNTHESIS (CHEMICAL); YARN;

CO STRIPPING VOLTAMMETRY; ELECTROCHEMICAL SURFACE AREA; METHANOL ELECTROOXIDATION; METHANOL OXIDATION; MULTIWALLED CARBON NANOTUBE (MWCNTS); OXIDATIVE REMOVALS; POLYOXOMETALATES; PTPD;

MULTIWALLED CARBON NANOTUBES (MWCN);

EID: 84883133991     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2013.03.022     Document Type: Conference Paper

References (18)

1. Lim BK, Jiang MJ, Camargo PH, Cho EC, Tao J, Lu XM, et al. PdePt bimetallic nanodendrites with high activity for oxygen reduction. Science 2009;324:1302-5.
2. Chen W, Kim J, Sun S, Chen S. Electrocatalytic reduction of oxygen by FePt alloy nanoparticles. J Phys Chem C 2008;112:3891-8.
3. Gasteiger HA, Kocha SS, Sompalli B, Wagner FT. Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs. Appl Catal B Environ 2005;56:9-35.
4. Bergamaski K, Pinheiro AL, Teixeira-Neto E, Nart FC. Nanoparticle size effects on methanol electrochemical oxidation on carbon supported platinum catalysts. J Phy Chem B 2006;110:19271-9.
5. Liu Y, Chi MF, Mazumder V, More KL, Soled S, Henao JD, et al. Composition-controlled synthesis of bimetallic PdPt nanoparticles and their electro-oxidation of methanol. Chem Mater 2011;23:4199-203.
6. Wakisaka M, Mitsui S, Hirose Y, Kawashima K, Uchida H, Watanabe M. Electronic structures of PteCo and PteRu alloys for CO-tolerant anode catalysts in polymer electrolyte fuel cells studied by EC-XPS. J Phys Chem B 2006;110:23489-96.
7. 2 oxidation. Angew Chem Int Ed 2010;49:3173-6.
8. Nilekar AU, Sasaki K, Farberow CA, Adzic RR, Mavrikakis M. Mixed-metal Pt monolayer electrocatalysts with improved CO tolerance. J Am Chem Soc 2011;133:18574-6.
9. Park S, Wieckowski A, Weaver MJ. Electrochemical infrared characterization of CO domains on rutheniumdecorated platinum nanoparticles. J Am Chem Soc 2003;125:2282-90.
10. Watanabe M, Motoo S. Electrocatalysis by Ad-atoms: part II. Enhancement of the oxidation of methanol on platinum by ruthenium Ad-atoms. J Electroanal Chem 1975;60:267-73.
11. Zhang H, Jin MS, Liu HY, Wang JG, Kim MJ, Yang D, et al. Facile synthesis of PdePt alloy nanocages and their enhanced performance for preferential oxidation of CO in excess hydrogen. ACS Nano 2011;5:8212-22.
12. Hsin YL, Hwang KC, Yeh CT. Poly(vinylpyrrolidone)-modified graphite carbon nanofibers as promising supports for PtRu catalysts in direct methanol fuel cells. J Am Chem Soc 2007;129:9999-10010.
13. Jin XL, He B, Miao JG, Yuan JH, Zhang QX, Niu L. Stabilization and dispersion of PtRu and Pt nanoparticles on multiwalled carbon nanotubes using phosphomolybdic acid, and the use of the resulting materials in a direct methanol fuel cell. Carbon 2012;50:3083-91.
14. 2 in polymer electrolyte fuel cells. Inter J Hydrogen Energ 2010;35:6853-62.
15. Wu BH, Hu D, Kuang YJ, Liu B, Zhang XH, Chen JH. Functionalization of carbon nanotubes by an ionic-liquid polymer: dispersion of Pt and PtRu nanoparticles on carbon nanotubes and their electrocatalytic oxidation of methanol. Angew Chem Int Ed 2009;48:4751-4.
16. Pan D, Chen JH, Tao WY, Nie LH, Yao SZ. Polyoxometalate modified carbon nanotubes: new catalyst support for methanol electro-oxidation. Langmuir 2006;22:5872-6.
17. Hull RV, Li L, Xing YC, Chusuei CC. Pt nanoparticle binding on functionalized multiwalled carbon nanotubes. Chem Mater 2006;18:1780-8.
18. Yang DQ, Sun SH, Dodelet JP, Sacher E. A facile route for the self-organized high-density decoration of Pt nanoparticles on carbon nanotubes. J Phy Chem C 2008;112:11717-21.