Morphology and electrochemical performance of Li[Li0.2Mn 0.56Ni0.16Co0.08]O2cathode materials prepared with different metal sources

Electrochimica Acta

Volumn 109, Issue , 2013, Pages 828-834

  Shi, S J ^a   Tu, J P ^a   Zhang, Y D ^a   Zhang, Y J ^a   Gu, C D ^a   Wang, X L ^a  

^a ZHEJIANG UNIVERSITY   (China)

Author keywords

Lithium nickel cobalt manganese oxide; Metal source; Porosity; Sol gel

Indexed keywords

CATHODES; ELECTRIC DISCHARGES; ELECTRODES; LITHIUM; MANGANESE; MANGANESE OXIDE; METALS; MORPHOLOGY; NICKEL; POROSITY; SOL-GEL PROCESS;

CATH-ODE MATERIALS; DISCHARGE CAPACITIES; ELECTROCHEMICAL PERFORMANCE; HIGH SPECIFIC SURFACE AREA; LAYERED STRUCTURES; LITHIUM NICKEL COBALT MANGANESE OXIDES; METAL SOURCES; PARTICLE MORPHOLOGIES;

ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY;

EID: 84883079602     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2013.08.002     Document Type: Article

References (60)

1. L.J. Long, W. Jie, X.Y. Yao, A new rechargeable lithium-Ion battery with axLi2MnO3 L;1 xLi Mn0.4Ni0.4Co0.2O2 cathode and a hard carbon anode, Elec-Trochim. Acta 56 2011 7392.
2. Y.H. Wang, X.F. Bie, K. Nikolowski, Relationships betwe En structural changesand electrochemical kinetics of Li-Excess Li1.13Ni0.3Mn0.57O2during the firstcharge, J. Phys. Chem. C 117 2013 3279.
3. A. Ito, D. Li, Y. Sato, M. Arao, M. Watanabe, M. Hatano, H. Horie, Y. Ohsaw,CycLi C deterioration and its improvement for Li-Rich layered cathode material Li[Ni0.17Li0.2 co0.07Mn0.56]O2, J. Power Sources 195 2010 567.
4. J. Gao, J. Kim, A. Manthiram, High capacity Li[Li0.2Mn0.54Ni0.13Co0.13] O2-V2O5composite cathodes with low irreversible capacity loss for lithium ion batteries,Electrochem. Commun. 11 2009 84.
5. S.J. Shi, J.P. Tu, Y.J. Mai, Y.Q. Zhang, C.D. Gu, X.L. Wang, Effect of carbon coating onelectrochemical performance of Li1.048Mn0.381Ni0.286Co0.286O2 cathode materialfor lithium-Ion batteries, Electrochim. Acta 63 2012 112.
6. S.J. Shi, J.P. Tu, Y.Y. Tang, Y.X. Yu, Y.Q. Zhang, X.L. Wang, Sy Nthesis and electro-Chemical performance of Li1.131Mn0.504Ni0.243Co0.122O2 cathode materials forlithium ion batteries via fre Eze drying, J. Power Sources 221 2013 300.
7. J. Liu, B.R. Jayan, A. Manthiram, Conductive surface modification with aluminumof high capacity layered Li
8. Z. Li, F. Du, X.F. Bie, Electrochemical kinetics of the Li[Li0.23Co0.3Mn0.47]O2 cathode material studied by GITT and EIS, J. Phys. Chem. C 114 2010 22751
9. S.J. Shi, J.P. Tu, Y.Y. Tang, X.Y. Liu, Y.Q. Zhang, X.L. Wang, C.D. Gu, EnhancedcycLi Ng stability of Li [Li0.2Mn0.54Ni0.13Co0.13] O2by surface modification of MgOwith melting impregnation method Electrochim. Acta 88 2013 671
10. S.K. Martha, J. Nanda, G.M. Veith, N.J. Dudney, Electrochemical andrate performance study of high-Voltage lithium-Rich composition:Li1.2Mn0.525Ni0. 175Co0.1O2, J. Power Sources 199 2012 220.
11. J. Liu, Q.Y. Wang, B. Re Eja-Jayan, A. Manthiram, Carbon-Coated high capac-Ity layered Li[Li0.2Mn0.54Ni0.13Co0.13] O2 cathodes Electrochem. Commun. 12 2010 750.
12. C.J. Jafta, K.I. Ozoemen, M.K. Mathe, W.D. Roos, Sy Nthesis, characterisation andelectrochemical intercalation kinetics of nanostructured aluminium-DopedLi[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode material for lithium ion battery, Elec-Trochim. Acta 85 2012 411.
13. S.-H. Yu, T. Yoon, J.Y. Mun, S. Park, Y.-S. Kang, J.-H. Park, S.M. Oh, Y.-E. Sung, Continuous activation of Li2MnO3component upon cycLi Ng inLi1.167Ni0.233Co0.100Mn0.467Mo0.033O2 cathode material for lithium ion batteries,J. Mater. Chem. A 1 2013 2833.
14. F. Wu, H.Q. Lu, Y.F. Su, N. Li, L.Y. Bao, S. Chen, Preparation and electrochem-Ical performance of Li-Rich layered cathode material Li[Ni0.2Li0.2Mn0.6]O2forlithium-Ion batteries, J. Appl. Electrochem. 40 2010 783
15. J.H. Li M, H. Bang, K.S. Le E, K. Amine, Y.K. Sun, Electrochemical charac-Terization of Li2MnO3-Li[Ni1/3Co1/3Mn1/3]O2-Li NiO2 cathode sy Nthesized viaco-Precipitation for lithium secondary batteries, J. Power Sources 189 2009571.
16. S.H. Kang, M.M. Thackeray, Enhancing the rate capability of high capacityxLi2MnO31 xLi MO2M = Mn, Ni, Co electrodes by Li-Ni-PO4treatment, Electrochemistry Communications 11 2009 748.
17. C.S. Johnson, N. Li, C. Lefief, M.M. Thackeray, Anomalous capacity and cycLi Ngstability of xLi2MnO31 xLi MO2electrodes M = Mn Ni, Co in lithium bat-Teries at 50C, Electrochem. Commun. 9 2007 787.
18. Y. Wu, A. Manthiram, High capacity, surface-Modified layeredLi[Li1 x/3Mn2 x/3Nix/3Cox/3]O2 cathodes with low irreversible capacityloss Electrochem. Solid State Lett. 9 2006 A221
19. X.J. Guo, Y.X. Li, M. Zheng, J.M. Zheng, J. Li, Z.L. Gong, Y. Yang, Structural and elec-Trochemical characterization of xLi [Li1/3Mn2/3] O21 x Li[Ni1/3Mn1/3Co1/3] O20 x 0.9 as cathode materials for lithium ion batteries, J. Power Sources 184 2008 414.
20. W.C. West, J. Soler, B.V. Ratnakumar, Preparation of high quality layered-Layered composite Li2MnO3-Li MO2M = Ni, Mn, Co Li-Ion cathodes by a bal Lmil Li Ng-AnneaLi Ng, J. Power Sources 204 2012 200.
21. S.-H. Kang, P. Kempgens, S. Gre Enbaum, A.J. Kropf, K. Amine, M.M. Thack-Eray, Interpreting the structural and electrochemical complexity of 0.5Li2MnO30.5Li MO2electrodes for lithium batteries M = Mn0.5 xNi0.5 xCo2x, 0 x 0.5,J. Mater. Chem. 17 2007 2069.
22. S.J. Jin, K.S. Park, M.H. Cho, C.H. Song, A.M. Stephan, K.S. Nahm, Effect of com-Position change of metals in transition metal sites on electrochemical behaviorof layered Li[Co1 2xLi1/3Mn2/3xNi1/2Mn1/2x]O2solid solutions, Solid StateIonics 177 2006 105.
23. S.H. Kang, K. Amine, Electrochemical studies of the Si-Based composites withlarge capacity and good cycLi Ng stability as anode materials for rechargeablelithium ion batteries, J. Power Sources 146 2005 654.
24. J.M. Zheng, X.B. Wu, Y. Yang, A comparison of preparation method on the elec-Trochemical performance of cathode material Li[Li0.2Mn0.54Ni0.13Co0.13] O2forlithium ion battery, Electrochim. Acta 56 2011 3071.
25. S. Sivaprakash, S.B. Majumder, Spectroscopic analyses of0.5Li[Ni0.8Co0.15Zr0.05]O2-0.5Li O2-0.5Li[Li1/3Mn2/3]O2 composite cathodes for lithiumrechargeable batteries, Solid State Ionics 181 2010 730.
26. Y.J. Wei, K. Nikolowski, S.Y. Zhan, H. Ehrenberg, S. Oswald, G. Chen, C.Z.Wang, H. Chen, Electrochemical kinetics and cycLi Ng performance of nanoLi[Li0.23Co0.3Mn0.47]O2 cathode material for lithium ion batteries, Electrochem.Commun. 11 2009 2008.
27. A. Francis, K. Daniela, T. Michael, Z. Leila, G. Judith, L. Nicole, G. Gil,M. Boris, A. Doron, Sy Nthesis of integrated cathode materials xLi2MnO31 xLi Mn1/3Ni1/3Co1/3O2, x = 0.3, 0.5, 0.7 and studies of their electrochemicalbehavior, J. Electrochem. Soc. 157 2010 A1121.
28. G.-Y. Kim, S.-B. Yi, Y.J. Park, H.-G. Kim, Electrochemical behaviors of Li[Li1 x/3Mn2 x/3Nix/3Cox/3]O2 cathode series 0 < x < 1 sy Nthesized bysucrose combustion process for high capacity lithium ion batteries, Mater. Res.Bul L. 43 2008 3543.
29. S.J. Shi, J.P. Tu, Y.Y. Tang, Y.X. Yu, Y.Q. Zhang, X.L. Wang, C.D. Gu, Combustion sy N-Thesis and electrochemical performance of Li[Li0.2Mn0.54Ni0. 13Co0.13]O2withimproved rate capability, J. Power Sources 228 2013 14.
30. Q.W. Peng, Z.Y. Tang, L.Q. Zhang, X.J. Liu, Sy Nthesis of layeredLi1.2 + x[Ni0.25Mn0.75]0.8 xO2materials 0 x 4/55 via a new simplemicrowave heating method and their electrochemical properties, Mater.Res. Bul L.44 2009 2147
31. D. Kim, S.-H. Kang, M. Balasubramanian, C.S. Johnson, High-Energy andhigh-Power Li-Rich nickel manganese oxide electrode materials, Electrochem.Commun. 12 2010 1618.
32. F.Q. Wang, J. Chen, M.H. Wu, B.L. Yi, Propylene oxide-Assisted fast sol-Gel sy N-Thesis of mesoporous and nano-Structured LiFePO4/C cathode materials, Ionics19 2013 451.
33. Y.Q. Qiao, J.P. Tu, J.Y. Xiang, X.L. Wang, Y.J. Mai, D. Zhang, W.L. Liu, Effects ofsy Nthetic route on structure and electrochemical performance of Li3V2PO43/Ccathode materials, Electrochim. Acta 56 2011 4139.
34. H. Heli, H. Yadegari, A. Jabbari, A study of the lithium intercalation into nanopar-Ticles of Li CoO2from an aqueous solution, J. Appl. Electrochem. 42 2012279.
35. Y.L. Cui, W.J. Bao, Z. Yuan, Q.C. Zhuang, Z. Sun, Comparison of different softchemical routes sy Nthesis of submicro-Li Mn2O4 and their inf Luence on its elec-Trochemical properties, J. Solid State Electrochem. 16 2012 1551.
36. G.D. Bhuvaneswari, N. Kalaiselvi, Comparison of corn starch-Assisted sol-Geland combustion methods to prepare Li MnxCoy NizO2 compounds, J. Solid State Electrochem. 17 2013 9.
37. R. Santhanam, B. Rambabu, Improved high rate cycLi Ng of Li-RichLi1.10Ni1/3Co1/3Mn1/3O2 cathode for lithium batteries, Int. J. Electrochem.4 2009 1770.
38. C. Nithya, R. Thirunakaran, A. Sivashanmugam, G.V.M. Kiruthika, S. Gopukumar,High-Capacity sol-Gel sy Nthesis of Li NixCoy Mn1 x yO20
39. [CoNi1/2Mn1/2xLi1/3Mn2/31 2x]O2solid solutions with layered lithiummanganese oxides, J. Power Sources 146 2005 630.
40. D. Bhuvaneswari, N. Kalaiselvi, Surfactant-Coassisted sol-Gel sy Nthesis to pre-Pare Li Niy MnyCo1 2yO2with improved electrochemical behavior, J. Solid State Electrochem. 16 2012 3667.
41. T.L. Zhao, S. Chen, L. Li, X.F. Zhang, R.J. Chen, I. Belharouak, F. Wu, K.Amine, Sythesis, characterization, and electrochemistry of cathode material Li[Li0.2 co0.13Ni0.13Mn0.54] O2using organic chelating agents for lithium-Ion bat-Teries J. Power Sources 228 2013 206
42. S. Tan, Z.R. Zhang, Y.X. Li, Y. Li, J.M. Zheng, Z.B. Zhou, Y. Yang, Trishexaf Luoro-Iso-Propylphosphate as an SEI-Forming additive on improving the electrochemicalperformance of the Li[Li0.2Mn0.56Ni0.16Co0.08]O2 cathode material, J. Elec-Trochem. Soc. 160 2013 A285.
43. J.L. Liu, J. Wang, Y.Y. Xia, A new rechargeable lithium-Ion battery with axLi2MnO31 xLi Mn0.4Ni0.4Co0.2O2 cathode and a hard carbon anode, Elec-Trochim. Acta 56 2011 7392.
44. J. Li, R. Klöpsch, M.C. Stan, S. Nowak, M. Kunze, M. Winter, S. Passerini, Sy N-Thesis and electrochemical performance of the high voltage cathode material Li[Li0.2Mn0.56Ni0.16Co0.08]O2with improved rate capability, J. Power Sources196 2011 4821.
45. J.S. Kim, C.S. Johnson, J.T. Vaughey, M.M. Thackeray, S.A. Hackney, W.Yoon, C.P. Grey, Electrochemical and structural properties of xLi2MO31 xLi Mn0.5Ni0.5O2electrodes for lithium batteries M = Ti, Mn, Zr;0 x 0.3, Chem. Mater. 16 2004 1996.
46. W.S. Yoon, S. Iannopol Lo, C.P. Grey, D. Carlier, J. Gorman, J. Re Ed, G. Ceder,Local structure and cation ordering in O3lithium nickel manganese oxides withstoichiometry Li[NixMn2 x/3Li1 2x/3]O2NMR studies and first principles cal-Culations, Electrochem. Solid State Lett. 7 2004 A167.
47. S.H. Kang, M.M. Thackeray, C.S. Johnson, J.T. Vaughey, S.A. Hackney, Commentson the structural complexity of lithium-Rich Li1 + xM1 xO2electrodes M = Mn,Ni, Co for lithium batteries, Electrochem. Commun. 8 2006 1531.
48. C.X. Cheng, L. Tan, H.W. Liu, X.T. Huang, High rate performances of the cathodematerial Li Ni1/3Co1/3Mn1/3O2sy Nthesized using low temperature hydroxideprecipitation, Mater. Res. Bul L. 46 2011 2032.
49. A.M.A. Hashem, A.E. Abdel-Ghany, A.E. Eid, J. Trottier, K. Zaghib, A. Mauger,C.M. Julien, Study of the surface modification of Li Ni1/3Co1/3Mn1/3O2 cathodematerial for lithium ion battery, J. Power Sources 196 2011 8632.
50. N.N. Sinha, N. Munichandraiah, High rate capability of porousLi Ni1/3Co1/3Mn1/3O2sy Nthesized by poly Mer template route, J. Electrochem.Soc. 157 2010 A647.
51. M.M. Thackeray, S.H. Kang, C.S. Johnson, J.T. Vaughey, R. Benedek, S.A. Hackney,Li2MnO3-Stabilized Li MO2, M = Mn, Ni, Co electrodes for lithium-Ion batteries,J. Mater. Chem. 17 2007 3112.
52. C.S. Johnson, N. Li, C. Lefief, J.T. Vaughey, M.M. Thackeray, Sy Nthesis char-Acterization and electrochemistry of lithium battery electrodes: XLi2MnO31 xLi Mn0.333Ni0.333Co0.333O20 x 0.7, Chem. Mater. 20 2008 6095.
53. W. He, J.F. Qian, Y.L. Cao, X.P. Ai, H.X. Yang, Improved electrochemical per-Formances of nanocrystal Li Ne Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode material forLi-Ion batteries, RSC Adv. 2 2012 3423.
54. H. Sclar, D. Kovachev, E. Zhechev, R. Stoyanov, R. Lavi, G. Kimmel, J. Grinblat,O. Girshevitz, F. Amalraj, O. Haik, E. Zinigra, B. Markovsky, D. Aurbach, On theperformance of Li Ni1/3Mn1/3Co1/3O2nanoparticles as a cathode material forlithium-Ion batteries, J. Electrochem. Soc. 156 2009 A938.
55. J. Park, J.H. Seo, G. Plett, W. Lu, A.M. Sastry, Numerical simulation of the effectof the dissolution of Li Mn2O4particles on Li-Ion battery performance, Elec-Trochem. Solid State Lett. 14 2011 A14.
56. D.H. Jang, Y.J. Shin, S.M. Oh, Dissolution of spinel oxides and capacity losses in4 V Li/LixMn2O4cel Ls, J. Electrochem. Soc. 143 1996 2204.
57. M. Wohlfahrt-Mehrens, C. Vogler, J. Garche, Aging mechanisms of lithium cath-Ode materials, J. Power Sources 127 2004 58.
58. H.L. Hayley, Y. Naoaki, S.M. Ying, K. Sunde Ep, B. Julien, P.G. Clare, S.-H. Yang,Changes in the cation ordering of layered O3LixNi0.5Mn0.5O2during electro-Chemical cycLi Ng to high voltages: An electron diffraction study, Chem. Mater.19 2007 2551.
59. S.K. Hu, G.H. Cheng, M.Y. Cheng, B.J. Hwang, R. Santhanam, Cycle life improve-Ment of ZrO2-Coated spherical Li Ni1/3Co1/3Mn1/3O2 cathode material forlithium ion batteries, J. Power Sources 188 2009 564.
60. S.J. Shi, J.P. Tu, Y.Y. Tang, Y.Q. Zhang, X.L. Wang, C.D. Gu, Preparation andcharacterization of macroporous Li1.2Mn0.54Ni0.13Co0.13O2 cathode material forlithium-Ion batteries via aerogel template, J. Power Sources 240 2013 140.