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Volumn 42, Issue 36, 2013, Pages 13036-13047

Ring-opening polymerization of cyclic esters by phenoxy-thioether complexes derived from biocompatible metals

Author keywords

[No Author keywords available]

Indexed keywords

ESTERIFICATION; ESTERS; LIGANDS; MOLECULAR WEIGHT DISTRIBUTION; POLYMERIZATION; ZINC; ZINC COMPOUNDS;

EID: 84882773920     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/c3dt51219c     Document Type: Article
Times cited : (39)

References (61)
  • 41
    • 0037187847 scopus 로고    scopus 로고
    • The formation of alkoxide species was studied using NMR spectroscopy carrying out the reaction between 3 and 1 equiv. of iPrOH in benzene-d6 at room temperature. In spite of the complexity of the spectrum the formation of butane confirmed the occurrence of alcoholysis of the Mg(n-Bu) bond under these conditions
    • M. Save M. Schappacher A. Soum Macromol. Chem. Phys. 2002 203 889 899
    • (2002) Macromol. Chem. Phys. , vol.203 , pp. 889-899
    • Save, M.1    Schappacher, M.2    Soum, A.3
  • 47
    • 0035840262 scopus 로고    scopus 로고
    • The differences in terms of reactivity for Mg complexes were minimal also at room temperature. After 7 hours the conversions were 60%, 50% and 50% for complexes 3, 4 and 5, respectively
    • M. H. Chisholm J. C. Gallucci H. Zhen J. C. Huffmann Inorg. Chem. 2001 40 5051 5054
    • (2001) Inorg. Chem. , vol.40 , pp. 5051-5054
    • Chisholm, M.H.1    Gallucci, J.C.2    Zhen, H.3    Huffmann, J.C.4
  • 52
    • 0033653325 scopus 로고    scopus 로고
    • Longer induction periods, of about 40 minutes and 2 hours, were observed when the polymerization reactions were performed at lower temperature (50 and 25°C, respectively). After the induction time a linear dependence of ln [LA] vs. time was observed (see Fig. S15 and S16 in the ESI)
    • V. Simic S. Pensec N. Spassky Macromol. Symp. 2000 153 109 121
    • (2000) Macromol. Symp. , vol.153 , pp. 109-121
    • Simic, V.1    Pensec, S.2    Spassky, N.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.