Oxidation and reduction of mercury by SCR DeNOx catalysts under flue gas conditions in coal fired power plants

Applied Catalysis B: Environmental

Volumn 144, Issue , 2014, Pages 486-497

  Stolle, Raik ^a   Koeser, Heinz ^a   Gutberlet, Heinz ^b  

^a MARTIN LUTHER UNIVERSITY HALLE WITTENBERG   (Germany)

^b NONE

Author keywords

Induced reduction; Mercury emission control; Mercury oxidation; Mercury reduction; SCR DeNOx catalyst

Indexed keywords

AMMONIA; BROMINE COMPOUNDS; CATALYSTS; CHLORINE COMPOUNDS; COAL; EMISSION CONTROL; FLUE GASES; FOSSIL FUEL POWER PLANTS; GAS EMISSIONS; GAS PLANTS; HYDROGEN FUELS; MOLYBDENUM OXIDE; OXIDATION; VANADIUM PENTOXIDE;

COAL-FIRED POWER PLANT; DE-NOX CATALYSTS; FIRST ORDER REACTIONS; FLUE GAS DESULPHURISATION; MERCURY EMISSION CONTROL; MERCURY OXIDATIONS; MERCURY REDUCTION; OXIDATION AND REDUCTION;

MERCURY (METAL);

EID: 84882762794     PISSN: 09263373     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apcatb.2013.07.040     Document Type: Article

References (28)

1. UNEP Mercury fate and transport in the global atmosphere: measurements, models and policy implications, Interim Report of the UNEP Global Mercury Partnership 2008.
2. Krishnakumar B., Niksa S., Sloss L., Jozewics W., Futsaeter G. Energy Fuels 2012, 26:4624-4634.
3. Senior C.L. Journal of the Air & Waste Management Association 2006, 56:23-31.
4. Krishnakumar B., Helble J.J. Fuel Processing Technology 2012, 94:1-9.
5. Van Otten B., Buitrago P.A., Senior C.L., Silcox G.D. Energy Fuels 2011, 25:3530-3536.
6. Busca G., Lietti L., Ramis G., Berti F. Applied Catalysis B 1998, 18:1-36.
7. Hadzic A. Chemical & Biochemical Engineering 2010, 24:401-408.
8. Richardson C., Machalek T., Miller S., Dene C., Chang R. Journal of the Air & Waste Management Association 2002, 52:941-947.
9. Gutberlet H., Spiesberger A., Kastner F., Tembrink J. VGB Kraftwerkstechnik 1992, 72:636-641.
10. Presto A.A., Granite E.J. Environmental Science & Technology 2006, 40:5601-5609.
11. Dranga B.A., Lazar L., Koeser H. Catalysts 2012, 2:139-170.
12. Straube S., Hahn T., Koeser H. Applied Catalysis B 2008, 79:286-295.
13. Zhuang Y., Laumb J., Liggett R., Holmes M., Pavlish J. Fuel Processing Technology 2007, 88:929-934.
14. Yang H.M., Pan W.P. Journal of Environmental Sciences 2007, 19:181-184.
15. Lee C.W., Serre S.D., Zhao Y., Lee S.J., Hastings T.W. Journal of the Air & Waste Management Association 2008, 58:484-493.
16. Rallo M., Heidel B., Brechtel K., Maroto-Valer M.M. Chemical Engineering Journal 2012, 198-199:87-94.
17. Niksa S., Fujiwara N. Journal of the Air & Waste Management Association 2005, 55:1866-1875.
18. Niksa S., Sibley A.F. Industrial & Engineering Chemistry Research 2010, 49:6332-6341.
19. Madsen K., Jensen D.A., Frandsen J.F., Thogersen R.J. A mechanistic study on the inhibition of the DeNOx reaction on the mercury oxidation over SCR catalysts. Proceedings of Air Quality VIII Conference 2011.
20. Gutberlet H., Tembrink J. Dry sampling method used by E.ON for mercury speciation in flue gases. EPRI Workshop 2004.
21. VGB-Guideline 302 He: Guideline for the Testing of DENOX Catalysts 1998, VGB Technical Association of Large Power Plant Operators, Germany.
22. Nagayasu T., Nakashoji H., Imai N. VGB Power Tech 2011, 91(4):68-73.
23. Vosteen B.W., Winkler H., Berry M.S. Native halogens in coals from US, China, and elsewhere - low chlorine coals need bromide addition for enhanced mercury capture. A&WMAs Power Plant Air Pollutant Control MEGA Symposium 2010.
24. Vosteen B.W., Kanefke R., Koeser H. VGB Power Tech 2006, 86(3):70-75.
25. Tronconi E., Nova I., Ciardelli C., Chatterjee D., Weibel M. Journal of Catalysis 2007, 245:1-10.
26. Topsoe N.-Y., Dumesic J.A., Topsoe H. Journal of Catalysis 1995, 151:241-252.
27. Mars P., van Krevelen D.W. Chemical Engineering Science 1954, 3(Suppl. 1):41-59.
28. Witko M., Hermann K., Tokarz R. Catalysis Today 1999, 50:553-565.