An improved approach for measuring Henry's law coefficients of atmospheric organics

Atmospheric Environment

Volumn 79, Issue , 2013, Pages 561-565

  Kish, J Duncan ^a   Leng, Chunbo ^a,b   Kelley, Judas ^a   Hiltner, Joseph ^a   Zhang, Yunhong ^b   Liu, Yong ^a  

^a UNIVERSITY OF COLORADO   (United States)

^b BEIJING INSTITUTE OF TECHNOLOGY   (China)

Author keywords

Bubble column technique; Henry's law constant; Infrared gas cell; Ionic strength effect; Temperature dependence

Indexed keywords

ACADEMIC SEMESTER; DIFFERENT CLASS; ENVIRONMENTAL CHEMICALS; GAS CELL; HENRY'S LAW COEFFICIENT; HENRY'S LAW CONSTANT; TEMPERATURE DEPENDENCE; UNDERGRADUATE STUDENTS;

BUBBLE COLUMNS; IONIC STRENGTH; STUDENTS;

ATMOSPHERIC CHEMISTRY;

AROMATIC HYDROCARBON; BUTYLAMINE; ENVIRONMENTAL CHEMICAL; NITROGEN; TOLUENE;

ACADEMIC RESEARCH; ANALYTICAL FRAMEWORK; ATMOSPHERIC CHEMISTRY; HYDRATION; STUDENT;

ABSORPTION; ARTICLE; ATMOSPHERE; CONSTANTS AND COEFFICIENTS; FEASIBILITY STUDY; FLOW RATE; HYDROLYSIS; IONIC STRENGTH; LIQUID; MEASUREMENT; PRESSURE; PRIORITY JOURNAL; TEMPERATURE; VAPOR;

EID: 84881539339     PISSN: 13522310     EISSN: 18732844     Source Type: Journal    
DOI: 10.1016/j.atmosenv.2013.07.023     Document Type: Article

References (18)

1. Betterton E.A. Henry's law constants of soluble and moderately soluble organic gases: effects of aqueous phase chemistry. Advanced Environmental Science and Technology 1992, 24:41-50.
2. Betterton E.A., Hoffmann M.R. Henry's law constants of some environmentally important aldehydes. Environmental Science and Technology 1988, 22:1415-1418.
3. Couvidat F., Seigneur C. Modeling secondary organic aerosol formation from isoprene oxidation under dry and humid conditions. Atmospheric Chemistry and Physics 2011, 11:893-909.
4. Ge X., Wexler A.S., Clegg S.L. Atmospheric amines - part I. A review. Atmospheric Environment 2011, 45:524-546.
5. Ge X., Wexler A.S., Clegg S.L. Atmospheric amines-part II. Thermodynamic properties and gas/particle partitioning. Atmospheric Environment 2011, 45:561-577.
6. Hoff J.T., Mackay D., Gillham R., Shiu W.Y. Partitioning of organic chemicals at the air-water interface in environmental systems. Environmental Science and Technology 1993, 27:2174-2180.
7. Ip H.S.S., Huang X.H.H., Yu J.Z. Effective Henry's law constants of glyoxal, glyoxylic acid, and glycolic acid. Geophysical Research Letters 2009, 36:L01802.
8. Karl M., Tsigaridis K., Vignati E., Dentener F. Formation of secondary organic aerosol from isoprene over Europe. Atmospheric Chemistry and Physics 2009, 9:7003-7030.
9. Lee S.H., Mukherjee S., Brewer B., Ryan R., Yu H., Gangoda M. Alaboratory experiment to measure Henry's law constants of volatile organic compounds with a bubble column and a Gas Chromatography Flame lionization Detector (GC-FID). Journal of Chemical Education 2012, 90(4):495-499.
10. NIST Chemistry Web Book, NIST Standard Reference Database Number 69 2005, National Institute for Standard Technology (NIST), Gaithersburg, MD. P.J. Linstrom, W.G. Mallard (Eds.).
11. Mackay D., Shiu W.Y., Sutherland R.P. Determination of air-water Henry's law constants for hydrophobic pollutants. Environmental Science and Technology 1979, 13:333-337.
12. Mouchel-Vallon C., Brauer P., Camredon M., Valorso R., Madronich S., Herrmann H., Aumont B. Explicit modeling of volatile organic compounds partitioning in the atmospheric aqueous phase. Atmospheric Chemistry and Physics 2013, 13:1023-1037.
13. Roberts J.M. Measurement of the Henry's law coefficient and first order loss rate of PAN in n-octanol. Geophysical Research Letters 2005, 32:L08803.
14. Schwarzenbath R.P., Gschwend P.M., Imboden D.M. Environmental Organic Chemistry 2003, John Wiley, Hoboken, N. J. second ed.
15. Sfara V., Zerba E.N., Alzogaray R.A. Fumigant insecticidal activity and repellent effect of five essential oils and seven monoterpenes on first-instar nymphs of Rhodnius prolixus. Journal of Medical Entomology 2009, 46(3):511-515.
16. Staudinger J., Roberts P.V. Acritical review of Henry's law constants for environmental applications. Environmental Science and Technology 1996, 26:205-297.
17. Tilgner A., Herrmann H. Radical-driven carbonyl-to-acid conversion and acid degradation in tropospheric aqueous systems studied by capram. Atmospheric Environment 2010, 44:5415-5422.
18. Yaws C.L. Handbook of Properties for Environmental and Green Engineering: Adsorption Capacity, Water Solubility, Henry's Law Constant 2008, Gulf Publishing Company, Houston.