Role of oxygen holes in LixCoO2 revealed by soft X-ray spectroscopy

Physical Review Letters

Volumn 111, Issue 5, 2013, Pages

  Mizokawa, T ^a   Wakisaka, Y ^a   Sudayama, T ^a   Iwai, C ^b   Miyoshi, K ^b   Takeuchi, J ^b   Wadati, H ^a   Hawthorn, D G ^c   Regier, T Z ^d   Sawatzky, G A ^e  

^a UNIVERSITY OF TOKYO   (Japan)

^b SHIMANE UNIVERSITY   (Japan)

^c UNIVERSITY OF WATERLOO   (Canada)

^d CANADIAN LIGHT SOURCE INC   (Canada)

^e UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

BACK FLOW; BATTERY MATERIALS; ELECTRONIC CONDUCTIVITY; HOLE STATE; MIXED VALENCE; SOFT X-RAY; SOFT X-RAY ABSORPTION SPECTROSCOPIES; USED BATTERIES;

COBALT COMPOUNDS; ELECTRONIC STRUCTURE; LITHIUM; LITHIUM BATTERIES; OXYGEN; X RAY SPECTROSCOPY;

OXYGEN VACANCIES;

EID: 84881533516     PISSN: 00319007     EISSN: 10797114     Source Type: Journal    
DOI: 10.1103/PhysRevLett.111.056404     Document Type: Article

References (29)

1. K. Mizushima, P. C. Jones, P. J. Wiseman, and J. B. Goodenough, Mater. Res. Bull. 15, 783 (1980). MRBUAC 0025-5408 10.1016/0025-5408(80)90012-4 (Pubitemid 11434876)
2. J. Zaanen, G. A. Sawatzky, and J. W. Allen, Phys. Rev. Lett. 55, 418 (1985). PRLTAO 0031-9007 10.1103/PhysRevLett.55.418
3. A. E. Bocquet, T. Mizokawa, T. Saitoh, H. Namatame, and A. Fujimori, Phys. Rev. B 46, 3771 (1992). PRBMDO 0163-1829 10.1103/PhysRevB.46.3771
4. M. K. Aydinol, A. F. Kohan, G. Ceder, K. Cho, and J. Joannopoulos, Phys. Rev. B 56, 1354 (1997). PRBMDO 0163-1829 10.1103/PhysRevB.56.1354
5. A. K. Padhi, K. S. Nanjundaswamy, and J. B. Goodenough, J. Electrochem. Soc. 144, 1188 (1997). JESOAN 0013-4651 10.1149/1.1837571
6. K. Takada, H. Sakurai, E. Takayama-Muromachi, F. Izumi, R. A. Dilanian, and T. Sasaki, Nature (London) 422, 53 (2003). NATUAS 0028-0836 10.1038/nature01450 (Pubitemid 36323291)
7. I. Terasaki, Y. Sasago, and K. Uchinokura, Phys. Rev. B 56, R12685 (1997). PRBMDO 0163-1829 10.1103/PhysRevB.56.R12685
8. M. L. Foo, Y. Wang, S. Watauchi, H. W. Zandbergen, T. He, R. J. Cava, and N. P. Ong, Phys. Rev. Lett. 92, 247001 (2004). PRLTAO 0031-9007 10.1103/PhysRevLett.92.247001
9. E. Plichta, S. Slane, M. Uchiyama, M. Salomon, D. Chua, W. B. Ebner, and H. W. Lin, J. Electrochem. Soc. 136, 1865 (1989). JESOAN 0013-4651 10.1149/1.2097063
10. H. F. Gibbard, J. Power Sources 26, 81 (1989). JPSODZ 0378-7753 10.1016/0378-7753(89)80017-5
11. T. Nagaura and K. Tazawa, Prog. Batteries Sol. Cells 9, 20 (1990). PBASDR 0198-7259
12. A. Honders, J. M. der Kinderen, A. H. van Heeren, J. H. de Wit, and G. H. J. Broers, Solid State Ionics 14, 205 (1984). SSIOD3 0167-2738 10.1016/0167-2738(84)90100-0
13. J. Molenda, C. Delmas, P. Dordor, and A. Stoklosa, Solid State Ionics 12, 473 (1984). SSIOD3 0167-2738 10.1016/0167-2738(84)90180-2
14. M. Ménétrier, I. Saadoune, S. Levasseur, and C. Delmas, J. Mater. Chem. 9, 1135 (1999). JMACEP 0959-9428 10.1039/a900016j
15. J. van Elp, J. L. Wieland, H. Eskes, P. Kuiper, G. A. Sawatzky, F. M. F. de Groot, and T. S. Turner, Phys. Rev. B 44, 6090 (1991). PRBMDO 0163-1829 10.1103/PhysRevB.44.6090
16. M. T. Czyżyk, R. Potze, and G. A. Sawatzky, Phys. Rev. B 46, 3729 (1992). PRBMDO 0163-1829 10.1103/PhysRevB.46.3729
17. K. Miyoshi, C. Iwai, H. Kondo, M. Miura, S. Nishigori, and J. Takeuchi, Phys. Rev. B 82, 075113 (2010). PRBMDO 1098-0121 10.1103/PhysRevB.82.075113
18. T. Mizokawa and A. Fujimori, Phys. Rev. B 54, 5368 (1996). PRBMDO 0163-1829 10.1103/PhysRevB.54.5368
19. T. Mizokawa, L. H. Tjeng, P. G. Steeneken, N. B. Brookes, I. Tsukada, T. Yamamoto, and K. Uchinokura, Phys. Rev. B 64, 115104 (2001). PRBMDO 0163-1829 10.1103/PhysRevB.64.115104
20. W. B. Wu, D. J. Huang, J. Okamoto, A. Tanaka, H.-J. Lin, F. C. Chou, A. Fujimori, and C. T. Chen, Phys. Rev. Lett. 94, 146402 (2005). PRLTAO 0031-9007 10.1103/PhysRevLett.94.146402 (Pubitemid 40629859)
21. D. J. Singh, Phys. Rev. B 61, 13397 (2000). PRBMDO 0163-1829 10.1103/PhysRevB.61.13397
22. C. A. Marianetti, G. Kotliar, and G. Ceder, Nat. Mater. 3, 627 (2004). NMAACR 1476-1122 10.1038/nmat1178
23. O. E. Peil, A. Georges, and F. Lechermann, Phys. Rev. Lett. 107, 236404 (2011). PRLTAO 0031-9007 10.1103/PhysRevLett.107.236404
24. H.-J. Lin, Y. Y. Chin, Z. Hu, G. J. Shu, F. C. Chou, H. Ohta, K. Yoshimura, S. Hébert, A. Maignan, A. Tanaka, L. H. Tjeng, and C. T. Chen, Phys. Rev. B 81, 115138 (2010). PRBMDO 1098-0121 10.1103/PhysRevB.81.115138
25. T. Motohashi, T. Ono, Y. Sugimoto, Y. Masubuchi, S. Kikkawa, R. Kanno, M. Karppinen, and H. Yamauchi, Phys. Rev. B 80, 165114 (2009). PRBMDO 1098-0121 10.1103/PhysRevB.80.165114
26. S. Laubach, S. Laubach, P. C. Schmidt, D. Ensling, S. Schmid, W. Jaegermann, A. Thisen, K. Nikolowski, and H. Ehrenberge, Phys. Chem. Chem. Phys. 11, 3278 (2009). PPCPFQ 1463-9076 10.1039/b901200a
27. K. Ikedo, Y. Wakisaka, T. Mizokawa, C. Iwai, K. Miyoshi, and J. Takeuchi, Phys. Rev. B 82, 075126 (2010). PRBMDO 1098-0121 10.1103/PhysRevB.82.075126
28. A. Van der Ven, M. K. Aydinol, G. Ceder, G. Kresse, and J. Hafner, Phys. Rev. B 58, 2975 (1998). PRBMDO 0163-1829 10.1103/PhysRevB.58.2975
29. G. G. Amatucci, J. M. Tarascon, and L. C. Klein, J. Electrochem. Soc. 143, 1114 (1996). JESOAN 0013-4651 10.1149/1.1836594