Chemical profiling of triacylglycerols and diacylglycerols in cow milk fat by ultra-performance convergence chromatography combined with a quadrupole time-of-flight mass spectrometry

Food Chemistry

Volumn 143, Issue , 2014, Pages 199-204

  Zhou, Qin ^a   Gao, Boyan ^a   Zhang, Xi ^b   Xu, Yongwei ^b   Shi, Haiming ^a   Yu, Liangli ^a,c  

^a SHANGHAI JIAO TONG UNIVERSITY   (China)

^b WATERS CORPORATION   (United States)

^c UNIVERSITY OF MARYLAND   (United States)

Author keywords

Chromatography; Cow milk; Diacylglycerol; Quadrupole time of flight mass; Spectrometry; Triacylglycerol; Ultra performance convergence

Indexed keywords

CHROMATOGRAPHIC ANALYSIS; GLYCEROL; MASS SPECTROMETRY; OILS AND FATS; SPECTROMETRY;

COW MILK; DIACYLGLYCEROL; QUADRUPOLE-TIME OF FLIGHTS; TRIACYLGLYCEROLS; ULTRA-PERFORMANCE CONVERGENCE;

CHROMATOGRAPHY;

DIACYLGLYCEROL; HEXANOIC ACID; MILK FAT; MYRISTIC ACID; OLEIC ACID; ORGANIC SOLVENT; PALMITIC ACID; STEARIC ACID; TRIACYLGLYCEROL;

ANALYTIC METHOD; ARTICLE; LIPIDOMICS; MILK; POSITIVE ION ELECTROSPRAY; TIME OF FLIGHT MASS SPECTROMETRY; ULTRA PERFORMANCE LIQUID CHROMATOGRAPHY;

EID: 84881499950     PISSN: 03088146     EISSN: 18737072     Source Type: Journal    
DOI: 10.1016/j.foodchem.2013.07.114     Document Type: Article

References (18)

1. Fontecha, J., Goudjil, H., Ríos, J. J., Fraga, M. J., & Juárez, M. (2005). Identity of the major triacylglycerols in ovine milk fat. International Dairy Journal, 15, 1217-1224. (Pubitemid 41219216)
2. Fontecha, J., Ríos, J. J., Lozada, L., and Fraga., M. J., & Juárez, M. (2000). Composition of goat's milk fat triglycerides analysed by silver ion adsorption-TLC and GC-MS. International Dairy Journal, 10, 119-128. (Pubitemid 30627047)
3. Gastaldi, D., Medana, C., Giancotti, V., Aigotti, R., Dal Bello, F., & Baiocchi, C. (2011). HPLC-APCI analysis of triacylglycerols in milk fat from different sources. European Journal of Lipid Science and Technology, 113, 197-207.
4. Gourmel, C., Perrenoud, A. G. G., Waller, L., Reginato, E., Verne, J., Dulery, B., et al. (2013). Evaluation and comparison of various separation techniques for the analysis of closely-related compounds of pharmaceutical interest. Journal of Chromatography A, 1282, 172-177.
5. Haddad, I., Mozzon, M., Strabbioli, R., & Frega, N. G. (2011). Electrospray ionization tandem mass spectrometry analysis of triacylglycerols molecular species in camel milk (Camelus dromedarius). International Dairy Journal, 21, 119-127.
6. Jensen, R. G., and Ferris., A. M., & Lammi-Keefe, C. J. (1992). Lipids in human milk and infant formulas. Annual Review of Nutrition, 12, 417-441.
7. Kalo, P., Kemppinen, A., Ollilainen, V., & Kuksis, A. (2004). Regiospecific determination of short-chain triacylglycerols in butterfat by normal-phase HPLC with on-line electrospray-tandem mass spectrometry. Lipids, 39, 915-928. (Pubitemid 40030385)
8. Laakso, P., & Manninen, P. (1997). Identification of milk fat triacylglycerols by capillary supercritical fluid chromatography-atmospheric pressure chemical ionization mass spectrometry. Lipids, 32, 1285-1295. (Pubitemid 28018704)
9. Lee, J. W., Uchikata, T., Matsubara, A., Nakamura, T., Fukusaki, E., & Bamba, T. (2012). Application of supercritical fluid chromatography/mass spectrometry to lipid profiling of soybean. Journal of Bioscience and Bioengineering, 112, 262-268.
10. Leiker, T. J., and Barkley., R. M., & Murphy, R. C. (2011). Analysis of diacylglycerol molecular species in cellular lipid extracts by normal-phase LC-electrospray mass spectrometry. International Journal of Mass Spectometry, 305, 103-108.
11. Li, J. R., Li, M., Xia, B., Ding, L. S., Xu, H. X., & Zhou, Y. (2013). Efficient optimization of ultra-high-performance supercritical fluid chromatographic separation of Rosa sericea by response surface methodology. Journal of Separation Science, 36, 2114-2120.
12. MacGibbon, A. K. H., & Taylor, M. W. (2006). Composition and structure of bovine milk lipids. In P. F. Fox & P. L. H. McSweeney (Eds.) (3rd ed. Advanced dairy chemistry Volume 2 lipids (3rd ed.), pp. 1-42). New York: Springer.
13. n ion-trap MS. Journal of the American Oil Chemists' Society, 80, 195-202.
14. Mottram, H. R., & Evershed, R. P. (2001). Elucidation of the composition of bovine milk fat triacylglycerols using high-performance liquid chromatography-atmospheric pressure chemical ionisation mass spectrometry. Journal of Chromatography A, 926, 239-253. (Pubitemid 32744729)
15. Mottram, H. R., and Woodbury., S. E., & Evershed, R. P. (1997). Identification of triacylglycerol positional isomers present in vegetable oils by high perfomance liquid chromatography/atmospheric pressure chemical ionization mass spectrometry. Rapid Communications in Mass Spectrometry, 11, 1240-1252. (Pubitemid 27358282)
16. Park, J. S., & Jung, M. Y. (2012). Development of high-performance liquid chromatography-time-of-flight mass spectrometry for the simultaneous characterization and quantitative analysis of gingerol-related compounds in ginger products. Journal of Agricultural and Food Chemistry, 60, 10015-10026.
17. Perrenoud, A. G. G., Boccard, J., Veuthey, J. L., & Guillarme, D. (2012). Analysis of basic compounds by supercritical fluid chromatography: Attempts to improve peak shape and maintain mass spectrometry compatibility. Journal of ChromatographyA, 1262, 205-213.
18. Shi, H. M., and Yang., H. S., Zhang, X. W., Sheng, Y., Huang, H. Q., & Yu, L. L. (2012). Isolation and characterization of five glycerol esters from Wuhan propolis, and their potential anti-inflammatory properties. Journal of Agricultural and Food Chemistry, 60, 10041-10047.