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Volumn 113, Issue , 2014, Pages 169-177

Partial sulfonation of PVdF-co-HFP: A preliminary study and characterization for application in direct methanol fuel cell

Author keywords

Direct methanol fuel cell; Ion exchange capacity; Polymer electrolyte membrane; PVdF co HFP; Sulfonation

Indexed keywords

COPOLYMERS; DIRECT METHANOL FUEL CELLS (DMFC); ION EXCHANGE; POLYELECTROLYTES; PROTON CONDUCTIVITY;

EID: 84881486061     PISSN: 03062619     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apenergy.2013.07.030     Document Type: Article
Times cited : (123)

References (50)
  • 1
    • 84863157075 scopus 로고    scopus 로고
    • A modified Nafion membrane with extremely low methanol permeability via surface coating of sulfonated organic silica
    • Zhang Y., Cai W., Si F., Ge J., Liang L., Liu C., et al. A modified Nafion membrane with extremely low methanol permeability via surface coating of sulfonated organic silica. Chem Commun 2012, 48:2870-2872.
    • (2012) Chem Commun , vol.48 , pp. 2870-2872
    • Zhang, Y.1    Cai, W.2    Si, F.3    Ge, J.4    Liang, L.5    Liu, C.6
  • 2
    • 62649150322 scopus 로고    scopus 로고
    • Nafion/polyaniline composite membranes specifically designed to allow proton exchange membrane fuel cells operation at low humidity
    • Yang J., Shen P.K., Varcoe J., Wei Z. Nafion/polyaniline composite membranes specifically designed to allow proton exchange membrane fuel cells operation at low humidity. J Power Sources 2009, 189:1016-1019.
    • (2009) J Power Sources , vol.189 , pp. 1016-1019
    • Yang, J.1    Shen, P.K.2    Varcoe, J.3    Wei, Z.4
  • 3
    • 84861526388 scopus 로고    scopus 로고
    • Methanol sorption and permeability in Nafion and acid-doped PBI and ABPBI membranes
    • Diaz L.A., Abuin G.C., Corti H.R. Methanol sorption and permeability in Nafion and acid-doped PBI and ABPBI membranes. J Membr Sci 2012, 411-412:35-44.
    • (2012) J Membr Sci , pp. 35-44
    • Diaz, L.A.1    Abuin, G.C.2    Corti, H.R.3
  • 4
    • 71249148003 scopus 로고    scopus 로고
    • Design and characterisation of Nafion membranes with incorporated ionic liquids cations
    • Neves L.A., Benavente J., Coelhoso I.M., Crespo J.G. Design and characterisation of Nafion membranes with incorporated ionic liquids cations. J Membr Sci 2010, 347:42-52.
    • (2010) J Membr Sci , vol.347 , pp. 42-52
    • Neves, L.A.1    Benavente, J.2    Coelhoso, I.M.3    Crespo, J.G.4
  • 5
    • 84861079878 scopus 로고    scopus 로고
    • Recent development of polymer electrolyte membranes for fuel cells
    • Zhang H., Shen P.K. Recent development of polymer electrolyte membranes for fuel cells. Chem Rev 2012, 112:2780-2832.
    • (2012) Chem Rev , vol.112 , pp. 2780-2832
    • Zhang, H.1    Shen, P.K.2
  • 7
    • 79959458671 scopus 로고    scopus 로고
    • Cross-linking of side chain unsaturated aromatic polyethers for high temperature polymer electrolyte membrane fuel cell applications
    • Papadimitriou K.D., Paloukis F., Neophytides S.G., Kallitsis J.K. Cross-linking of side chain unsaturated aromatic polyethers for high temperature polymer electrolyte membrane fuel cell applications. Macromolecules 2011, 44:4942-4951.
    • (2011) Macromolecules , vol.44 , pp. 4942-4951
    • Papadimitriou, K.D.1    Paloukis, F.2    Neophytides, S.G.3    Kallitsis, J.K.4
  • 8
    • 77953667187 scopus 로고    scopus 로고
    • New fluorinated polymers bearing pendant phosphonic acid groups. Proton conducting membranes for fuel cell
    • Tayouo R., David G., Améduri B., Rozière J., Roualdès S. New fluorinated polymers bearing pendant phosphonic acid groups. Proton conducting membranes for fuel cell. Macromolecules 2010, 43:5269-5276.
    • (2010) Macromolecules , vol.43 , pp. 5269-5276
    • Tayouo, R.1    David, G.2    Améduri, B.3    Rozière, J.4    Roualdès, S.5
  • 9
  • 10
    • 33847031436 scopus 로고    scopus 로고
    • Study of basic biopolymer as proton membrane for fuel cell systems
    • Ramírez-Salgado J. Study of basic biopolymer as proton membrane for fuel cell systems. Electrochim Acta 2007, 52:3766-3778.
    • (2007) Electrochim Acta , vol.52 , pp. 3766-3778
    • Ramírez-Salgado, J.1
  • 11
    • 84874400052 scopus 로고    scopus 로고
    • A sandwich structured membrane for direct methanol fuel cells operating with neat methanol
    • Wu Q.X., Zhao T.S., Chen R., An L. A sandwich structured membrane for direct methanol fuel cells operating with neat methanol. Appl Energy 2013, 106:301-306.
    • (2013) Appl Energy , vol.106 , pp. 301-306
    • Wu, Q.X.1    Zhao, T.S.2    Chen, R.3    An, L.4
  • 13
    • 27844596792 scopus 로고    scopus 로고
    • TM electrolyte membranes under hydrated conditions
    • TM electrolyte membranes under hydrated conditions. Polymer 2005, 46:11707-11715.
    • (2005) Polymer , vol.46 , pp. 11707-11715
    • Kundu, S.1    Simon, L.C.2    Fowler, M.3    Grot, S.4
  • 14
    • 33750020827 scopus 로고    scopus 로고
    • On the decay of Nafion proton conductivity at high temperature and relative humidity
    • Casciola M., Alberti G., Sganappa M., Narducci R. On the decay of Nafion proton conductivity at high temperature and relative humidity. J Power Sources 2006, 162:141-145.
    • (2006) J Power Sources , vol.162 , pp. 141-145
    • Casciola, M.1    Alberti, G.2    Sganappa, M.3    Narducci, R.4
  • 15
    • 80055023326 scopus 로고    scopus 로고
    • A review on methanol crossover in direct methanol fuel cells: challenges and achievements
    • Ahmed M., Dincer I. A review on methanol crossover in direct methanol fuel cells: challenges and achievements. Int J Energy Res 2011, 35:1213-1228.
    • (2011) Int J Energy Res , vol.35 , pp. 1213-1228
    • Ahmed, M.1    Dincer, I.2
  • 16
    • 77955715433 scopus 로고    scopus 로고
    • Creep and stress-rupture of Nafion® membranes under controlled environment
    • Solasi R., Huang X., Reifsnider K. Creep and stress-rupture of Nafion® membranes under controlled environment. Mech Mater 2010, 42:678-685.
    • (2010) Mech Mater , vol.42 , pp. 678-685
    • Solasi, R.1    Huang, X.2    Reifsnider, K.3
  • 17
    • 78650607410 scopus 로고    scopus 로고
    • A review of polymer electrolyte membrane fuel cells: technology, applications, and needs on fundamental research
    • Wang Y., Chen K.S., Mishler J., Cho S.C., Adroher X.C. A review of polymer electrolyte membrane fuel cells: technology, applications, and needs on fundamental research. Appl Energy 2011, 88:981-1007.
    • (2011) Appl Energy , vol.88 , pp. 981-1007
    • Wang, Y.1    Chen, K.S.2    Mishler, J.3    Cho, S.C.4    Adroher, X.C.5
  • 18
    • 84884209900 scopus 로고    scopus 로고
    • Enabling high-concentrated fuel operation of fuel cells with microfluidic principles: a feasibility study
    • Zhang H., Xuan J., Xu H., Leung M.K.H., Leung D.Y.C., Zhang L., et al. Enabling high-concentrated fuel operation of fuel cells with microfluidic principles: a feasibility study. Appl Energy 2013, 10.1016/j.apenergy.2013.01.077.
    • (2013) Appl Energy
    • Zhang, H.1    Xuan, J.2    Xu, H.3    Leung, M.K.H.4    Leung, D.Y.C.5    Zhang, L.6
  • 19
    • 77953130226 scopus 로고    scopus 로고
    • A study on the overall efficiency of direct methanol fuel cell by methanol crossover current
    • Seo S.H., Lee C.S. A study on the overall efficiency of direct methanol fuel cell by methanol crossover current. Appl Energy 2010, 87:2597-2604.
    • (2010) Appl Energy , vol.87 , pp. 2597-2604
    • Seo, S.H.1    Lee, C.S.2
  • 20
    • 9344253337 scopus 로고    scopus 로고
    • Characteristics of PVdF copolymer/Nafion blend membrane for direct methanol fuel cell (DMFC)
    • Cho K.-Y., Eom J.-Y., Jung H.-Y., Choi N.-S., Lee Y.M., Park J.-K., et al. Characteristics of PVdF copolymer/Nafion blend membrane for direct methanol fuel cell (DMFC). Electrochim Acta 2004, 50:583-588.
    • (2004) Electrochim Acta , vol.50 , pp. 583-588
    • Cho, K.-Y.1    Eom, J.-Y.2    Jung, H.-Y.3    Choi, N.-S.4    Lee, Y.M.5    Park, J.-K.6
  • 21
    • 0037879278 scopus 로고    scopus 로고
    • Chemically-modified Nafion®/poly(vinylidene fluoride) blend ionomers for proton exchange membrane fuel cells
    • Song M.-K., Kim Y.-T., Fenton J.M., Kunz H.R., Rhee H.-W. Chemically-modified Nafion®/poly(vinylidene fluoride) blend ionomers for proton exchange membrane fuel cells. J Power Sources 2003, 117:14-21.
    • (2003) J Power Sources , vol.117 , pp. 14-21
    • Song, M.-K.1    Kim, Y.-T.2    Fenton, J.M.3    Kunz, H.R.4    Rhee, H.-W.5
  • 23
    • 4243192295 scopus 로고    scopus 로고
    • Nafion-Nafion/polyvinylidene fluoride-Nafion laminated polymer membrane for direct methanol fuel cells
    • Kim H.J., Kim H.J., Shul Y.G., Han H.S. Nafion-Nafion/polyvinylidene fluoride-Nafion laminated polymer membrane for direct methanol fuel cells. J Power Sources 2004, 135:66-71.
    • (2004) J Power Sources , vol.135 , pp. 66-71
    • Kim, H.J.1    Kim, H.J.2    Shul, Y.G.3    Han, H.S.4
  • 24
    • 33748086054 scopus 로고    scopus 로고
    • Preparation and characteristics of Nafion membrane coated with a PVdF copolymer/recast Nafion blend for direct methanol fuel cell
    • Cho K.-Y., Jung H.-Y., Sung K.A., Kim W.-K., Sung S.-J., Park J.-K., et al. Preparation and characteristics of Nafion membrane coated with a PVdF copolymer/recast Nafion blend for direct methanol fuel cell. J Power Sources 2006, 159:524-528.
    • (2006) J Power Sources , vol.159 , pp. 524-528
    • Cho, K.-Y.1    Jung, H.-Y.2    Sung, K.A.3    Kim, W.-K.4    Sung, S.-J.5    Park, J.-K.6
  • 25
    • 79955807711 scopus 로고    scopus 로고
    • Progress in the production and modification of PVDF membranes
    • Liu F., Hashim N.A., Liu Y., Abed M.R.M., Li K. Progress in the production and modification of PVDF membranes. J Membr Sci 2011, 375:1-27.
    • (2011) J Membr Sci , vol.375 , pp. 1-27
    • Liu, F.1    Hashim, N.A.2    Liu, Y.3    Abed, M.R.M.4    Li, K.5
  • 26
    • 33344472604 scopus 로고    scopus 로고
    • Proton exchange membranes based on PVDF/SEBS blends
    • Mokrini A., Huneault M.A. Proton exchange membranes based on PVDF/SEBS blends. J Power Sources 2006, 154:51-58.
    • (2006) J Power Sources , vol.154 , pp. 51-58
    • Mokrini, A.1    Huneault, M.A.2
  • 27
    • 0000136635 scopus 로고    scopus 로고
    • Thermal stability of styrene grafted and sulfonated proton conducting membranes based on poly(vinylidene fluoride)
    • Hietala S., Koel M., Skou E., Elomaa M., Sundholm F. Thermal stability of styrene grafted and sulfonated proton conducting membranes based on poly(vinylidene fluoride). J Mater Chem 1998, 8:1127-1132.
    • (1998) J Mater Chem , vol.8 , pp. 1127-1132
    • Hietala, S.1    Koel, M.2    Skou, E.3    Elomaa, M.4    Sundholm, F.5
  • 28
    • 77149154019 scopus 로고    scopus 로고
    • Irradiated PVdF-HFP-tin oxide composite membranes for the applications of direct methanol fuel cells
    • Kumar G.G., Shin J., Nho Y.-C., seon Hwang I., Fei G., Kim A.R., et al. Irradiated PVdF-HFP-tin oxide composite membranes for the applications of direct methanol fuel cells. J Membr Sci 2010, 350:92-100.
    • (2010) J Membr Sci , vol.350 , pp. 92-100
    • Kumar, G.G.1    Shin, J.2    Nho, Y.-C.3    seon Hwang, I.4    Fei, G.5    Kim, A.R.6
  • 30
    • 84875839112 scopus 로고    scopus 로고
    • Robust, self-healing superamphiphobic fabrics prepared by two-step coating of fluoro-contaning polymer, fluoroalkyl silane, and modified silica nanoparticles
    • Zhou H., Wang H., Niu H., Gestos A., Lin T. Robust, self-healing superamphiphobic fabrics prepared by two-step coating of fluoro-contaning polymer, fluoroalkyl silane, and modified silica nanoparticles. Adv Funct Mater 2012, 10.1002/adfm.201202030.
    • (2012) Adv Funct Mater
    • Zhou, H.1    Wang, H.2    Niu, H.3    Gestos, A.4    Lin, T.5
  • 31
    • 84870223471 scopus 로고    scopus 로고
    • The effect of sulfonated graphene oxide on sulfonated poly(ether ether ketone) membrane for direct methanol fuel cells
    • Heo Y., Im H., Kim J. The effect of sulfonated graphene oxide on sulfonated poly(ether ether ketone) membrane for direct methanol fuel cells. J Membr Sci 2012, 10.1016/j.memsci.2012.09.019.
    • (2012) J Membr Sci
    • Heo, Y.1    Im, H.2    Kim, J.3
  • 32
    • 47249140480 scopus 로고    scopus 로고
    • Synthesis and properties of sulfonated poly[bis(benzimidazobenzisoquinolinones)] as hydrolytically and thermooxidatively stable proton conducting ionomers
    • Li N., Zhang S., Liu J., Zhang F. Synthesis and properties of sulfonated poly[bis(benzimidazobenzisoquinolinones)] as hydrolytically and thermooxidatively stable proton conducting ionomers. Macromolecules 2008, 41:4165-4172.
    • (2008) Macromolecules , vol.41 , pp. 4165-4172
    • Li, N.1    Zhang, S.2    Liu, J.3    Zhang, F.4
  • 33
    • 77957713044 scopus 로고    scopus 로고
    • Sulfonated PEEK and fluorinated polymer based blends for fuel cell applications: investigation of the effect of type and molecular weight of the fluorinated polymers on the membrane's properties
    • Inan T.Y., Doǧan H., Unveren E.E., Eker E. Sulfonated PEEK and fluorinated polymer based blends for fuel cell applications: investigation of the effect of type and molecular weight of the fluorinated polymers on the membrane's properties. Int J Hydrogen Energy 2010, 35:12038-12053.
    • (2010) Int J Hydrogen Energy , vol.35 , pp. 12038-12053
    • Inan, T.Y.1    Doǧan, H.2    Unveren, E.E.3    Eker, E.4
  • 34
    • 34548256755 scopus 로고    scopus 로고
    • Formation and evaluation of semi-IPN of Nafion 117 membrane for direct methanol fuel cell 1. Crosslinked sulfonated polystyrene in the pores of Nafion 117
    • Kundu P.P., Kim B.T., Ahn J.E., Han H.S., Shul Y.G. Formation and evaluation of semi-IPN of Nafion 117 membrane for direct methanol fuel cell 1. Crosslinked sulfonated polystyrene in the pores of Nafion 117. J Power Sources 2007, 171:86-91.
    • (2007) J Power Sources , vol.171 , pp. 86-91
    • Kundu, P.P.1    Kim, B.T.2    Ahn, J.E.3    Han, H.S.4    Shul, Y.G.5
  • 35
    • 76849084276 scopus 로고    scopus 로고
    • Preparation and properties of cross-linked sulfonated poly(arylene ether sulfone)/sulfonated polyimide blend membranes for fuel cell application
    • Bi H., Wang J., Chen S., Hu Z., Gao Z., Wang L., et al. Preparation and properties of cross-linked sulfonated poly(arylene ether sulfone)/sulfonated polyimide blend membranes for fuel cell application. J Membr Sci 2010, 350:109-116.
    • (2010) J Membr Sci , vol.350 , pp. 109-116
    • Bi, H.1    Wang, J.2    Chen, S.3    Hu, Z.4    Gao, Z.5    Wang, L.6
  • 36
    • 26844468484 scopus 로고    scopus 로고
    • Photo-cross-linking of sulfonated styrene-ethylene-butylene copolymer membranes for fuel cells
    • Chen S.-L., Benziger J.B., Bocarsly A.B., Zhang T. Photo-cross-linking of sulfonated styrene-ethylene-butylene copolymer membranes for fuel cells. Ind Eng Chem Res 2005, 44:7701-7705.
    • (2005) Ind Eng Chem Res , vol.44 , pp. 7701-7705
    • Chen, S.-L.1    Benziger, J.B.2    Bocarsly, A.B.3    Zhang, T.4
  • 37
    • 34248188108 scopus 로고    scopus 로고
    • Blend membranes based on disulfonated poly(aryl ether ether ketone)s (SPEEK) and poly(amide imide) (PAI) for direct methanol fuel cell usages
    • Zhao C., Wang Z., Bi D., Lin H., Shao K., Fu T., et al. Blend membranes based on disulfonated poly(aryl ether ether ketone)s (SPEEK) and poly(amide imide) (PAI) for direct methanol fuel cell usages. Polymer 2007, 48:3090-3097.
    • (2007) Polymer , vol.48 , pp. 3090-3097
    • Zhao, C.1    Wang, Z.2    Bi, D.3    Lin, H.4    Shao, K.5    Fu, T.6
  • 38
    • 84881510279 scopus 로고    scopus 로고
    • Sulfonated polyarylethersulfones. US Patent# 3,709,841.
    • Quentin J-P. Sulfonated polyarylethersulfones. US Patent# 3,709,841.
    • Quentin, J.-P.1
  • 39
    • 76649086333 scopus 로고    scopus 로고
    • Crosslinked sulfonated poly(bis-A)-sulfones as proton exchange membrane for PEM fuel cell application
    • Yu J., Dong C., Liu J., Li C., Fang J., Guan R. Crosslinked sulfonated poly(bis-A)-sulfones as proton exchange membrane for PEM fuel cell application. J Mater Sci 2010, 45:1017-1024.
    • (2010) J Mater Sci , vol.45 , pp. 1017-1024
    • Yu, J.1    Dong, C.2    Liu, J.3    Li, C.4    Fang, J.5    Guan, R.6
  • 40
    • 67649413070 scopus 로고    scopus 로고
    • Novel sulfonated poly(arylene ether ketone) copolymers bearing carboxylic or benzimidazole pendant groups for proton exchange membranes
    • Lin H., Zhao C., Cui Z., Ma W., Fu T., Na H., et al. Novel sulfonated poly(arylene ether ketone) copolymers bearing carboxylic or benzimidazole pendant groups for proton exchange membranes. J Power Sources 2009, 193:507-514.
    • (2009) J Power Sources , vol.193 , pp. 507-514
    • Lin, H.1    Zhao, C.2    Cui, Z.3    Ma, W.4    Fu, T.5    Na, H.6
  • 41
    • 33847723987 scopus 로고    scopus 로고
    • Synthesis of sulfonated polybenzimidazoles from functionalized monomers: preparation of ionic conducting membranes
    • Jouanneau J., Mercier R., Gonon L., Gebel G. Synthesis of sulfonated polybenzimidazoles from functionalized monomers: preparation of ionic conducting membranes. Macromolecules 2007, 40:983-990.
    • (2007) Macromolecules , vol.40 , pp. 983-990
    • Jouanneau, J.1    Mercier, R.2    Gonon, L.3    Gebel, G.4
  • 42
    • 36348990242 scopus 로고    scopus 로고
    • Single-step synthesis of sulfonated polyoxadiazoles and their use as proton conducting membranes
    • Gomes D., Roeder J., Ponce M.L., Nunes S.P. Single-step synthesis of sulfonated polyoxadiazoles and their use as proton conducting membranes. J Power Sources 2008, 175:49-59.
    • (2008) J Power Sources , vol.175 , pp. 49-59
    • Gomes, D.1    Roeder, J.2    Ponce, M.L.3    Nunes, S.P.4
  • 43
    • 0030566147 scopus 로고    scopus 로고
    • Sulfonated polyphosphazene ion-exchange membranes
    • Wycisk R., Pintauro P.N. Sulfonated polyphosphazene ion-exchange membranes. J Membr Sci 1996, 119:155-160.
    • (1996) J Membr Sci , vol.119 , pp. 155-160
    • Wycisk, R.1    Pintauro, P.N.2
  • 44
    • 84889654820 scopus 로고    scopus 로고
    • Enhanced performance of direct methanol fuel cells: a study on the combined effect of various supporting electrolytes, flow channel designs and operating temperatures
    • Kumar P., Dutta K., Kundu P.P. Enhanced performance of direct methanol fuel cells: a study on the combined effect of various supporting electrolytes, flow channel designs and operating temperatures. Int J Energy Res 2013, 10.1002/er.3034.
    • (2013) Int J Energy Res
    • Kumar, P.1    Dutta, K.2    Kundu, P.P.3
  • 45
    • 50949098848 scopus 로고    scopus 로고
    • Comparison of homogeneously and heterogeneously sulfonated polyetheretherketone membranes in preparation, properties and cell performance
    • Do K.N.T., Kim D. Comparison of homogeneously and heterogeneously sulfonated polyetheretherketone membranes in preparation, properties and cell performance. J Power Sources 2008, 185:63-69.
    • (2008) J Power Sources , vol.185 , pp. 63-69
    • Do, K.N.T.1    Kim, D.2
  • 46
    • 77955476452 scopus 로고    scopus 로고
    • A novel visible spectrophotometric method for the determination of methanol using sodium nitroprusside as spectroscopic probe
    • Zhan Y.-Y., Zhang Y., Li Q.-M., Du X.-Z. A novel visible spectrophotometric method for the determination of methanol using sodium nitroprusside as spectroscopic probe. J Chin Chem Soc 2010, 57:230-235.
    • (2010) J Chin Chem Soc , vol.57 , pp. 230-235
    • Zhan, Y.-Y.1    Zhang, Y.2    Li, Q.-M.3    Du, X.-Z.4
  • 47
    • 84881508481 scopus 로고    scopus 로고
    • Processes for preparation of sulfonated polyaniline compositions and uses thereof
    • US Patent# 5,093,439.
    • Epstein AJ, Yue J. Processes for preparation of sulfonated polyaniline compositions and uses thereof. US Patent# 5,093,439.
    • Epstein, A.J.1    Yue, J.2
  • 48
    • 0035889814 scopus 로고    scopus 로고
    • Gas permeation properties of poly(amide-6-b-ethylene oxide)-silica hybrid membranes
    • Kim J.H., Lee Y.M. Gas permeation properties of poly(amide-6-b-ethylene oxide)-silica hybrid membranes. J Membr Sci 2001, 193:209-225.
    • (2001) J Membr Sci , vol.193 , pp. 209-225
    • Kim, J.H.1    Lee, Y.M.2
  • 49
    • 34548253107 scopus 로고    scopus 로고
    • Ionic cluster size distributions of swollen Nafion/sulfated β-cyclodextrin membranes characterized by nuclear magnetic resonance cryoporometry
    • Jeon J.-D., Kwak S.-Y. Ionic cluster size distributions of swollen Nafion/sulfated β-cyclodextrin membranes characterized by nuclear magnetic resonance cryoporometry. J Phys Chem B 2007, 111:9437-9443.
    • (2007) J Phys Chem B , vol.111 , pp. 9437-9443
    • Jeon, J.-D.1    Kwak, S.-Y.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.