Polycyclic aromatic hydrocarbons (PAH), soot and light gases formed in the pyrolysis of acetylene at different temperatures: Effect of fuel concentration

Journal of Analytical and Applied Pyrolysis

Volumn 103, Issue , 2013, Pages 126-133

  Sánchez, Nazly E ^a   Millera, Ángela ^a   Bilbao, Rafael ^a   Alzueta, María U ^a  

^a UNIVERSITY OF ZARAGOZA   (Spain)

Author keywords

Acetylene pyrolysis; Gas chromatography mass spectrometry (GC MS); Light gases; Polycyclic aromatic hydrocarbons (PAH); Soot

Indexed keywords

ACETYLENE; BENZENE; DUST; ENVIRONMENTAL PROTECTION AGENCY; GAS CHROMATOGRAPHY; GASES; HYDROGEN; LIGHTING; MASS SPECTROMETRY; PYROLYSIS; SOOT;

ACETYLENE PYROLYSIS; CONCENTRATION OF PRODUCTS; GAS CHROMATOGRAPHY-MASS SPECTROMETRIES (GC-MS); HYDROGEN CONCENTRATION; MAXIMUM CONCENTRATIONS; POLYCYCLIC AROMATIC HYDROCARBON (PAH); REACTANT CONCENTRATIONS; REACTION TEMPERATURE;

POLYCYCLIC AROMATIC HYDROCARBONS;

EID: 84881263677     PISSN: 01652370     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jaap.2012.10.027     Document Type: Conference Paper

References (48)

1. 10 hydrocarbon products of catechol pyrolysis Energy and Fuels 22 2008 976 986
2. 2 pyrolysis Industrial and Engineering Chemistry Research 46 2007 7550 7560
3. 2 pyrolysis Chemical Engineering Journal 127 2007 1 9
4. C. Gardner, G.N. Greaves, G.K. Hargrave, S. Jarvis, P. Wildman, F. Meneau, W. Bras, and G. Thomas In situ measurements of soot formation in simple flames using small angle X-ray scattering Nuclear Instruments and Methods in Physics Research Section B 238 2005 334 339
5. B.J. Finlayson-Pitts, and J.N. Pitts Chemistry of the Upper and Lower Atmosphere first ed. 2000 Academic Press California
6. A. Lunch Polycyclic aromatic hydrocarbon-induced carcinogenesis - an introduction A. Lunch, The Carcinogenic Effects of Polycyclic Aromatic Hydrocarbons 2004 Imperial College Press Cambridge 1 18
7. U.S. Environmental Protection Agency Team, Health assessment document for diesel engine exhaust, National Center for Environmental Assessment, Report N: EPA/600/8-90/057F, Environmental Protection Agency (EPA), 2002, Washington, DC.
8. M. Ochsenkuhn-Petropouiou, K. Staikos, G. Matuschek, and A. Kettrup On-line determination of polycyclic aromatic hydrocarbons in airborne particulate matter by using pyrolysis/GC-MS Journal of Analytical and Applied Pyrolysis 70 2003 73 85
9. A.B. Ross, S. Junyapoon, J.M. Jones, A. Williams, and K.D. Bartle A study of different soots using pyrolysis-GC-MS and comparison with solvent extractable material Journal of Analytical and Applied Pyrolysis 74 2005 494 501
10. N.E. Sánchez, A. Callejas, A. Millera, R. Bilbao, and M.U. Alzueta Formation of PAH and soot during acetylene pyrolysis at different gas residence times and reaction temperatures Energy 43 2012 30 36
11. M. Frenklach, and H. Wang Detailed modeling of soot particle nucleation and growth Proceedings of the Combustion Institute 23 1991 1559 1566
12. H. Wang, and M. Frenklach Calculations of rate coefficients for chemically activated reactions of acetylene with vinylic and aromatic radicals Journal of Physical Chemistry 98 1994 11465 11489
13. G.L. Agafonov, V.N. Smirnov, and P.A. Vlasov Shock tube and modeling study of soot formation during the pyrolysis and oxidation of a number of aliphatic and aromatic hydrocarbons Proceedings of the Combustion Institute 33 2011 625 632
14. N. Hansen, J.A. Miller, T. Kasper, K. Kohse-Höinghaus, P.R. Westmoreland, J. Wang, and T.A. Cool Benzene formation in premixed fuel-rich 1,3-butadiene flames Proceedings of the Combustion Institute 32 2009 623 630
15. M. Frenklach On surface growth mechanism of soot particles Proceedings of the Combustion Institute 26 1996 2285 2293
16. M. Frenklach Reaction mechanism of soot formation in flames Physical Chemistry Chemical Physics 4 2002 2028 2037
17. H. Wang, D.X. Du, C.J. Sung, and C.K. Law Experiments and numerical simulation on soot formation in opposed-jet ethylene diffusion flames Proceedings of the Combustion Institute 26 1996 2359 2368
18. H. Böhm, H. Jander, and D. Tanke PAH growth and soot formation in the pyrolysis of acetylene and benzene at high temperatures and pressures: modeling and experiment Proceedings of the Combustion Institute 27 1998 1605 1612
19. T. Mendiara, M.P. Domene, A. Millera, R. Bilbao, and M.U. Alzueta An experimental study of the soot formed in the pyrolysis of acetylene Journal of Analytical and Applied Pyrolysis 74 2005 486 493
20. K. Norinaga, O. Deutschmann, N. Saegusa, and J. Hayashi Analysis of pyrolysis products from light hydrocarbons and kinetic modeling for growth of polycyclic aromatic hydrocarbons with detailed chemistry Journal of Analytical and Applied Pyrolysis 86 2009 148 160
21. Y. Li, Z. Tian, L. Zhang, T. Yuan, K. Zhang, B. Yang, and F. Qi An experimental study of the rich premixed ethylbenzene flame at low pressure Proceedings of the Combustion Institute 32 2009 647 655
22. 2 hydrocarbons Combustion and Flame 121 2000 122 136
23. 4 pyrolysis at different temperatures Journal of Analytical and Applied Pyrolysis 79 2007 244 251
24. A.M. Mastral, J.M. López, M.S. Callén, T. García, R. Murillo, and M.V. Navarro Spatial and temporal PAH concentrations in Zaragoza, Spain Science of the Total Environment 307 2003 111 124
25. J.C. Chuang, W.H. Steve, and N. Wilson Field comparison of polyurethane foam and XAD-2 resin for air sampling for polynuclear aromatic hydrocarbons Environmental Science and Technology 21 1987 798 804
26. N.E. Sánchez, A. Callejas, A. Millera, R. Bilbao, and M.U. Alzueta Polycyclic aromatic hydrocarbon (PAH) and soot formation in the pyrolysis of acetylene and ethylene: Effect of the Reaction temperature Energy and Fuels 26 2012 4823 4829
27. U.S. Environmental Protection Agency, Soxhlet Extraction, Method 3540C, Available at http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/3540c.pdf.
28. U.S. Environmental Protection Agency, Determination of semivolatile organic compounds by gas chromatography/mass spectrometry (CG/MS), Method 8270D, Available at http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/8270d.pdf.
29. C. Esarte, A. Millera, R. Bilbao, and M.U. Alzueta Gas and soot products formed in the pyrolysis of acetylene-ethanol blends under flow reactor conditions Fuel Processing Technology 90 2009 496 503
30. P.A. Tesner, and S.V. Shurupov Soot formation during pyrolysis of napthalene anthracene, pyrene Combustion Science and Technology 126 1997 139 151
31. R.D. Kern, and K. Xie Shock tube studies of gas phase reactions preceding the soot formation process Progress in Energy and Combustion Science 17 1991 191 210
32. A.V. Krestinin, M.B. Kislov, A.V. Raevskii, O.I. Kolesova, and L.N. Stesik On the mechanism of soot particle formation Kinetics and Catalysis 41 2000 90 98
33. H. Oruga Pyrolysis of acetylene behind shock waves Bulletin of the Chemical Society of Japan 50 1977 1044 1050
34. A. Comandini, T. Malewicki, and K. Brezinsky Chemistry of polycyclic aromatic hydrocarbons formation from phenyl radical pyrolysis and reaction of phenyl and acetylene Journal of Physical Chemistry A 116 2012 2409 2434
35. S.C. Moldoveanu Pyrolysis of Organic Molecules with Applications to Health and Environmental Issue first ed. 2010 Elsevier Amsterdam
36. K. Norinaga, V.M. Janardhanan, and O. Deutschmann Detailed chemical kinetic modeling of pyrolysis of ethylene acetylene, and propylene at 1073-1373 K with a plug-flow reactor model International Journal of Chemical Kinetics 40 2008 199 208
37. K. Norinaga, and O. Deutschmann Detailed kinetic modeling of gas-phase reactions in the chemical vapour deposition of carbon from light hydrocarbons Industrial and Engineering Chemistry Research 46 2007 3547 3557
38. J.A. Miller, and C.F. Melius Kinetic and thermodynamic issues in the formation of aromatic compounds in flames of aliphatic fuels Combustion and Flame 91 1992 21 39
39. J.A. Miller Theory and Modeling in Combustion Chemistry, Combustion Research Facility 1996 Sandia National Laboratories Livermore, CA
40. G.L. Agafonov, I. Naydenova, P.A. Vlasov, and J. Warnatz Detailed kinetic modeling of soot formation in shock tube pyrolysis and oxidation of toluene and n-heptane Proceedings of the Combustion Institute 31 2007 575 583
41. G.L. Agafonov, P.A. Vlasov, and V.N. Smirnov Soot formation in the pyrolysis of benzene methylbenzene, and ethylbenzene in shock waves Kinetics and Catalysis 52 2011 358 370
42. N.D. Marsh, E.B. Ledesma, A.K. Sandrowitz, and M.J. Wornat Yield of polycyclic aromatic hydrocarbons from the pyrolysis of catechol [ortho-dihydroxybenzene]: temperature and residence time effects Energy and Fuels 18 2004 209 217
43. G.L. Agafonov, A.A. Borisov, V.N. Smirnov, K.Y. Troshin, P.A. Vlasov, and J. Warnatz Soot formation during pyrolysis of methane and rich methane/oxygen mixtures behind reflected shock waves Combustion Science and Technology 180 2008 1876 1899
44. J.A. Mulholland, L. Mingming, and D.-H. Ki Pyrolytic growth of polycyclic aromatic hydrocarbons by cyclopentadienyl moieties Proceedings of the Combustion Institute 28 2000 2593 2599
45. Z.A. Mansurov Soot formation in combustion processes (review) Combustion, Explosion, and Shock Waves 41 2005 727 744
46. H. Böhm, and H. Jander PAH formation in acetylene-benzene pyrolysis Physical Chemistry Chemical Physics 1 1999 3775 3781
47. R. Wang, and P. Cadman Soot and PAH production from spray combustion of different hydrocarbons behind reflected shock waves Combustion and Flame 112 1998 359 370
48. H. Richter, S. Granata, W.H. Green, and J.B. Howard Detailed modeling of PAH and soot formation in a laminar premixed benzene/oxygen/argon/low-pressure flame Proceedings of the Combustion Institute 30 2005 1397 1405