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Volumn 5, Issue 8, 2013, Pages 2395-2404

Enantioselective merger of aminocatalysis with π-Lewis Acid Metal Catalysis: Asymmetric Preparation of Carbo- and Heterocycles

Author keywords

Aldehydes; Alkynes; Asymmetric catalysis; Metal catalysis; Organocatalysis

Indexed keywords

ALKYNES; ASYMMETRIC CATALYSIS; ASYMMETRIC PREPARATION; ENANTIOSELECTIVE PREPARATION; ENANTIOSELECTIVE SYNTHESIS; HETEROCYCLIC STRUCTURES; METAL CATALYSIS; ORGANOCATALYSIS;

EID: 84880939693     PISSN: 18673880     EISSN: 18673899     Source Type: Journal    
DOI: 10.1002/cctc.201300313     Document Type: Article
Times cited : (29)

References (69)
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    • The absolute stereochemistry of the major enantiomer of pyrrolidines 6a-6j was attributed by analogy to cyclopentanes.
    • The absolute stereochemistry of the major enantiomer of pyrrolidines 6a-6j was attributed by analogy to cyclopentanes.
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    • The intervention of an enol-type mechanism has been ruled out because the use of a chiral primary amine instead of cyclohexylamine significantly affected the enantioselectivity outcome of the reaction (see the Supporting Information).
    • The intervention of an enol-type mechanism has been ruled out because the use of a chiral primary amine instead of cyclohexylamine significantly affected the enantioselectivity outcome of the reaction (see the Supporting Information).
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    • 2 coordination of the terminal alkyne to copper(I) complexes, see:
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    • 2 coordination of the terminal alkyne to copper(I) complexes, see:
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    • The cis stereochemistry of 8a was determined on the basis of NOESY experiments (see the Supporting Information for more details).
    • The cis stereochemistry of 8a was determined on the basis of NOESY experiments (see the Supporting Information for more details).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.