In situ transmission electron microscopy study of electrochemical lithiation and delithiation cycling of the conversion anode RuO2

ACS Nano

Volumn 7, Issue 7, 2013, Pages 6354-6360

  Gregorczyk, Keith E ^a   Liu, Yang ^b   Sullivan, John P ^b   Rubloff, Gary W ^a  

^a UNIVERSITY OF MARYLAND   (United States)

^b SANDIA NATIONAL LABORATORIES   (United States)

Author keywords

conversion electrode; energy storage; in situ transmission electron microscopy; ruthenium dioxide

Indexed keywords

ELECTROCHEMICAL LITHIATION; IN-SITU TRANSMISSION ELECTRON MICROSCOPIES; INTERMEDIATE PHASE; MODEL MATERIALS; NANOSTRUCTURED NETWORKS; RUTHENIUM DIOXIDE; SIGNIFICANT SURFACES; THEORETICAL CAPACITY;

ENERGY STORAGE; IN SITU PROCESSING; LITHIUM; NANOWIRES; REACTION INTERMEDIATES; TRANSMISSION ELECTRON MICROSCOPY;

RUTHENIUM ALLOYS;

LITHIUM; NANOMATERIAL; RUTHENIUM DERIVATIVE; RUTHENIUM TETRAOXIDE; RUTHENIUM TETROXIDE;

CHEMISTRY; DEVICE FAILURE ANALYSIS; DEVICES; ELECTROCHEMISTRY; ELECTRODE; EQUIPMENT DESIGN; MATERIALS TESTING; PARTICLE SIZE; PROCEDURES; SURFACE PROPERTY; TRANSMISSION ELECTRON MICROSCOPY; ULTRASTRUCTURE; ARTICLE; EQUIPMENT; EQUIPMENT FAILURE; METHODOLOGY;

ELECTROCHEMISTRY; ELECTRODES; EQUIPMENT DESIGN; EQUIPMENT FAILURE ANALYSIS; LITHIUM; MATERIALS TESTING; MICROSCOPY, ELECTRON, TRANSMISSION; NANOSTRUCTURES; PARTICLE SIZE; RUTHENIUM COMPOUNDS; SURFACE PROPERTIES;

EID: 84880789333     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn402451s     Document Type: Article

References (39)

1. Liu, X. H.; Liu, Y.; Kushima, A.; Zhang, S. L.; Zhu, T.; Li, J.; Huang, J. Y. In Situ TEM Experiments of Electrochemical Lithiation and Delithiation of Individual Nanostructures Adv. Energy Mater. 2012, 2, 722-741
2. Liu, X. H.; Huang, J. Y. In Situ TEM Electrochemistry of Anode Materials in Lithium Ion Batteries Energy Environ. Sci. 2011, 4, 3844-3860
3. 2 Nanowire Electrode Science 2010, 330, 1515-1520
4. 2 Nanowires in a Flooding Geometry Phys. Rev. Lett. 2011, 106
5. 2 Nanowires Micron 2012, 43, 1127-1133
6. 2 Nanowire during Lithium Intercalation Nano Lett. 2011, 11, 1874-1880
7. Zhang, L. Q.; Liu, X. H.; Liu, Y.; Huang, S.; Zhu, T.; Gui, L. J.; Mao, S. X.; Ye, Z. Z.; Wang, C. M.; Sullivan, J. P. et al. Controlling the Lithiation-Induced Strain and Charging Rate in Nanowire Electrodes by Coating ACS Nano 2011, 5, 4800-4809
8. Liu, X. H.; Wang, J. W.; Huang, S.; Fan, F. F.; Huang, X.; Liu, Y.; Krylyuk, S.; Yoo, J.; Dayeh, S. A.; Davydov, A. V. et al. In Situ Atomic-Scale Imaging of Electrochemical Lithiation in Silicon Nat. Nanotechnol. 2012, 7, 749-756
9. Liu, X. H.; Zhong, L.; Huang, S.; Mao, S. X.; Zhu, T.; Huang, J. Y. Size-Dependent Fracture of Silicon Nanoparticles during Lithiation ACS Nano 2012, 6, 1522-1531
10. Liu, N.; Wu, H.; Mcdowell, M. T.; Yao, Y.; Wang, C. M.; Cui, Y. A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes Nano Lett. 2012, 12, 3315-3321
11. Karki, K.; Epstein, E.; Cho, J. H.; Jia, Z.; Li, T.; Picraux, S. T.; Wang, C. S.; Cumings, J. Lithium-Assisted Electrochemical Welding in Silicon Nanowire Battery Electrodes Nano Lett. 2012, 12, 1392-1397
12. Mcdowell, M. T.; Ryu, I.; Lee, S. W.; Wang, C. M.; Nix, W. D.; Cui, Y. Studying the Kinetics of Crystalline Silicon Nanoparticle Lithiation with In Situ Transmission Electron Microscopy Adv. Mater. 2012, 24, 6034-6041
13. Liu, X. H.; Zheng, H.; Zhong, L.; Huan, S.; Karki, K.; Zhang, L. Q.; Liu, Y.; Kushima, A.; Liang, W. T.; Wang, J. W. et al. Anisotropic Swelling and Fracture of Silicon Nanowires during Lithiation Nano Lett. 2011, 11, 3312-3318
14. Liu, X. H.; Huang, S.; Picraux, S. T.; Li, J.; Zhu, T.; Huang, J. Y. Reversible Nanopore Formation in Ge Nanowires during Lithiation-Delithiation Cycling: An In Situ Transmission Electron Microscopy Study Nano Lett. 2011, 11, 3991-3997
15. 3 Layers during Lithiation-Delithiation Cycles Nano Lett. 2011, 11, 4188-4194
16. Liu, X. H.; Wang, J. W.; Liu, Y.; Zheng, H.; Kushima, A.; Huang, S.; Zhu, T.; Mao, S. X.; Li, J.; Zhang, S. L. et al. In Situ Transmission Electron Microscopy of Electrochemical Lithiation, Delithiation and Deformation of Individual Graphene Nanoribbons Carbon 2012, 50, 3836-3844
17. Liu, Y.; Zheng, H.; Liu, X. H.; Huang, S.; Zhu, T.; Wang, J. W.; Kushima, A.; Hudak, N. S.; Huang, X.; Zhang, S. L. et al. Lithiation-Induced Embrittlement of Multiwalled Carbon Nanotubes ACS Nano 2011, 5, 7245-7253
18. Kushima, A.; Liu, X. H.; Zhu, G.; Wang, Z. L.; Huang, J. Y.; Li, J. Leapfrog Cracking and Nanoamorphization of ZnO Nanowires during In Situ Electrochemical Lithiation Nano Lett. 2011, 11, 4535-4541
19. Liao, H. W.; Karki, K.; Zhang, Y.; Cumings, J.; Wang, Y. H. Interfacial Mechanics of Carbon Nanotube@Amorphous-Si Coaxial Nanostructures Adv. Mater. 2011, 23, 4318-4322
20. Wang, J. W.; Liu, X. H.; Zhao, K. J.; Palmer, A.; Patten, E.; Burton, D.; Mao, S. X.; Suo, Z. G.; Huang, J. Y. Sandwich-Lithiation and Longitudinal Crack in Amorphous Silicon Coated on Carbon Nanofibers ACS Nano 2012, 6, 9158-9167
21. Gu, M.; Li, Y.; Li, X. L.; Hu, S. Y.; Zhang, X. W.; Xu, W.; Thevuthasan, S.; Baer, D. R.; Zhang, J. G.; Liu, J. et al. In Situ TEM Study of Lithiation Behavior of Silicon Nanoparticles Attached to and Embedded in a Carbon Matrix ACS Nano 2012, 6, 8439-8447
22. Ruzmetov, D.; Oleshko, V. P.; Haney, P. M.; Lezec, H. J.; Karki, K.; Baloch, K. H.; Agrawal, A. K.; Davydov, A. V.; Krylyuk, S.; Liu, Y. et al. Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries Nano Lett. 2012, 12, 505-511
23. Cabana, J.; Monconduit, L.; Larcher, D.; Palacin, M. R. Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting through Conversion Reactions Adv. Mater. 2010, 22, E170-E192
24. Wang, X.; Tang, D. M.; Li, H. Q.; Yi, W.; Zhai, T. Y.; Bando, Y.; Golberg, D. Revealing the Conversion Mechanism of CuO Nanowires during Lithiation-Delithiation by In Situ Transmission Electron Microscopy Chem. Commun. 2012, 48, 4812-4814
25. Wang, F.; Yu, H. C.; Chen, M. H.; Wu, L.; Perieira, N.; Thorton, K.; Van Der Ven, A.; Zhu, Y.; Amatucci, G. G.; Graetz, J. Tracking Lithium Transport and Electrochemical Reactions in Nanoparticles Nat. Commun. 2012, 3, 1201
26. 2 with High Capacity Adv. Funct. Mater. 2003, 13, 621-625
27. Haynes, W. M. CRC Handbook of Chemistry and Physics; CRC Press: Boca Raton, FL, 2013; Vol. 93.
28. 2 Adv. Mater. 2008, 20, 501-505
29. Balaya, P.; Bhattacharyya, A. J.; Jamnik, J.; Zhukovskii, Y. F.; Kotomin, E. A.; Maier, J. Nano-Ionics in the Context of Lithium Batteries J. Power Sources 2006, 159, 171-178
30. 2-Li System Phys. Chem. Chem. Phys. 2009, 11, 6424-6429
31. Zhukovskii, Y. F.; Balaya, P.; Kotomin, E. A.; Maier, J. Evidence for Interfacial-Storage Anomaly in Nanocomposites for Lithium Batteries from First-Principles Simulations Phys. Rev. Lett. 2006, 96, 058302
32. 2 Nanowires with One- and Two-Nanocontact Electrical Characterizations Appl. Phys. Lett. 2007, 90, 013105
33. Neupane, S.; Kaganas, G.; Valenzuela, R.; Kumari, L.; Wang, X. W.; Li, W. Z. Synthesis and Characterization of Ruthenium Dioxide Nanostructures J. Mater. Sci. 2011, 46, 4803-4811
34. 2 Nanorods on Sapphire Substrates J. Phys.: Condens. Matter 2004, 16, 8475-8484
35. Liu, D. R.; Williams, D. B. The Electron-Energy-Loss Spectrum of Lithium Metal Philos. Mag. B 1986, 53, L123-L128
36. Wang, F.; Graetz, J.; Moreno, M. S.; Ma, C.; Wu, L. J.; Volkov, V.; Zhu, Y. M. Chemical Distribution and Bonding of Lithium in Intercalated Graphite: Identification with Optimized Electron Energy Loss Spectroscopy ACS Nano 2011, 5, 1190-1197
37. 2 Thin Films J. Appl. Phys. 1997, 82, 1730-1735
38. Zashkvar, V.; Redkin, V. S.; Korsunsk, M. Characteristic Electron Energy-Loss Spectrum for Ruthenium Fiz. Tverd. Tela 1970, 11, 1944
39. 2 Nanowire by Polarized Raman Spectroscopy Appl. Phys. Lett. 2010, 96, 213108