Quantification of gas-phase glyoxal and methylglyoxal via the Laser-Induced Phosphorescence of (methyl)GLyOxal Spectrometry (LIPGLOS) Method

Atmospheric Measurement Techniques

Volumn 5, Issue 1, 2012, Pages 181-192

  Henry, S B ^a   Kammrath, A ^a,b   Keutsch, F N ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

^b KIMBERLY CLARK CORPORATION   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; ATMOSPHERIC CHEMISTRY; CALIBRATION; INSTRUMENTATION; MEASUREMENT METHOD; MOLECULAR ANALYSIS; NUMERICAL MODEL; SPECIATION (CHEMISTRY); SPECTROMETRY; TROPOSPHERE; VOLATILE ORGANIC COMPOUND; WAVELENGTH;

EID: 84880764828     PISSN: 18671381     EISSN: 18678548     Source Type: Journal    
DOI: 10.5194/amt-5-181-2012     Document Type: Article

References (37)

1. Chan, A. W. H., Galloway, M. M., Kwan, A. J., Chhabra, P. S., Keutsch, F. N., Wennberg, P. O., Flagan, R. C., and Seinfeld, J. H.: Photooxidation of 2-Methyl-3-Buten-2-ol (MBO) as a Potential Source of Secondary Organic Aerosol, Envir. Sci. Tech., 43, 4647-4652, 2009.
2. Dub́e, W. P., Brown, S. S., Osthoff, H. D., Nunley, M. R., Ciciora, S. J., Paris, M. W., McLaughlin, R. J., and Ravishankara, A. R.: Aircraft instrument for simultaneous, in situ measurement of NO3 and N2O5 via pulsed cavity ring-down spectroscopy, Rev. Sci. Instrum., 77, 034101, doi:10.1063/1.2176058, 2006.
3. Fu, T.-M., Jacob, D. J., Wittrock, F., Burrows, J., Vrekoussis, M., and Henze, D.: Global budgets of atmospheric glyoxal and methylglyoxal, and implications for formation of secondary organic aerosols, J. Geophys. Res., 113, D15303, doi:10.1029/2007JD009505, 2008.
4. Galloway, M. M., Chhabra, P. S., Chan, A. W. H., Surratt, J. D., Flagan, R. C., Seinfeld, J. H., and Keutsch, F. N.: Glyoxal uptake on ammonium sulphate seed aerosol: reaction products and reversibility of uptake under dark and irradiated conditions, Atmos. Chem. Phys., 9, 3331-3345, doi:10.5194/acp-9-3331- 2009, 2009.
5. Galloway, M. M., Huisman, A. J., Yee, L. D., Chan, A.W. H., Loza, C. L., Seinfeld, J. H., and Keutsch, F. N.: Yields of oxidized volatile organic compounds during the OH radical initiated oxidation of isoprene, methyl vinyl ketone, and methacrolein under high-NOx conditions, Atmos. Chem. Phys., 11, 10779-10790, doi:10.5194/acp-11-10779-2011, 2011.
6. Guenther, A., Hewitt, C., Erickson, D., Fall, R., Geron, C., Graedel, T., Harley, P., Klinger, L., Lerdau, M., Mckay, W., Pierce, T., Scholes, B., Steinbrecher, R., Tallamaraju, R., Taylor, J., and Zimmerman, P.: A global model of natural volatile organiccompound emissions, J. Geophys. Res.-Atmos., 100, 8873-8392, 1995.
7. Hallquist, M., Wenger, J. C., Baltensperger, U., Rudich, Y., Simpson, D., Claeys, M., Dommen, J., Donahue, N. M., George, C., Goldstein, A. H., Hamilton, J. F., Herrmann, H., Hoffmann, T., Iinuma, Y., Jang, M., Jenkin, M. E., Jimenez, J. L., Kiendler-Scharr, A., Maenhaut, W., McFiggans, G., Mentel, Th. F., Monod, A., Pŕev̂ot, A. S. H., Seinfeld, J. H., Surratt, J. D., Szmigielski, R., and Wildt, J.: The formation, properties and impact of secondary organic aerosol: current and emerging issues, Atmos. Chem. Phys., 9, 5155-5236, doi:10.5194/acp-9-5155-2009, 2009.
8. Ho, S. S. H. and Yu, J. Z.: Determination of airborne carbonyls: Comparison of a thermal desorption/GC method with the standard DNPH/HPLC method, Environ. Sci. Technol, 38, 862-870, 2004.
9. Horowitz, A., Meller, R., and Moortgat, G. K.: The UVVIS absorption cross sections of the-dicarbonyl compounds: pyruvic acid, biacetyl and glyoxal, J. Photoch. Photobio. A, 146, 19-27, 2001.
10. Huisman, A. J., Hottle, J. R., Coens, K. L., DiGangi, J. P., Galloway, M. M., Kammrath, A., and Keutsch, F. N.: Laser-induced phosphorescence for the in situ detection of glyoxal at part per trillion mixing ratios, Anal. Chem., 80, 5884-5891, 2008.
11. Isaksen, I. S. A., Granier, C., Myhre, G., Berntsen, T. K., Dalsøren, S. B., Gauss, M., Klimont, Z., Benestad, R., Bousquet, P., Collins, W., Cox, T., Eyring, V., Fowler, D., Fuzzi, S., J̈ockel, P., Laj, P., Lohmann, U., Maione, M., Monks, P., Prevot, A. S. H., Raes, F., Richter, A., Rognerud, B., Schulz, M., Shindell, D., Stevenson, D. S., Storelvmo, T., Wang, W. C., van Weele, M., Wild, M., and Wuebbles, D.: Atmospheric composition change: Climate-Chemistry interactions, Atmos. Environ., 43, 5138-5192, 2009.
12. Kroll, J. H., Ng, N. L., Murphy, S. M., Varutbangkul, V., Flagan, R. C., and Seinfeld, J. H.: Chamber studies of secondary organic aerosol growth by reactive uptake of simple carbonyl compounds, J. Geophys. Res.-Atmos, 110, D23207, doi:10.1029/2005JD006004, 2005.
13. Lee, Y.-N., Zhou, X., and Hallock, K.: Atmospheric carbonyl compounds at a rural southeastern United States site, J. Geophys. Res., 100, 25933-25944, 1995.
14. Lippmann, M.: Health effects of tropospheric ozone, Environ. Sci. Technol., 25, 1954-1962, 1991.
15. Lohmann, U. and Feichter, J.: Global indirect aerosol effects: a review, Atmos. Chem. Phys., 5, 715-737, doi:10.5194/acp-5-715-2005, 2005.
16. Meller, R., Raber, W., Crowley, J. N., Jenkin, M. E., and Moortgat, G. K.: The UV-visible absorption spectrum of methylglyoxal, J. Photoch. Photobio. A, 62, 163-171, 1991.
17. Munger, J. W., Jacob, D. J., Daube, B. C., Horowitz, L. W., Keene, W. C., and Heikes, B. G.: Formaldehyde, glyoxal, and methylglyoxal in air and cloudwater at a rural mountain site in central Virginia, J. Geophys. Res., 100, 9325-9333, 1995.
18. O'Keefe, A. and Deacon, D. A. G.: Cavity Ring-down Optical Spectrometer for Absorption-Measurements Using Pulsed Laser Sources, Rev. Sci. Instrum., 59, 2544-2551, 1988.
19. Osthoff, H. D., Brown, S. S., Ryerson, T. B., Fortin, T. J., Lerner, B. M., Williams, E. J., Pettersson, A., Baynard, T., Dub, W. P., Ciciora, S. J., and Ravishankara, A. R.: Measurement of atmospheric NO2 by pulsed cavity ring-down spectroscopy, J. Geophys. Res., 111, D12305, doi:10.1029/2005JD006942, 2006.
20. Paulot, F., Crounse, J. D., Kjaergaard, H. G., Kroll, J. H., Seinfeld, J. H., and Wennberg, P. O.: Isoprene photooxidation: new insights into the production of acids and organic nitrates, Atmos. Chem. Phys., 9, 1479-1501, doi:10.5194/acp-9-1479-2009, 2009.
21. Sinreich, R., Coburn, S., Dix, B., and Volkamer, R.: Ship-based detection of glyoxal over the remote tropical Pacific Ocean, Atmos. Chem. Phys., 10, 11359-11371, 2010, http://www.atmos-chem-phys.net/10/11359/2010/.
22. Spaulding, R. S., Schade, G. W., Goldstein, A. H., and Charles, M. J.: Characterization of secondary atmospheric photooxidation products: Evidence for biogenic and anthropogenic sources, J. Geophys. Res.-Atmos, 108, D4247, doi:10.1029/2002JD002478, 2003.
23. Stieb, D. M., Beveridge, R. C., Brook, J. R., Smith-Doiron, M., Burnett, R. T., Dales, R. E., Beaulieu, S., Judek, S., and Mamedov, A.: Air pollution, aeroallergens and cardiorespiratory emergency department visits in Saint John, Canada, J. Expo. Anal. Env. Epid., 10, 461-477, 2000.
24. Thalman, R. and Volkamer, R.: Inherent calibration of a blue LED-CE-DOAS instrument to measure iodine oxide, glyoxal, methyl glyoxal, nitrogen dioxide, water vapour and aerosol extinction in open cavity mode, Atmos. Meas. Tech., 3, 1797-1814, doi:10.5194/amt-3-1797-2010, 2010.
25. Tuazon, E. C., Atkinson, R., Mac Leod, H., Biermann, H. W., Winer, A. M., Carter, W. P. L., and Pitts, J. N.: Yields of glyoxal and methylglyoxal from the nitrogen oxide(NOx)-air photooxidations of toluene and m-and p-xylene, Envir. Sci. Tech., 18, 981-984, 1984.
26. Turro, N. J. and Engel, R.: Quenching of Biacetyl Fluorescence and Phosphorescence, J. Am. Chem. Soc., 91, 7113-7121, 1969.
27. US EPA, Center for Environmental Research Information, Research and Development: Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, TO-11A, Center for Environmental Research Information, National Risk Management Laboratory, Office of Research and Development, US EPA, Cincinnati, OH, 2nd edn., 1999.
28. Volkamer, R., Molina, L. T., Molina, M. J., Shirley, T., and Brune, W. H.: DOAS measurement of glyoxal as an indicator for fast VOC chemistry in urban air, Geophys. Res. Lett., 32, L08806, doi:10.1029/2005GL022616, 2005a.
29. Volkamer, R., Platt, U., and Wirtz, K.: Primary and Secondary Glyoxal Formation from Aromatics: Experimental Evidence for the BicycloalkylRadical Pathway from Benzene, Toluene, and p-Xylene, J. Phys. Chem. A, 105, 7865-7874, 2005b.
30. Volkamer, R., Spietz, P., Burrows, J., and Platt, U.: High-resolution absorption cross-section of glyoxal in the UV-vis and IR spectral ranges, J. Photoch. Photobio. A, 172, 35-46, 2005c.
31. Volkamer, R., San Martinti, F., Molina, L. T., Salcedo, D., Jimenez, J., and Molina, M. J.: A missing sink for gas-phase glyoxal in Mexico City: Formation of secondary organic aerosol, Geophys. Res. Lett., 34, L19807, doi:10.1029/2007GL030752, 2007.
32. Vrekoussis, M., Wittrock, F., Richter, A., and Burrows, J. P.: Temporal and spatial variability of glyoxal as observed from space, Atmos. Chem. Phys., 9, 4485-4504, 2009, http://www.atmos-chem-phys.net/9/4485/2009/.
33. Vrekoussis, M., Wittrock, F., Richter, A., and Burrows, J. P.: GOME-2 observations of oxygenated VOCs: what can we learn from the ratio glyoxal to formaldehyde on a global scale?, Atmos. Chem. Phys., 10, 10145-10160, doi:10.5194/acp-10-10145-2010, 2010.
34. Washenfelder, R. A., Langford, A. O., Fuchs, H., and Brown, S. S.: Measurement of glyoxal using an incoherent broadband cavity enhanced absorption spectrometer, Atmos. Chem. Phys., 8, 7779-7793, doi:10.5194/acp-8-7779-2008, 2008.
35. Wittrock, F., Richter, A., Oetjen, H., Burrows, J., Kanakidou, M., Myriokefalitakis, S., Volkamer, R., Beirle, S., Platt, U., and Wagner, T.: Simultaneous global observations of glyoxal and formaldehyde from space, Geophys. Res. Lett., 33, L16804, doi:10.1029/2006GL026310, 2006.
36. Yu, G., Bayer, A. R., Galloway, M. M., Korshavn, K. J., Fry, C. G., and Keutsch, F. N.: Glyoxal in Aqueous Ammonium Sulfate Solutions: Products, Kinetics and Hydration Effects, Environ. Sci. Technol., 45, 6336-6342, doi:10.1021/es200989n, 2011.
37. Zalicki, P. and Zare, R. N.: Cavity ring-down spectroscopy for quantitative absorption measurements, J. Chem. Phys., 102, 2708-2717, 1994.