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Note that this formalism appeared originally in the 1st ed. of Fröhlich's monograph of the same name published in 1949. Thermodynamic effects of electric field have been described similarly by R. Becker, Electromagnetic Fields and Interactions, edited by F. Sauter (Blackie and Sons, London, 1964), Vol. 2 (translated by A. W. Knudsen)
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84887368659
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note
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In Böttcher's description, the energy of a dipole in an electric field is given by, W = -μ Ed cos θ, where Ed was defined as the directing field (p. 161 of Ref. 4). Ed is greater than E. To convert Ed to E, we use Böttcher's conclusion (pp. 175-176 of Ref. 4) that the ratio Ed/Ec lies between 1.1 and 1.5 in liquids, with the cavity field, Ec = [3εs/(2εs + 1)]E. This gives Ec ≅ 1.5 E when εs ≫ 1. Thus, the ratio Ed/E is between 1.6 and 2.2.
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84887369532
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note
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These effects are (a) anisotropic polarizability of a molecule, (b) hyperpolarizability of a dipolar molecule, (c) increase in the density due to electrostriction, (d) increase in T due to electro-caloric effect, (e) the Joule heating as a result of transport of ionic charge, and (f) the dielectric heating by irreversible absorption of electrical energy, measured by the dielectric loss, ε″ that changes εs and ε0, which violate the Boltzmann superposition.
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Roland, C.M.1
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