메뉴 건너뛰기




Volumn 138, Issue 15, 2013, Pages

Effects of electric field on the entropy, viscosity, relaxation time, and glass-formation

Author keywords

[No Author keywords available]

Indexed keywords

CONFIGURATIONAL ENTROPY; DIELECTRIC RESPONSE; DIPOLAR INTERACTION; EFFECTS OF ELECTRIC FIELDS; FIELD-INDUCED CHANGES; NON-ARRHENIUS KINETICS; NONLINEAR DIELECTRIC RESPONSE; ULTRAVISCOUS LIQUIDS;

EID: 84880414605     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.4799268     Document Type: Article
Times cited : (62)

References (59)
  • 3
    • 0004240239 scopus 로고
    • Chemical Catalogue, New York
    • P. Debye, Polar Molecules (Chemical Catalogue, New York, 1929).
    • (1929) Polar Molecules
    • Debye, P.1
  • 4
    • 0013353570 scopus 로고
    • Dielectrics in Static Fields
    • completely revised by O. C. van Belle, P. Bordewijk, and A. Rip Elsevier, New York, Chap. 7
    • C. J. F. Böttcher, Theory of Dielectric Polarization, Vol. 1: Dielectrics in Static Fields, completely revised by O. C. van Belle, P. Bordewijk, and A. Rip (Elsevier, New York, 1973), Chap. 7.
    • (1973) Theory of Dielectric Polarization , vol.1
    • Böttcher, C.J.F.1
  • 5
    • 79952754934 scopus 로고
    • General molecular theory and electric field effects in isotropic dielectrics
    • Senior Reporter, M. Davies The Chemical Society, London
    • S. Kielich, "General molecular theory and electric field effects in isotropic dielectrics," in Dielectric and Related Molecular Processes, Senior Reporter, M. Davies (The Chemical Society, London, 1972), Vol. 1, p. 192.
    • (1972) Dielectric and Related Molecular Processes , vol.1 , pp. 192
    • Kielich, S.1
  • 8
    • 0003767112 scopus 로고
    • Note that this formalism appeared originally in the 1st ed. of Fröhlich's monograph of the same name published in 1949. Thermodynamic effects of electric field have been described similarly by R. Becker, Blackie and Sons, London, (translated by A. W. Knudsen)
    • Note that this formalism appeared originally in the 1st ed. of Fröhlich's monograph of the same name published in 1949. Thermodynamic effects of electric field have been described similarly by R. Becker, Electromagnetic Fields and Interactions, edited by F. Sauter (Blackie and Sons, London, 1964), Vol. 2 (translated by A. W. Knudsen)
    • (1964) Electromagnetic Fields and Interactions , vol.2
    • Sauter, F.1
  • 18
    • 0010156808 scopus 로고
    • Non-linear dielectric effects
    • Senior Reporter, M. Davies The Chemical Society, London
    • G. P. Jones, "Non-linear dielectric effects," in Dielectric and Related Molecular Processes, Senior Reporter, M. Davies (The Chemical Society, London, 1975), Vol. 2, p. 198.
    • (1975) Dielectric and Related Molecular Processes , vol.2 , pp. 198
    • Jones, G.P.1
  • 19
    • 4344649348 scopus 로고    scopus 로고
    • Nonlinear Dielectric Phenomena in Complex Liquids
    • See also Proceedings of the NATO Advanced Research Workshop on Nonlinear Dielectric Phenomena in Complex Liquids, Jaszowiec-Ustron, Poland, 10-14 May 2003, NATO Science Series, Kluwer Academic, Dordrecht
    • See also Nonlinear Dielectric Phenomena in Complex Liquids, edited by S. J. Rzoska and V. P. Zhelezny, in Proceedings of the NATO Advanced Research Workshop on Nonlinear Dielectric Phenomena in Complex Liquids, Jaszowiec-Ustron, Poland, 10-14 May 2003, NATO Science Series, Mathematics, Physics and Chemistry, Vol. 157 (Kluwer Academic, Dordrecht, 2004).
    • (2004) Mathematics, Physics and Chemistry , vol.157
    • Rzoska, S.J.1    Zhelezny, V.P.2
  • 42
    • 84887368659 scopus 로고    scopus 로고
    • note
    • In Böttcher's description, the energy of a dipole in an electric field is given by, W = -μ Ed cos θ, where Ed was defined as the directing field (p. 161 of Ref. 4). Ed is greater than E. To convert Ed to E, we use Böttcher's conclusion (pp. 175-176 of Ref. 4) that the ratio Ed/Ec lies between 1.1 and 1.5 in liquids, with the cavity field, Ec = [3εs/(2εs + 1)]E. This gives Ec ≅ 1.5 E when εs ≫ 1. Thus, the ratio Ed/E is between 1.6 and 2.2.
  • 47
    • 84887369532 scopus 로고    scopus 로고
    • note
    • These effects are (a) anisotropic polarizability of a molecule, (b) hyperpolarizability of a dipolar molecule, (c) increase in the density due to electrostriction, (d) increase in T due to electro-caloric effect, (e) the Joule heating as a result of transport of ionic charge, and (f) the dielectric heating by irreversible absorption of electrical energy, measured by the dielectric loss, ε″ that changes εs and ε0, which violate the Boltzmann superposition.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.