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Volumn 38, Issue 22, 2013, Pages 9541-9552

Review of methanol reforming-Cu-based catalysts, surface reaction mechanisms, and reaction schemes

Author keywords

Cu; Hydrogen production; Methanol reforming; Methoxy; Surface reaction mechanism

Indexed keywords

CATALYSTS; COPPER; HYDROGEN PRODUCTION; MEMBRANE TECHNOLOGY; METHANOL; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC); SURFACE REACTIONS;

EID: 84879961365     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2013.03.023     Document Type: Article
Times cited : (256)

References (129)
  • 1
    • 29244449828 scopus 로고    scopus 로고
    • Challenges and future developments in proton exchange membrane fuel cells
    • K. Sopian, and W.R.W. Daud Challenges and future developments in proton exchange membrane fuel cells Renew Energy 31 2006 719 727
    • (2006) Renew Energy , vol.31 , pp. 719-727
    • Sopian, K.1    Daud, W.R.W.2
  • 2
    • 60649107994 scopus 로고    scopus 로고
    • Synthesis and optimization of future hydrogen energy infrastructure planning in Peninsular Malaysia
    • S.K. Kamarudin, W.R.W. Daud, Z. Yaakub, Z. Misron, W. Anuar, and N.A.N.N. Yusuf Synthesis and optimization of future hydrogen energy infrastructure planning in Peninsular Malaysia Int J Hydrogen Energy 34 2009 2077 2088
    • (2009) Int J Hydrogen Energy , vol.34 , pp. 2077-2088
    • Kamarudin, S.K.1    Daud, W.R.W.2    Yaakub, Z.3    Misron, Z.4    Anuar, W.5    Yusuf, N.A.N.N.6
  • 5
    • 0035976473 scopus 로고    scopus 로고
    • Fuel cells for road transport purposes - Yes or no?
    • B.D. McNicol, D.A.J. Rand, and K.R. Williams Fuel cells for road transport purposes - yes or no? J Power Sources 100 2001 47 59
    • (2001) J Power Sources , vol.100 , pp. 47-59
    • McNicol, B.D.1    Rand, D.A.J.2    Williams, K.R.3
  • 7
    • 0036534536 scopus 로고    scopus 로고
    • Steam reforming of methanol over copper-based monoliths: The effects of zirconia doping
    • B. Lindstrom, and L.J. Pettersson Steam reforming of methanol over copper-based monoliths: the effects of zirconia doping J Power Sources 106 2002 264 273
    • (2002) J Power Sources , vol.106 , pp. 264-273
    • Lindstrom, B.1    Pettersson, L.J.2
  • 9
    • 84857049202 scopus 로고    scopus 로고
    • Optimization of the preparation procedure of cobalt modified silicas as catalysts in methanol decomposition
    • T. Tsoncheva, A. Gallo, N. Scotti, M. Dimitrov, R. Delaigle, and E.M. Gaigneaux Optimization of the preparation procedure of cobalt modified silicas as catalysts in methanol decomposition Appl Catal A Gen 417 2012 209 219
    • (2012) Appl Catal A Gen , vol.417 , pp. 209-219
    • Tsoncheva, T.1    Gallo, A.2    Scotti, N.3    Dimitrov, M.4    Delaigle, R.5    Gaigneaux, E.M.6
  • 12
    • 78049336420 scopus 로고    scopus 로고
    • Catalytic partial oxidation of methanol over copper-zinc based catalysts: A comparative study of alumina, zirconia, and magnesia as promoters
    • C.L. Li, and Y.C. Lin Catalytic partial oxidation of methanol over copper-zinc based catalysts: a comparative study of alumina, zirconia, and magnesia as promoters Catal Lett 140 2010 69 76
    • (2010) Catal Lett , vol.140 , pp. 69-76
    • Li, C.L.1    Lin, Y.C.2
  • 14
    • 78049355056 scopus 로고    scopus 로고
    • Decomposition and partial oxidation of methanol over metal oxide Cu-Zn-Ce-based monoliths
    • A.Y. Kapran, S.O. Soloviev, and S.N. Orlyk Decomposition and partial oxidation of methanol over metal oxide Cu-Zn-Ce-based monoliths React Kinet Mech Catal 101 2010 343 353
    • (2010) React Kinet Mech Catal , vol.101 , pp. 343-353
    • Kapran, A.Y.1    Soloviev, S.O.2    Orlyk, S.N.3
  • 15
    • 0003162655 scopus 로고    scopus 로고
    • A comparative study of reactions of methanol over catalysts derived from NiAl- and CoAl-layered double hydroxides and their Sn-containing analogues
    • S. Velu, K. Suzuki, and T. Osaki A comparative study of reactions of methanol over catalysts derived from NiAl- and CoAl-layered double hydroxides and their Sn-containing analogues Catal Lett 69 2000 43 50
    • (2000) Catal Lett , vol.69 , pp. 43-50
    • Velu, S.1    Suzuki, K.2    Osaki, T.3
  • 16
    • 69349104589 scopus 로고    scopus 로고
    • Comparison of steam and autothermal reforming of methanol using a packed-bed low-cost copper catalyst
    • H.Y. Tang, P. Erickson, H.C. Yoon, and C.H. Liao Comparison of steam and autothermal reforming of methanol using a packed-bed low-cost copper catalyst Int J Hydrogen Energy 34 2009 7656 7665
    • (2009) Int J Hydrogen Energy , vol.34 , pp. 7656-7665
    • Tang, H.Y.1    Erickson, P.2    Yoon, H.C.3    Liao, C.H.4
  • 17
  • 18
    • 2342474039 scopus 로고    scopus 로고
    • Reaction study of auto thermal steam reforming of methanol to hydrogen using a novel nano CuZnAl-catalyst
    • S.T. Yong, K. Hidajat, and S. Kawi Reaction study of auto thermal steam reforming of methanol to hydrogen using a novel nano CuZnAl-catalyst J Power Sources 131 2004 91 95
    • (2004) J Power Sources , vol.131 , pp. 91-95
    • Yong, S.T.1    Hidajat, K.2    Kawi, S.3
  • 19
    • 55249112448 scopus 로고    scopus 로고
    • 3OH ratio in autothermal reforming of methanol by using a reduced copper-based catalyst
    • 3OH ratio in autothermal reforming of methanol by using a reduced copper-based catalyst Int J Hydrogen Energy 33 2008 6619 6626
    • (2008) Int J Hydrogen Energy , vol.33 , pp. 6619-6626
    • Yoon, H.C.1    Erickson, P.A.2    Kim, H.M.3
  • 20
    • 56749178659 scopus 로고    scopus 로고
    • Equilibrium model validation through the experiments of methanol autothermal reformation
    • K.S. Choi, H.M. Kim, J.L. Dorr, H.C. Yoon, and P.A. Erickson Equilibrium model validation through the experiments of methanol autothermal reformation Int J Hydrogen Energy 33 2008 7039 7047
    • (2008) Int J Hydrogen Energy , vol.33 , pp. 7039-7047
    • Choi, K.S.1    Kim, H.M.2    Dorr, J.L.3    Yoon, H.C.4    Erickson, P.A.5
  • 21
    • 79952246482 scopus 로고    scopus 로고
    • Thermal behavior and hydrogen production of methanol steam reforming and autothermal reforming with spiral preheating
    • W.H. Chen, and Y.J. Syu Thermal behavior and hydrogen production of methanol steam reforming and autothermal reforming with spiral preheating Int J Hydrogen Energy 36 2011 3397 3408
    • (2011) Int J Hydrogen Energy , vol.36 , pp. 3397-3408
    • Chen, W.H.1    Syu, Y.J.2
  • 22
    • 0000904678 scopus 로고    scopus 로고
    • Oxidative steam reforming of methanol over CuZnAl(Zr)-oxide catalysts for the selective production of hydrogen for fuel cells: Catalyst characterization and performance evaluation
    • S. Velu, K. Suzuki, M. Okazaki, M.P. Kapoor, T. Osaki, and F.J. Ohashi Oxidative steam reforming of methanol over CuZnAl(Zr)-oxide catalysts for the selective production of hydrogen for fuel cells: catalyst characterization and performance evaluation J Catal 194 2000 373 384
    • (2000) J Catal , vol.194 , pp. 373-384
    • Velu, S.1    Suzuki, K.2    Okazaki, M.3    Kapoor, M.P.4    Osaki, T.5    Ohashi, F.J.6
  • 25
    • 35848951576 scopus 로고    scopus 로고
    • Methanol steam reforming for hydrogen production
    • D.R. Palo, R.A. Dagle, and J.D. Holladay Methanol steam reforming for hydrogen production Chem Rev 10 2007 3992 4021
    • (2007) Chem Rev , vol.10 , pp. 3992-4021
    • Palo, D.R.1    Dagle, R.A.2    Holladay, J.D.3
  • 26
    • 84868022569 scopus 로고    scopus 로고
    • 3 catalysts: The role of Gallia polymorphs, intermetallic compounds, and pretreatment conditions on selectivity and stability in different reactions
    • 3 catalysts: the role of Gallia polymorphs, intermetallic compounds, and pretreatment conditions on selectivity and stability in different reactions ChemCatChem 4 2012 1764 1775
    • (2012) ChemCatChem , vol.4 , pp. 1764-1775
    • Li, L.1    Zhang, B.2    Kunkes, E.3    Föttinger, K.4    Armbrüster, M.5    Su, D.S.6
  • 27
    • 84858233311 scopus 로고    scopus 로고
    • Hydrogen production by methanol steam reforming on copper boosted by zinc-assisted water activation
    • C. Rameshan, W. Stadlmayr, S. Penner, H. Lorenz, N. Memmel, and M. Havecker Hydrogen production by methanol steam reforming on copper boosted by zinc-assisted water activation Angew Chem Int Ed 51 2012 3002 3006
    • (2012) Angew Chem Int Ed , vol.51 , pp. 3002-3006
    • Rameshan, C.1    Stadlmayr, W.2    Penner, S.3    Lorenz, H.4    Memmel, N.5    Havecker, M.6
  • 29
    • 0020845462 scopus 로고
    • Structure and function of real catalysts
    • K. Klier Structure and function of real catalysts Appl Surf Sci 19 1984 267 297
    • (1984) Appl Surf Sci , vol.19 , pp. 267-297
    • Klier, K.1
  • 30
  • 31
    • 0001167643 scopus 로고    scopus 로고
    • Study of the reducibility of copper in CuO-ZnO catalysts by temperature-programmed reduction
    • G. Fierro, M.L. Jacono, M. Inversi, P. Porta, F. Cioci, and R. Lavecchia Study of the reducibility of copper in CuO-ZnO catalysts by temperature- programmed reduction Appl Catal A Gen 137 1996 327 348
    • (1996) Appl Catal A Gen , vol.137 , pp. 327-348
    • Fierro, G.1    Jacono, M.L.2    Inversi, M.3    Porta, P.4    Cioci, F.5    Lavecchia, R.6
  • 32
    • 0002141709 scopus 로고
    • The role of hydrogen in methanol synthesis over copper-catalyst
    • R. Burch, S.E. Golunski, and M.S. Spencer The role of hydrogen in methanol synthesis over copper-catalyst Catal Lett 5 1990 55 60
    • (1990) Catal Lett , vol.5 , pp. 55-60
    • Burch, R.1    Golunski, S.E.2    Spencer, M.S.3
  • 33
    • 33845543008 scopus 로고
    • The role of copper and zinc-oxide in methanol synthesis catalyst
    • R. Burch, S.E. Golunski, and M.S. Spencer The role of copper and zinc-oxide in methanol synthesis catalyst J Chem Soc Faraday Trans 86 1990 2683 2691
    • (1990) J Chem Soc Faraday Trans , vol.86 , pp. 2683-2691
    • Burch, R.1    Golunski, S.E.2    Spencer, M.S.3
  • 34
    • 80051905928 scopus 로고    scopus 로고
    • Low-level CO in hydrogen-rich gas supplied by a methanol processor for PEMFCs
    • C.C. Chen, M.S. Jeng, C.H. Leu, C.C. Yang, Y.L. Lin, and S.C. King Low-level CO in hydrogen-rich gas supplied by a methanol processor for PEMFCs Chem Eng Sci 66 2011 5095 5106
    • (2011) Chem Eng Sci , vol.66 , pp. 5095-5106
    • Chen, C.C.1    Jeng, M.S.2    Leu, C.H.3    Yang, C.C.4    Lin, Y.L.5    King, S.C.6
  • 36
    • 0023055785 scopus 로고
    • Stable and metastable metal-surfaces in heterogeneous catalysis
    • M.S. Spencer Stable and metastable metal-surfaces in heterogeneous catalysis Nature 323 1986 685 687
    • (1986) Nature , vol.323 , pp. 685-687
    • Spencer, M.S.1
  • 37
    • 0001691487 scopus 로고    scopus 로고
    • Partial oxidation of methanol to produce hydrogen over Cu-Zn-based catalysts
    • L. Alejo, R. Lago, M.A. Peña, and J.L.G. Fierro Partial oxidation of methanol to produce hydrogen over Cu-Zn-based catalysts Appl Catal A Gen 162 1997 281 297
    • (1997) Appl Catal A Gen , vol.162 , pp. 281-297
    • Alejo, L.1    Lago, R.2    Peña, M.A.3    Fierro, J.L.G.4
  • 41
    • 0000215776 scopus 로고
    • Copper-alumina spinel catalysts for steam reforming of methanol
    • M. Matsukata, S. Uemiya, and E. Kikuchi Copper-alumina spinel catalysts for steam reforming of methanol Chem Lett 5 1988 761 764
    • (1988) Chem Lett , vol.5 , pp. 761-764
    • Matsukata, M.1    Uemiya, S.2    Kikuchi, E.3
  • 42
    • 34548456008 scopus 로고    scopus 로고
    • Combined steam reforming of methanol over Cu-Mn spinel oxide catalysts
    • J. Papavasiliou, G. Avgouropoulos, and T. Ioannides Combined steam reforming of methanol over Cu-Mn spinel oxide catalysts J Catal 251 2007 7 20
    • (2007) J Catal , vol.251 , pp. 7-20
    • Papavasiliou, J.1    Avgouropoulos, G.2    Ioannides, T.3
  • 43
    • 0037669076 scopus 로고    scopus 로고
    • Water gas shift reaction for the reformed fuels over Cu/MnO catalysts prepared via spinel-type oxide
    • Y. Tanaka, T. Utaka, R. Kikuchi, T. Takeguchi, K. Sasaki, and K. Eguchi Water gas shift reaction for the reformed fuels over Cu/MnO catalysts prepared via spinel-type oxide J Catal 215 2003 271 278
    • (2003) J Catal , vol.215 , pp. 271-278
    • Tanaka, Y.1    Utaka, T.2    Kikuchi, R.3    Takeguchi, T.4    Sasaki, K.5    Eguchi, K.6
  • 45
  • 46
    • 0034217377 scopus 로고    scopus 로고
    • XRD and TPR studies of Cu-Al hydrotalcite derived highly-dispersed mixed metal oxides
    • Y. Lwin, A.B. Mohamad, Z. Yaakob, and W.R.W. Daud XRD and TPR studies of Cu-Al hydrotalcite derived highly-dispersed mixed metal oxides React Kinet Catal Lett 70 2000 303 310
    • (2000) React Kinet Catal Lett , vol.70 , pp. 303-310
    • Lwin, Y.1    Mohamad, A.B.2    Yaakob, Z.3    Daud, W.R.W.4
  • 47
    • 16244364831 scopus 로고    scopus 로고
    • 4: A precursor for copper catalyst with high thermal stability and activity
    • 4: a precursor for copper catalyst with high thermal stability and activity Catal Lett 100 2005 89 93
    • (2005) Catal Lett , vol.100 , pp. 89-93
    • Kameoka, S.1    Tanabe, T.2    Tsai, A.P.3
  • 50
    • 81255160847 scopus 로고    scopus 로고
    • Dimethyl ether steam reforming under daily start-up and shut-down (DSS)-like operation over CuFe2O4 spinel and alumina composite catalysts
    • N. Shimoda, H. Muroyama, T. Matsui, K. Faungnawakij, R. Kikuchi, and K. Eguchi Dimethyl ether steam reforming under daily start-up and shut-down (DSS)-like operation over CuFe2O4 spinel and alumina composite catalysts Appl Catal A Gen 409-410 2011 91 98
    • (2011) Appl Catal A Gen , vol.409-410 , pp. 91-98
    • Shimoda, N.1    Muroyama, H.2    Matsui, T.3    Faungnawakij, K.4    Kikuchi, R.5    Eguchi, K.6
  • 52
    • 0034904342 scopus 로고    scopus 로고
    • The effect of cobalt on the structural properties and reduciblity of CuCoZnAl layered double hydroxided and their thermally derived mixed oxides
    • S. Velu, K. Suzuki, S. Hashimoto, N. Satoh, F. Ohashi, and S. Tomura The effect of cobalt on the structural properties and reduciblity of CuCoZnAl layered double hydroxided and their thermally derived mixed oxides J Mater Chem 11 2001 2049 2060
    • (2001) J Mater Chem , vol.11 , pp. 2049-2060
    • Velu, S.1    Suzuki, K.2    Hashimoto, S.3    Satoh, N.4    Ohashi, F.5    Tomura, S.6
  • 54
    • 38349164694 scopus 로고    scopus 로고
    • Waste-free soft reactive grinding synthesis of high-surface-area copper-manganese spinel oxide catalysts highly effective for methanol steam reforming
    • Q. Liu, L.C. Wang, M. Chen, Y.M. Liu, Y. Cao, and H.Y. He Waste-free soft reactive grinding synthesis of high-surface-area copper-manganese spinel oxide catalysts highly effective for methanol steam reforming Catal Lett 121 2008 144 150
    • (2008) Catal Lett , vol.121 , pp. 144-150
    • Liu, Q.1    Wang, L.C.2    Chen, M.3    Liu, Y.M.4    Cao, Y.5    He, H.Y.6
  • 55
    • 77950339365 scopus 로고    scopus 로고
    • A high surface area superparamagnetic mesoporous spinel ferrite synthesized by a template-free approach and its adsorptive property
    • Z. Gao, F.M. Cui, S.Z. Zeng, L.M. Guo, and J.L. Shi A high surface area superparamagnetic mesoporous spinel ferrite synthesized by a template-free approach and its adsorptive property Micropor Mesopor Mat 132 2010 188 195
    • (2010) Micropor Mesopor Mat , vol.132 , pp. 188-195
    • Gao, Z.1    Cui, F.M.2    Zeng, S.Z.3    Guo, L.M.4    Shi, J.L.5
  • 58
    • 43449101897 scopus 로고    scopus 로고
    • Synthesis of high surface area zinc chromate spinel with mesopore network from Zn-Cr-layered double hydroxide precursor
    • L. Zou, X. Xiang, J. Fan, F. Li, and D.G. Evans Synthesis of high surface area zinc chromate spinel with mesopore network from Zn-Cr-layered double hydroxide precursor J Phys Chem Solids 69 2008 1075 1078
    • (2008) J Phys Chem Solids , vol.69 , pp. 1075-1078
    • Zou, L.1    Xiang, X.2    Fan, J.3    Li, F.4    Evans, D.G.5
  • 59
    • 0035743239 scopus 로고    scopus 로고
    • Time-resolved XANES investigation of CuO/ZnO in the oxidative methanol reforming reaction
    • T.L. Reitz, P.L. Lee, K.F. Czaplewski, J.C. Lang, K.E. Popp, and H.H. Kung Time-resolved XANES investigation of CuO/ZnO in the oxidative methanol reforming reaction J Catal 199 2001 193 201
    • (2001) J Catal , vol.199 , pp. 193-201
    • Reitz, T.L.1    Lee, P.L.2    Czaplewski, K.F.3    Lang, J.C.4    Popp, K.E.5    Kung, H.H.6
  • 61
    • 36048929295 scopus 로고    scopus 로고
    • Cu/ZnO/Al2O3 catalysts for oxidative steam reforming of methanol: The role of Cu and the dispersing oxide matrix
    • M. Turco, G. Bagnasco, C. Cammarano, P. Senese, U. Costantino, and M. Sisani Cu/ZnO/Al2O3 catalysts for oxidative steam reforming of methanol: the role of Cu and the dispersing oxide matrix Appl Catal B Environ 77 2007 46 57
    • (2007) Appl Catal B Environ , vol.77 , pp. 46-57
    • Turco, M.1    Bagnasco, G.2    Cammarano, C.3    Senese, P.4    Costantino, U.5    Sisani, M.6
  • 62
    • 0001702363 scopus 로고
    • Surface vibrations of adsorbed intermediates in the reaction of alcohols with Cu (100)
    • B.A. Sexton Surface vibrations of adsorbed intermediates in the reaction of alcohols with Cu (100) Surf Sci 88 1979 299 318
    • (1979) Surf Sci , vol.88 , pp. 299-318
    • Sexton, B.A.1
  • 63
    • 0000935292 scopus 로고
    • 2CO on a Copper (110) catalyst
    • 2CO on a Copper (110) catalyst J Catal 53 1978 208 227
    • (1978) J Catal , vol.53 , pp. 208-227
    • Wachs, I.E.1    Madix, R.J.2
  • 64
    • 0000961491 scopus 로고
    • Reaction of methanol with Cu (111) and Cu (111) + O (ads)
    • J.N. Russell, S.M. Gates, and J.T. Yates Reaction of methanol with Cu (111) and Cu (111) + O (ads) Surf Sci 163 1985 516 540
    • (1985) Surf Sci , vol.163 , pp. 516-540
    • Russell, J.N.1    Gates, S.M.2    Yates, J.T.3
  • 65
    • 79957992444 scopus 로고    scopus 로고
    • In situ DRIFTS study on the methanol oxidation by lattice oxygen over Cu/ZnO catalyst
    • S.D. Lin, H. Cheng, and T.C. Hsiao In situ DRIFTS study on the methanol oxidation by lattice oxygen over Cu/ZnO catalyst J Mol Catal A: Chem 342-343 2011 35 40
    • (2011) J Mol Catal A: Chem , vol.342-343 , pp. 35-40
    • Lin, S.D.1    Cheng, H.2    Hsiao, T.C.3
  • 67
    • 37049066822 scopus 로고
    • Promotion of methanol synthesis and the water-gas shift reactions by adsorbed oxygen on supported copper-catalysts
    • G.C. Chinchen, M.S. Spencer, K.C. Waugh, and D.A. Whan Promotion of methanol synthesis and the water-gas shift reactions by adsorbed oxygen on supported copper-catalysts J Chem Soc Faraday Trans 83 1987 2193 2212
    • (1987) J Chem Soc Faraday Trans , vol.83 , pp. 2193-2212
    • Chinchen, G.C.1    Spencer, M.S.2    Waugh, K.C.3    Whan, D.A.4
  • 68
    • 38449120301 scopus 로고    scopus 로고
    • 4 spinel-lattice catalyst for methanol decomposition
    • 4 spinel-lattice catalyst for methanol decomposition Catal Today 131 2008 188 196
    • (2008) Catal Today , vol.131 , pp. 188-196
    • Yong, S.T.1    Hidajat, K.2    Kawi, S.3
  • 69
    • 35348822451 scopus 로고    scopus 로고
    • Effect of co-feed species on methanol conversion over Cu/ZnO/Al2O3 and its possible mechanism
    • T.C. Hsiao, and S.D. Lin Effect of co-feed species on methanol conversion over Cu/ZnO/Al2O3 and its possible mechanism J Mol Chem A 277 2007 137 144
    • (2007) J Mol Chem A , vol.277 , pp. 137-144
    • Hsiao, T.C.1    Lin, S.D.2
  • 70
    • 65249116933 scopus 로고    scopus 로고
    • Potential energy surface of methanol decomposition on Cu(110)
    • D. Mei, L. Xu, and G. Henkelman Potential energy surface of methanol decomposition on Cu(110) J Phys Chem C 113 2009 4522 4537
    • (2009) J Phys Chem C , vol.113 , pp. 4522-4537
    • Mei, D.1    Xu, L.2    Henkelman, G.3
  • 72
    • 33845449425 scopus 로고    scopus 로고
    • Implication of the role of oxygen anions and oxygen vacancies for methanol decomposition over zirconia supported copper catalysts
    • G.S. Wu, L.C. Wang, Y.M. Liu, Y. Cao, W.L. Dai, and H.Y. He Implication of the role of oxygen anions and oxygen vacancies for methanol decomposition over zirconia supported copper catalysts Appl Surf Sci 253 2006 974 982
    • (2006) Appl Surf Sci , vol.253 , pp. 974-982
    • Wu, G.S.1    Wang, L.C.2    Liu, Y.M.3    Cao, Y.4    Dai, W.L.5    He, H.Y.6
  • 74
    • 56549130361 scopus 로고    scopus 로고
    • 2O catalysis on supported copper clusters
    • 2O catalysis on supported copper clusters J Phys Chem C 112 2008 17235 17243
    • (2008) J Phys Chem C , vol.112 , pp. 17235-17243
    • Kim, D.K.1    Iglesia, E.2
  • 75
    • 34848885773 scopus 로고    scopus 로고
    • Total oxidation of methanol on Cu110): A density functional theory study
    • S. Sakong, and A. Gross Total oxidation of methanol on Cu110): a density functional theory study J Phys Chem A 111 2007 8814 8822
    • (2007) J Phys Chem A , vol.111 , pp. 8814-8822
    • Sakong, S.1    Gross, A.2
  • 76
    • 78650182274 scopus 로고    scopus 로고
    • First-principles study on the origin of the different selectivities for methanol steam reforming on Cu(111) and Pd(111)
    • X.K. Gu, and W.X. Li First-principles study on the origin of the different selectivities for methanol steam reforming on Cu(111) and Pd(111) J Phys Chem C 114 2010 21539 21547
    • (2010) J Phys Chem C , vol.114 , pp. 21539-21547
    • Gu, X.K.1    Li, W.X.2
  • 82
    • 33845283194 scopus 로고
    • FT-IR study of the adsorption and transformation of formaldehye on oxide surface
    • G. Busca, J. Lamotte, J.C. Lavalley, and V. Lorenzelli FT-IR study of the adsorption and transformation of formaldehye on oxide surface J Am Chem Soc 109 1987 5197 5202
    • (1987) J Am Chem Soc , vol.109 , pp. 5197-5202
    • Busca, G.1    Lamotte, J.2    Lavalley, J.C.3    Lorenzelli, V.4
  • 85
    • 0002362150 scopus 로고
    • Infrared spectroscopic identification of species arising from reactive adsorption of carbon oxides on metal-oxide surfaces
    • G. Busca, and V. Lorenzelli Infrared spectroscopic identification of species arising from reactive adsorption of carbon oxides on metal-oxide surfaces Mater Chem 7 1982 89 126
    • (1982) Mater Chem , vol.7 , pp. 89-126
    • Busca, G.1    Lorenzelli, V.2
  • 88
    • 0000506254 scopus 로고
    • Isotopic labeling studies of the mechanism of dehydrogenation of methanol to methyl formate over copper-based catalysts
    • N.W. Cant, S.P. Tonner, and D.L. Trimm Isotopic labeling studies of the mechanism of dehydrogenation of methanol to methyl formate over copper-based catalysts J Catal 91 1985 197 207
    • (1985) J Catal , vol.91 , pp. 197-207
    • Cant, N.W.1    Tonner, S.P.2    Trimm, D.L.3
  • 90
    • 0002231597 scopus 로고
    • Mechanism of formation of methyl formate from formaldehyde over Cu-catalysts
    • K. Takahashi, N. Takezawa, and H. Kobayashi Mechanism of formation of methyl formate from formaldehyde over Cu-catalysts Chem Lett 7 1983 1061 1064
    • (1983) Chem Lett , vol.7 , pp. 1061-1064
    • Takahashi, K.1    Takezawa, N.2    Kobayashi, H.3
  • 91
    • 0000402907 scopus 로고
    • Mechanism of methyl formate formation on Cu/ZnO catalysts
    • M.J. Chung, D.J. Moon, K.Y. Park, and S.K. Ihm Mechanism of methyl formate formation on Cu/ZnO catalysts J Catal 136 1992 609 612
    • (1992) J Catal , vol.136 , pp. 609-612
    • Chung, M.J.1    Moon, D.J.2    Park, K.Y.3    Ihm, S.K.4
  • 92
    • 84862787150 scopus 로고    scopus 로고
    • First-principles study of the methyl formate pathway of methanol steam reforming on PdZn(111) with comparison to Cu(111)
    • S. Lin, D. Xie, and H. Guo First-principles study of the methyl formate pathway of methanol steam reforming on PdZn(111) with comparison to Cu(111) J Mol Catal A: Chem 356 2012 165 170
    • (2012) J Mol Catal A: Chem , vol.356 , pp. 165-170
    • Lin, S.1    Xie, D.2    Guo, H.3
  • 93
    • 62949247408 scopus 로고    scopus 로고
    • Steam reforming of formaldehyde on Cu(100) surface: A density functional study
    • J.-Y. Bo, S. Zhang, and K.H. Lim Steam reforming of formaldehyde on Cu(100) surface: a density functional study Catal Lett 129 2009 444 448
    • (2009) Catal Lett , vol.129 , pp. 444-448
    • Bo, J.-Y.1    Zhang, S.2    Lim, K.H.3
  • 95
    • 0002522561 scopus 로고
    • Hydrogenolysis of methyl formate over copper on silica. 1. Study of surface Species by in situ infrared-spectroscopy
    • D.M. Monti, N.W. Cant, D.L. Trimm, and M.S. Wainwright Hydrogenolysis of methyl formate over copper on silica. 1. Study of surface Species by in situ infrared-spectroscopy J Catal 100 1986 17 27
    • (1986) J Catal , vol.100 , pp. 17-27
    • Monti, D.M.1    Cant, N.W.2    Trimm, D.L.3    Wainwright, M.S.4
  • 96
    • 33845379766 scopus 로고
    • Methanol, formaldehyde, and formic-acid adsorption on methanol synthesis catalysts
    • J.F. Edwards, and G.L. Schrader Methanol, formaldehyde, and formic-acid adsorption on methanol synthesis catalysts J Phys Chem 89 1985 782 788
    • (1985) J Phys Chem , vol.89 , pp. 782-788
    • Edwards, J.F.1    Schrader, G.L.2
  • 97
    • 58149212698 scopus 로고
    • Intermediate species on zirconia supported methanol aerogel catalyst. 5. Adsorption of methanol
    • D. Bianchi, T. Chafik, M. Khalfallah, and S.J. Teichner Intermediate species on zirconia supported methanol aerogel catalyst. 5. Adsorption of methanol Appl Catal A Gen 123 1995 89 110
    • (1995) Appl Catal A Gen , vol.123 , pp. 89-110
    • Bianchi, D.1    Chafik, T.2    Khalfallah, M.3    Teichner, S.J.4
  • 98
    • 24044482290 scopus 로고    scopus 로고
    • An infrared and inelastic neutron scattering spectroscopic investigation on the interaction of eta-alumina and methanol
    • A.R. McInroy, D.T. Lundie, J.M. Winfield, C.C. Dudman, P. Jones, and S.F. Parker An infrared and inelastic neutron scattering spectroscopic investigation on the interaction of eta-alumina and methanol Phys Chem Chem Phys 7 2005 3093 3101
    • (2005) Phys Chem Chem Phys , vol.7 , pp. 3093-3101
    • McInroy, A.R.1    Lundie, D.T.2    Winfield, J.M.3    Dudman, C.C.4    Jones, P.5    Parker, S.F.6
  • 99
    • 0033221931 scopus 로고    scopus 로고
    • Synergism between Cu and Zn sites in Cu/Zn catalysts for methanol synthesis
    • H.Y. Chen, S.P. Lau, L. Chen, J. Jin, C.H.A. Huan, and K.L. Tan Synergism between Cu and Zn sites in Cu/Zn catalysts for methanol synthesis Appl Surf Sci 152 1999 193 199
    • (1999) Appl Surf Sci , vol.152 , pp. 193-199
    • Chen, H.Y.1    Lau, S.P.2    Chen, L.3    Jin, J.4    Huan, C.H.A.5    Tan, K.L.6
  • 100
    • 33847087660 scopus 로고
    • Adsorption of alcohols on zinc-oxide surfaces
    • M. Nagao, and T. Morimoto Adsorption of alcohols on zinc-oxide surfaces J Phys Chem 84 1980 2054 2058
    • (1980) J Phys Chem , vol.84 , pp. 2054-2058
    • Nagao, M.1    Morimoto, T.2
  • 101
    • 57249100470 scopus 로고    scopus 로고
    • Gallium-hydrogen bond formation on gallium and gallium-palladium silica-supported catalysts
    • S.E. Collins, M.A. Baltanas, J.L.G. Fierro, and A.L. Bonivardi Gallium-hydrogen bond formation on gallium and gallium-palladium silica-supported catalysts J Catal 211 2002 252 264
    • (2002) J Catal , vol.211 , pp. 252-264
    • Collins, S.E.1    Baltanas, M.A.2    Fierro, J.L.G.3    Bonivardi, A.L.4
  • 102
    • 3042607951 scopus 로고    scopus 로고
    • Reaction scheme of partial oxidation of methane to synthesis gas over yttrium-stabilized zirconia
    • J. Zhu, J.G. van Ommen, and L. Lefferts Reaction scheme of partial oxidation of methane to synthesis gas over yttrium-stabilized zirconia J Catal 225 2004 388 397
    • (2004) J Catal , vol.225 , pp. 388-397
    • Zhu, J.1    Van Ommen, J.G.2    Lefferts, L.3
  • 103
    • 33846308100 scopus 로고    scopus 로고
    • Steam reforming of methanol over copper-containing catalysts: Influence of support material on microkinetics
    • B. Frank, F.C. Jentoft, H. Soerijanto, J. Krohnert, R. Schlogl, and R. Schomacker Steam reforming of methanol over copper-containing catalysts: Influence of support material on microkinetics J Catal 246 2007 177 192
    • (2007) J Catal , vol.246 , pp. 177-192
    • Frank, B.1    Jentoft, F.C.2    Soerijanto, H.3    Krohnert, J.4    Schlogl, R.5    Schomacker, R.6
  • 107
    • 0034429984 scopus 로고    scopus 로고
    • Hydrogen production from steam-methanol reforming: Thermodynamic analysis
    • Y. Lwin, W.R.W. Daud, A.B. Mohamad, and Z. Yaakob Hydrogen production from steam-methanol reforming: thermodynamic analysis Int J Hydrogen Energy 25 2000 47 53
    • (2000) Int J Hydrogen Energy , vol.25 , pp. 47-53
    • Lwin, Y.1    Daud, W.R.W.2    Mohamad, A.B.3    Yaakob, Z.4
  • 108
    • 0020719668 scopus 로고
    • Kinetics of a catalytic steam reforming of methanol in a CSTR reactor
    • E. Santacesaria, and S. Carrà Kinetics of a catalytic steam reforming of methanol in a CSTR reactor Appl Catal 5 1983 345 358
    • (1983) Appl Catal , vol.5 , pp. 345-358
    • Santacesaria, E.1    Carrà, S.2
  • 111
    • 0036534890 scopus 로고    scopus 로고
    • 3 catalyts: A kinetic analysis and strategies for suppression of CO formation
    • 3 catalyts: a kinetic analysis and strategies for suppression of CO formation J Power Sources 106 2002 249 257
    • (2002) J Power Sources , vol.106 , pp. 249-257
    • Agrell, J.1    Bigersson, H.2    Boutonnet, M.3
  • 114
    • 0038804185 scopus 로고    scopus 로고
    • Hydrogen generation in a Pd membrane fuel processor: Assessment of methanol-based reaction systems
    • M.P. Harold, B. Nair, and G. Kolios Hydrogen generation in a Pd membrane fuel processor: assessment of methanol-based reaction systems Chem Eng Sci 58 2003 2551 2571
    • (2003) Chem Eng Sci , vol.58 , pp. 2551-2571
    • Harold, M.P.1    Nair, B.2    Kolios, G.3
  • 115
    • 3543005946 scopus 로고    scopus 로고
    • Concept and design of a novel compact reactor for autothermal steam reforming with integrated evaporation and CO cleanup
    • A. Morillo, A. Freund, and C. Merten Concept and design of a novel compact reactor for autothermal steam reforming with integrated evaporation and CO cleanup Ind Eng Chem Res 43 2004 4624 4634
    • (2004) Ind Eng Chem Res , vol.43 , pp. 4624-4634
    • Morillo, A.1    Freund, A.2    Merten, C.3
  • 116
    • 2442547441 scopus 로고    scopus 로고
    • Hydrogen recovery from methanol steam reforming in a dense membrane reactor: Simulation study
    • F. Gallucci, L. Paturzo, and A. Basile Hydrogen recovery from methanol steam reforming in a dense membrane reactor: simulation study Ind Eng Chem Res 43 2004 2420 2432
    • (2004) Ind Eng Chem Res , vol.43 , pp. 2420-2432
    • Gallucci, F.1    Paturzo, L.2    Basile, A.3
  • 118
    • 0027908193 scopus 로고
    • Kinetic study of steam reforming of methanol over copper-based catalysts
    • C.J. Jiang, D.L. Trimm, and M.S. Wainwright Kinetic study of steam reforming of methanol over copper-based catalysts Appl Catal 93 1993 245 255
    • (1993) Appl Catal , vol.93 , pp. 245-255
    • Jiang, C.J.1    Trimm, D.L.2    Wainwright, M.S.3
  • 119
    • 0001363816 scopus 로고    scopus 로고
    • Methanol reforming for fuel-cell applications: Development of zirconia-containing Cu-Zn-Al catalysts
    • J.P. Breen, and J.R.H. Ross Methanol reforming for fuel-cell applications: development of zirconia-containing Cu-Zn-Al catalysts Catal Today 51 1999 521 533
    • (1999) Catal Today , vol.51 , pp. 521-533
    • Breen, J.P.1    Ross, J.R.H.2
  • 120
    • 0142011467 scopus 로고    scopus 로고
    • Production of hydrogen from methanol over binary Cu/ZnO catalysts part II. Catalytic activity and reaction pathways
    • J. Agrell, M. Boutonnet, and J.L.G. Fierro Production of hydrogen from methanol over binary Cu/ZnO catalysts part II. Catalytic activity and reaction pathways Appl Catal A Gen 253 2003 213 223
    • (2003) Appl Catal A Gen , vol.253 , pp. 213-223
    • Agrell, J.1    Boutonnet, M.2    Fierro, J.L.G.3
  • 121
    • 57649105265 scopus 로고    scopus 로고
    • Characterization and oxidation states of Cu and Pd in Pd-CuO/ZnO/ZrO2 catalysts for hydrogen production by methanol partial oxidation
    • S. Schuyten, S. Guerrero, J.T. Miller, T. Shibata, and E.E. Wolf Characterization and oxidation states of Cu and Pd in Pd-CuO/ZnO/ZrO2 catalysts for hydrogen production by methanol partial oxidation Appl Catal A Gen 352 2009 133 144
    • (2009) Appl Catal A Gen , vol.352 , pp. 133-144
    • Schuyten, S.1    Guerrero, S.2    Miller, J.T.3    Shibata, T.4    Wolf, E.E.5
  • 124
    • 50949112321 scopus 로고    scopus 로고
    • Thermodynamic equilibrium composition analysis of methanol autothermal reforming for proton exchange membrane fuel cell based on FLUENT Software
    • S. Wang, and S.D. Wang Thermodynamic equilibrium composition analysis of methanol autothermal reforming for proton exchange membrane fuel cell based on FLUENT Software J Power Sources 185 2008 451 458
    • (2008) J Power Sources , vol.185 , pp. 451-458
    • Wang, S.1    Wang, S.D.2
  • 126
    • 34250216062 scopus 로고    scopus 로고
    • Hydrogen production by oxidative steam reforming of methanol using ceria promoted copper-alumina catalysts
    • S. Patel, and K.K. Pant Hydrogen production by oxidative steam reforming of methanol using ceria promoted copper-alumina catalysts Fuel Process Technol 88 2007 825 832
    • (2007) Fuel Process Technol , vol.88 , pp. 825-832
    • Patel, S.1    Pant, K.K.2
  • 127
    • 33750628269 scopus 로고    scopus 로고
    • Compact string reactor for autothermal hydrogen production
    • C. Horny, A. Renken, and L. Kiwi-Minsker Compact string reactor for autothermal hydrogen production Catal Today 120 2007 45 53
    • (2007) Catal Today , vol.120 , pp. 45-53
    • Horny, C.1    Renken, A.2    Kiwi-Minsker, L.3
  • 128
    • 33750953247 scopus 로고    scopus 로고
    • Characteristics of hydrogen produced by partial oxidation and auto-thermal reforming in a small methanol reformer
    • R.F. Horng, H.M. Chou, C.H. Lee, and H.T. Tsai Characteristics of hydrogen produced by partial oxidation and auto-thermal reforming in a small methanol reformer J Power Sources 161 2006 1225 1233
    • (2006) J Power Sources , vol.161 , pp. 1225-1233
    • Horng, R.F.1    Chou, H.M.2    Lee, C.H.3    Tsai, H.T.4
  • 129
    • 0035858786 scopus 로고    scopus 로고
    • Selective production of hydrogen for fuel cells via oxidative steam reforming of methanol over CuZnAl(Zr)-oxide catalysts
    • S. Velu, K. Suzuki, M.P. Kapoor, F. Ohashi, and T. Osaki Selective production of hydrogen for fuel cells via oxidative steam reforming of methanol over CuZnAl(Zr)-oxide catalysts Appl Catal A Gen 213 2001 47 63
    • (2001) Appl Catal A Gen , vol.213 , pp. 47-63
    • Velu, S.1    Suzuki, K.2    Kapoor, M.P.3    Ohashi, F.4    Osaki, T.5


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