Equilibrium approach for CO2 and H2S absorption with aqueous solutions of alkanolamines: Theory and parameter estimation

Industrial and Engineering Chemistry Research

Volumn 52, Issue 26, 2013, Pages 9203-9226

  Luiz De Medeiros, José ^a   Chagas Barbosa, Leandro ^a   Araújo, Ofélia De Queiroz F ^a  

^a FEDERAL UNIVERSITY OF RIO DE JANEIRO   (Brazil)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS ALKANOLAMINES; COMPUTATIONAL EFFORT; CUBIC EQUATIONS OF STATE; EQUILIBRIUM APPROACHES; EQUILIBRIUM REACTIONS; IDEAL GAS PROPERTIES; INTERFACIAL TRANSFER; MOLECULAR COMPLEXES;

ALKANOLAMINES; CARBON DIOXIDE; EQUILIBRIUM CONSTANTS; PARAMETER ESTIMATION; THERMODYNAMICS;

GASES;

EID: 84879848630     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie302558b     Document Type: Article

References (60)

1. Sheilan, M. H., Spooner, B. H., and Hoorn, E. Amine Treating and Sour Water Stripping, 3 rd ed.; 2007.
2. 2 in Aqueous N-Methyldiethanolamine through the Simulated Annealing Algorithm Can. J. Chem. Eng. 2005, 83, 344
3. Jamal, A.; Meisen, A.; Lim, C. J. Kinetics of Carbon Dioxide Absorption and Desorption in Aqueous Alkanolamine Solutions Using a Novel Hemispherical Contactor-II. Experimental Results and Parameter Estimation Chem. Eng. Sci. 2006, 61, 6590
4. Kvamsdal, H. M.; Rochelle, G. T. Effects of the Temperature Bulge in CO2 Absorption from Flue Gas by Aqueous Monoethanolamine Ind. Eng. Chem. Res. 2008, 47, 867
5. Lepaumier, H.; Picq, D.; Carrette, P. L. New Amines for CO2 Capture. I. Mechanisms of Amine Degradation in the Presence of CO2 Ind. Eng. Chem. Res. 2009, 48, 9061
6. Sartori, G.; Ho, W. S.; Savage, D. W.; Chludzinski, G. R.; Wlechert, S. Sterically-Hindered Amines for Acid-Gas Absorption Sep. Purif. Rev. 1987, 16 (2) 171
7. Hook, R. J. An Investigation of Some Sterically Hindered Amines as Potential Carbon Dioxide Scrubbing Compounds Ind. Eng. Chem. Res. 1997, 36 (5) 1779
8. Samanta, A.; Bandyopadhyay, S. S. Absorption of Carbon Dioxide into Aqueous Solutions of Piperazine Activated 2-amino-2-methyl-1-propanol Chem. Eng. Sci. 2009, 64, 1185
9. 2S into Aqueous Blends of N-Methyl-diethanolamine and Diethanolamine Environ. Sci. Technol. 2006, 40, 6076
10. Li, M. H.; Shen, K. P. Solubility of Hydrogen Sulfide in Aqueous Mixtures of Monoethanolamine with N-Methyl-diethanolamine J. Chem. Eng. Data 1993, 38, 105
11. 2 in aqueous solutions of methyldiethanolamine and diethanolamine with 2-amino-2-methyl-1-propanol Fluid Phase Equilib. 2004, 218, 261
12. 2S in aqueous solutions of methyl-diethanolamine and diethanolamine with 2-amino-2-methyl-1-propanol at 313, 343, and 393K in the range 2.5-1036 kPa Fluid Phase Equilib. 2004, 224, 83
13. 2 Absorption/Desorption in Mixtures of Methyl-diethanolamine with Monoethanolamine or Diethanolamine Chem. Eng. Sci. 1991, 11, 2828
14. 2/Amine Absorption-Desorption Systems Gas Sep. Purif. 1994, 8, 3
15. 2 in Solutions of MDEA+Water Chem. Eng. Sci. 2000, 55, 4139
16. 2S Using Aqueous Solutions of MEA and DEA Fluid Phase Equilib. 2001, 185, 31
17. 2S Absorption and Desorption in an Aqueous MDEA-Solution Using a Rate-Based non-Equilibrium Approach Chem. Eng. Proc. 2003, 43, 701
18. Kabouche, A.; Meniai, A. H.; Bencheikh-Lehocine, M. Modeling the Absorption of Acidic Gases by Alkanolamine Solutions Incorporating Several Reactions Chem. Eng. Technol. 2005, 28, 67
19. 2 Post-combustion Capture AIChE J. 2007, 53 (4) 846
20. 2 Absorption Performance into Single and Blended Alkanolamines in a Packed Column Ind. Eng. Chem. Res. 2004, 43, 2228
21. Astarita, G.; Savage, D. W. Gas Absorption and Desorption with Reversible Instantaneous Chemical Reaction Chem. Eng. Sci. 1980, 35, 1755
22. Danckwerts, P. V. Absorption by Simultaneous Diffusion and Chemical Reaction Trans. Faraday Soc. 1950, 46, 300
23. Danckwerts, P. V. Gas-Liquid Reactions; McGraw-Hill: New York, 1979.
24. Billet, R.; Schultes, M. Predicting Mass Transfer in Packed Columns Chem. Eng. Technol. 1993, 16, 1
25. Bravo, J. L.; Rocha, J. A.; Fair, J. R. Comprehensive Model for the Performance of Columns Containing Structured Packings Inst. Chem. Eng. Symp. Ser. 1992, 1, A489
26. Brito, M. H.; von Stockar, U.; Bangerter, A. M.; Bomio, P. Effective Mass-Transfer Area in a Pilot Plant Column Equipped with Structured Packings and with Ceramic Rings Ind. Eng. Chem. Res. 1994, 33, 647
27. Leye, L.; Froment, G. F. Rigorous Simulation and Design of Columns for Gas Absorption and Chemical Reaction-I. Packed Columns Comput. Chem. Eng. 1986, 10, 493
28. Rinker, E. B.; Ashour, S. S.; Sandall, O. C. Kinetics and Modelling of Carbon Dioxide Absorption into Aqueous Solutions of N-Methyl-diethanolamine Chem. Eng. Sci. 1995, 50, 755
29. Gabrielsen, J.; Michelsen, M. L.; Stenby, E. H.; Kontogeorgis, G. M. A Model for Estimating CO2 Solubility in Aqueous Alkanolamines Ind. Eng. Chem. Res. 2005, 44, 3348
30. Gabrielsen, J.; Michelsen, M. L.; Stenby, E. H.; Kontogeorgis, G. M. Modeling of CO2 Absorber Using an AMP Solution AIChE J. 2006, 52, 3443
31. Gabrielsen, J.; Svendsen, H. F.; Michelsen, M. L.; Stenby, E. H.; Kontogeorgis, G. M. Experimental validation of a rate-based model for CO2 capture using an AMP solution Chem. Eng. Sci. 2007, 62, 2397
32. Chunxi, L.; Fürst, W. Representation of CO2 and H2S Solubility in Aqueous MDEA Solutions Using an Electrolyte Equation of State Chem. Eng. Sci. 2000, 55, 2975
33. Deshmukh, R.; Mather, A. A Mathematical Model for Equilibrium Solubility of Hydrogen Sulfide and Carbon Dioxide in Aqueous Alkanolamine Solutions Chem. Eng. Sci. 1981, 36, 355
34. Austgen, D. M.; Rochelle, G. T.; Peng, X.; Chen, C. C. Model of vapour-liquid equilibria for aqueous gas-alkanolamine systems using the electrolyte-NRTL equation Ind. Eng. Chem. Res. 1989, 28, 1060
35. Austgen, D. M.; Rochelle, G. T.; Chen, C. C. Model of vapor-liquid equilibria for aqueous gas-alkanolamine systems. 2. Representation of hydrogen sulfide and carbon dioxide solubility in aqueous MDEA and carbon dioxide solubility in aqueous mixtures of MDEA with MEA or DEA Ind. Eng. Chem. Res. 1991, 30, 543
36. 2S-Water Ind. Eng. Chem. Res. 1997, 36, 3944
37. 2S Absorption by Aqueous Solutions of Diethanolamine Using an Electrolyte Equation of State Ind. Eng. Chem. Res. 1999, 38, 3473
38. Prausnitz, J. M.; Lichtenthaler, R. N.; Azevedo, E. G. Molecular Thermodynamics of Fluid-Phase Equilibria, 2 nd ed.; Prentice-Hall: Englewood Cliffs, 1986.
39. 2S with Aqueous Solutions of Ethanolamines. In ENPROMER 2005-4th Mercosur Congress on Process Systems Engineering, Rio de Janeiro, E-papers, 2005.
40. 2 in Aqueous Mixtures of MEA with MDEA J. Chem. Eng. Data 1992, 37, 96
41. 2S in Aqueous Mixtures of MEA with MDEA J. Chem. Eng. Data 1993, 38, 105
42. Jou, F. Y.; Carroll, J. J.; Mather, A. E.; Otto, F. D. Solubility of Mixtures of Hydrogen Sulfide and Carbon Dioxide in Aqueous N-Methyl- diethanolamine Solutions J. Chem. Eng. Data 1993, 38, 75
43. 2 in Aqueous Mixtures of Alkanolamines J. Chem. Eng. Data 1994, 39, 548
44. Jou, F. Y.; Mather, A.; Otto, F. Solubility of H2S and CO2 in Aqueous Methyl-diethanolamine Solutions Ind. Eng. Chem. Process Des. Dev. 1982, 21, 539
45. Kent, R. L.; Eisenberg, B. Better Data for Amine Treating Hydrocarbon Process. 1976, 55, 87
46. Kuranov, G.; Rumpf, B.; Maurer, G.; Smirnova, N. VLE modelling for aqueous systems containing methyl-diethanolamine, carbon dioxide and hydrogen sulphide Fluid Phase Equilib. 1997, 136, 147
47. Kundu, M.; Bandyopadhyay, S. S. Solubility of CO2 in water + diethanolamine + N-methyldiethanolamine Fluid Phase Equilib. 2006, 248, 158
48. Mandal, B.; Bandyopadhyay, S. S. Absorption of Carbon Dioxide into Aqueous Blends of 2-amino-2-methyl-1-propanol and Monoethanolamine Chem. Eng. Sci. 2006, 61, 5440
49. Mokhatab, S.; Poe, W.; Speight, J. Handbook of Natural Gas Transmission and Processing, 1 st ed.; 2006.
50. Murrieta-Guevara, F.; Rebolledo-Libreros, M. E.; Romero-Martínez, A.; Trejo, A. Solubility of CO2 in aqueous mixtures of diethanolamine with methyl-diethanolamine and with 2-amino-2-methyl-1-propanol Fluid Phase Equilib. 1998, 150-151, 721
51. Sidi-Boumedine, R.; Horstmann, S.; Fischer, K.; Provost, E.; Fürst, W.; Gmehling, J. Experimental determination of carbon dioxide solubility data in aqueous alkanolamine solutions Fluid Phase Equilib. 2004, 218, 85
52. Sidi-Boumedine, R.; Horstmann, S.; Fischer, K.; Provost, E.; Fürst, W.; Gmehling, J. Experimental determination of hydrogen sulfide solubility data in aqueous alkanolamine solutions Fluid Phase Equilib. 2004, 218, 149
53. 2O into Aqueous Solutions of Methyl-diethanolamine AIChE J. 1989, 35, 861
54. Vrachnos, A.; Voutsas, E.; Magoulas, K.; Lygeros, A. Thermodynamics of Acid Gas-MDEA-Water Systems Ind. Eng. Chem. Res. 2004, 43, 2798
55. Benamor, A.; Aroua, M. K. Modeling of CO2 solubility and carbamate concentration in DEA, MDEA and their mixtures using the Deshmukh-Mather model Fluid Phase Equilib. 2005, 231, 150
56. Reid, R. C.; Prausnitz, J. M.; Poling, B. E. The Properties of Gases and Liquids, 4 th ed.; McGraw-Hill: New York, 1987.
57. Britt, H. I.; Luecke, R. H. The Estimation of Parameters in Non-Linear Implicit Models Technometrics 1973, 15, 233
58. Anderson, T. F.; Abrams, D. S.; Greens, E. A. Evaluation of Parameters for Nonlinear Thermodynamic Models AIChE J. 1978, 24 (1) 20
59. Deming, W. E. Statistical Adjustment of Data; Wiley: New York, 1943.
60. Himmelblau, D. M. Process Analysis by Statistical Methods; John Wiley & Sons: 1970.