A remote lewis acid trigger dramatically accelerates biaryl reductive elimination from a platinum complex

Journal of the American Chemical Society

Volumn 135, Issue 26, 2013, Pages 9612-9615

  Liberman Martin, Allegra L ^a,b   Bergman, Robert G ^a,b   Tilley, T Don ^a,b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL SWITCHES; COORDINATION SPHERE; LEWIS ACID; METAL CENTERS; PLATINUM COMPLEXES; REDUCTIVE ELIMINATION;

CARRIER CONCENTRATION;

ELECTRON DENSITY MEASUREMENT;

LEWIS ACID; NITROGEN; PLATINUM COMPLEX; PLATINUM DERIVATIVE; PYRAZINE DERIVATIVE;

ACCELERATION; ARTICLE; CHEMICAL BINDING; DENSITY; ELECTRON; ELECTROPHILICITY; ELIMINATION REACTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE;

LEWIS ACIDS; MOLECULAR STRUCTURE; ORGANOPLATINUM COMPOUNDS; OXIDATION-REDUCTION; PYRAZINES;

EID: 84879766374     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja404339u     Document Type: Article

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