PCDD/F formation in an iron/potassium-catalyzed diesel particle filter

Environmental Science and Technology

Volumn 47, Issue 12, 2013, Pages 6510-6517

  Heeb, Norbert V ^a   Zennegg, Markus ^a   Haag, Regula ^a   Wichser, Adrian ^a   Schmid, Peter ^a   Seiler, Cornelia ^a   Ulrich, Andrea ^a   Honegger, Peter ^a   Zeyer, Kerstin ^a   Emmenegger, Lukas ^a   Bonsack, Peter ^b   Zimmerli, Yan ^b   Czerwinski, Jan ^b   Kasper, Markus ^c   Mayer, Andreas ^d  

^a SWISS FEDERAL LABORATORIES FOR MATERIALS SCIENCE AND TECHNOLOGY   (Switzerland)

^b University of Applied Sciences Biel   (Switzerland)

^c Matter Aerosol AG   (Switzerland)

^d Technik Thermischer Maschinen ^*  (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

2 , 3 , 7 , 8-TCDD; CATALYTIC PROPERTIES; FILTER REGENERATION; FUEL-BORNE CATALYSTS; HEAVY DUTY VEHICLES; PCDD/F FORMATION; POLYCHLORINATED DIBENZODIOXINS/FURANS; SOLUBLE CATALYSTS;

CATALYST REGENERATION; DISTRIBUTED COMPUTER SYSTEMS; FUELS; MONTE CARLO METHODS; SIGNAL FILTERING AND PREDICTION; SILICON CARBIDE; TARGET TRACKING;

CATALYSIS;

CHLORINE; COPPER; DIBENZOFURAN; FERRIC OXIDE; FURAN DERIVATIVE; IRON; MAGNETITE; POLYCHLORINATED DIBENZODIOXIN; POTASSIUM; SILICON CARBIDE;

AUTOMOBILE; CARBON EMISSION; CATALYSIS; CHEMICAL POLLUTANT; FILTER; IRON;

ARTICLE; CATALYST; DIESEL ENGINE; FILTER; PROMOTER REGION;

BENZOFURANS; CATALYSIS; FILTRATION; IRON; POTASSIUM; TETRACHLORODIBENZODIOXIN;

EID: 84879243352     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es400760h     Document Type: Article

References (40)

1. Diesel, R. Arbeitsverfahren und Ausführungsart für Verbrennungs-kraftmaschinen. Deutsches Reichs Patent 67207, 1892.
2. Brüske-Hohlfeld, I.; Möhner, M.; Ahrens, W.; Pohlabeln, H.; Heinrich, J.; Kreuzer, M.; Jöckel, K.-H.; Wichmann, H.-E. Lung cancer risk in male workers occupationally exposed to diesel motor emissions in Germany Am. J. Ind. Med. 1999, 36, 405-414
3. Silverman, D. T.; Samanic, C. M.; Lubin, J. H.; Blair, A. E.; Steward, P. A.; Vermeulen, R.; Coble, J. B.; Rothman, N.; Schleiff, P. L.; Travis, D.; Ziegler, R. G.; Wacholder, S.; Attfield, M. D. The diesel exhaust in miners study: A nested case-control study of lung cancer and diesel exhaust J. Natl. Cancer Inst. 2012, 104, 1-14
4. Attfield, M. D.; Schleiff, P. L.; Lubin, J. H.; Blair, A.; Steward, P. A.; Vermeulen, R.; Coble, J. B.; Silberman, D. T. The diesel exhaust in miners study: A cohort mortality study with emphasis on lung cancer J. Natl. Cancer Inst. 2012, 104, 1-15
5. World Health Organization, International Agency for Research on Cancer, Diesel engine exhaust carcinogenic, Press release No 213. Available at http://press.iarc.fr/pr213-E.pdf.
6. Mayer, A.; Ulrich, A.; Heeb, N. V.; Czerwinski, J.; Neubert, T. Particle filter properties after 2000 h real world operation Soc. Auto. Eng. 2008, 01-0332, 1-7
7. Swiss Normative Organization, SNR 277206 Testing particle filter systems for internal combustion engines. Available at http://www.snv.ch.
8. World Health Organization, Environmental Health Criteria202, Selected non-heterocyclic polycyclic aromatic hydrocarbons. Available at http://www.who.int/ipcs/publications/ehc.
9. World Health Organization, EnvironmentalHealth Criteria229, Selected nitro-and nitro-oxy-polycyclic aromatic hydrocarbons. Available at http://www.who.int/ipcs/publications/ehc.
10. Heeb, N.; Ulrich, A.; Emmenegger, L.; Czerwinski, J.; Mayer, A.; Wyser, M. Secondary emissions risk assessment of diesel particulate traps Soc. Auto. Eng. 2005, 2005-24-014, 329-338
11. Heeb, N. V.; Schmid, P.; Kohler, M.; Gujer, E.; Zennegg, M.; Wenger, D.; Wichser, A.; Ulrich, A.; Gfeller, U.; Honegger, P.; Zeyer, K.; Emmenegger, L.; Petermann, J.-L.; Czerwinski, J.; Mosimann, T.; Kasper, M.; Mayer, A. Secondary effects of catalytic diesel particulate filters: Conversion of PAHs versus formation of nitro-PAHs Environ. Sci. Technol. 2008, 42, 3773-3779
12. Liu, Z. G.; Berg, D. R.; Swor, T. A.; Schauer, J. J. Comparative analysis on the effects of diesel particulate filter and selective catalytic reduction systems on a wide spectrum of chemical species emissions Environ. Sci. Technol. 2008, 42, 6080-6085
13. Heeb, N. V.; Schmid, P.; Kohler, M.; Gujer, E.; Zennegg, M.; Wenger, D.; Wichser, A.; Ulrich, A.; Gfeller, U.; Honegger, P.; Zeyer, K.; Emmenegger, L.; Petermann, J.-L.; Czerwinski, J.; Mosimann, T.; Kasper, M.; Mayer, A. Impact of low and high oxidation diesel particulate filters on genotoxic exhaust constituents Environ. Sci. Technol. 2010, 44, 1078-1084
14. Laroo, A. C.; Schenk, C. R.; Sanchez, J.; McDonald, J. Emissions of PCDD/Fs, PCBs, and PAHs from a modern diesel engine equipped with catalyzed emission control systems Environ. Sci. Technol. 2011, 45, 6420-6428
15. US-EPA, Environmental Protection Agency, Clean Air Act,Section 202, Washington DC, 2002. Available on http://www.epa.gov/oar/caa/caa202.tx t
16. Buser, H. R.; Bosshardt, H. P.; Rappe, C.; Lindahl, R. Identification of polychlorinated dibenzo-p-dioxin isomers found in fly ash Chemosphere 1978, 7, 419-429
17. Hagenmaier, H.; Kraft, M.; Brunner, H.; Haag, R. Catalytic effects of fly ash from waste incineration facilities on the formation and decomposition of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans Environ. Sci. Technol. 1987, 21, 1080-1084
18. Gullett, B. K.; Bruce, K. R.; Beach, L. O.; Drago, A. M. Mechanistic steps in the production of PCDD and PCDF during waste combustion Chemosphere 1992, 25, 1387-1392
19. Hinton, W. S.; Lane, S. M. Effect of zinc, copper and sodium on formation of polychlorinated dioxins on MWS incineration fly ash Chemosphere 1992, 25, 811-819
20. Born, J. G. P.; Louw, R.; Mulder, P. Fly ash mediated (oxy)chlorination of phenol and its role in PCDD/F formation Chemosphere 1993, 26, 2087-2095
21. Fängmark, I.; Strömberg, B.; Berge, N.; Rappe, C. Influence of post combustion temperature profiles on the formation of PCDDs, PCDFs, PCBzs and PCBs in a pilot incinerator Environ. Sci. Technol. 1994, 28, 624-629
22. Altwicker, E. R. Formation of PCDD/F in municipal solid waste incinerators: laboratory and modeling studies J. Hazardous Mater. 1996, 47, 137-161
23. 2-catalyzed condensation of 2,6-chlorinated phenols Combust. Sci. Technol. 2001, 169, 107-126
24. Wikström, E.; Ryan, S.; Touati, A.; Gullett, B. Key parameters for de novo formation of polychlorinated dibenzo-p -dioxins and dibenzofurans Environ. Sci. Technol. 2003, 37, 1962-1970
25. Ryu, J.-Y.; Mulholland, J. A. Homologue and isomer patterns of polychlorinated dibenzo-p -dioxins and dibenzofurans from phenol precursors: Comparison with municipal waste incinerator data Environ. Sci. Technol. 2005, 39, 4398-4406
26. Clunies-Ross, C.; Stanmore, B. R.; Millar, G. J. Dioxins in diesel exhaust Nature 1996, 381, 379
27. Heeb, N. V.; Zennegg, M.; Gujer, E.; Honegger, P.; Zeyer, K.; Gfeller, U.; Wichser, A.; Kohler, M.; Schmid, P.; Emmenegger, L.; Ulrich, A.; Wenger, D.; Petermann, J.-L.; Czerwinski, J.; Mosimann, T.; Kasper, M.; Mayer, A. Secondary effects of catalytic diesel particulate filters: Copper-induced de novo formation of PCDD/Fs Environ. Sci. Technol. 2007, 41, 5789-5794
28. Swiss federal regulation on air pollution control, SR 814.318.142.1. Requirements for construction engines and their particulate filter systems-Status January 2009. Available at http://www.admin.ch.
29. Oehme, M.; Larssen, S.; Brevik, E. M. Emission factors of PCDD and PCDF for road vehicles obtained by tunnel experiment Chemosphere 1991, 23, 1699-1708
30. Gertler, A.; Sagebiel, J.; Dippel, W. Measurement of dioxin and furan emission factors from heavy duty diesel vehicles J. Air Waste Manage. Assoc. 1998, 48, 276-278
31. Geueke, K. J.; Gessner, A.; Quass, U.; Broker, G.; Hiester, E. PCDD/F emissions from heavy duty vehicle diesel engines Chemosphere 1999, 38, 2791-2806
32. Gullett, B. K.; Ryan, J. V. On-road emissions of PCDDs and PCDFs from heavy duty diesel vehicles Environ. Sci. Technol. 2002, 36, 3036-3040
33. Liu, Z. G.; Wall, J. C.; Barge, P.; Dettmann, M. E.; Ottinger, N. A. Investigation of PCDD/F emissions from mobile source diesel engines: Impact of copper Zeolite SCR catalysts and exhaust aftertreatment configurations Environ. Sci. Technol. 2011, 45, 2965-2972
34. United Nations Environment Program, UNE-EN 1948-1: (2007, Stationary source emissions-Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs-Part 1: Sampling of PCDDs/PCDFs.
35. Wunderli, S.; Zennegg, M.; Dolezal, I. S.; Gujer, E.; Moser, U.; Wolfensberger, M.; Hasler, P.; Noger, D.; Studer, C.; Karlaganis, G. Determination of polychlorinated dibenzo-p -dioxins and dibenzo-furans in solid residues from wood combustion by HRGC/HRMS Chemosphere 2000, 40, 641-649
36. Salvat, O.; Marez, P.; Bélot, G. Passenger car serial application of a particulate filter system on a common rail direct injection diesel engine Soc. Auto. Eng. 2000, 2000-01-0473, 1-13
37. 2 Reduction and hydrogenation to ammonia by a molecular iron-potassium complex Science 2011, 334, 780-783
38. Ozkara-Aydinoglu, S.; Atac, O.; Gül, O. F.; Kinayyigit, S.; Sal, S.; Baranak, M.; Boz, I. α-Olefin selectivity of Fe-Cu-K catalysts in Fischer-Tropsch synthesis: Effects of catalyst composition and process conditions Chem. Eng. J. 2012, 181-182, 581-589
39. 2 green house gases on Jungfraujoch (HALCLIM-4) Final Report. Available at http://www.empa.ch/climate gases.
40. Federal Office for the Environment, Tested and approved particle filter systems for diesel engines-Status December 2012. Available at http://www.bafu.admin.ch/publikationen.