Mesoporous catalysts based on Keggin-type heteropolyacids supported on MCM-41 and their application in thiophene hydrodesulfurization

Fuel

Volumn 110, Issue , 2013, Pages 249-258

  Méndez, Franklin J ^a   Llanos, Aura ^b   Echeverría, Marcel ^a,b   Jáuregui, Reynaldo ^a,b   Villasana, Yanet ^a   Díaz, Yraida ^a   Liendo Polanco, Gustavo ^c   Ramos García, Miguel A ^d   Zoltan, Tamara ^a   Brito, Joaquín L ^a  

^a INSTITUTO VENEZOLANO DE INVESTIGACIONES CIENTÍFICAS   (Venezuela)

^b UNIVERSIDAD CENTRAL DE VENEZUELA   (Venezuela)

^c UNIVERSIDAD DE ORIENTE   (Venezuela)

^d Instituto Zuliano de Investigaciones Tecnologicas   (Venezuela)

Author keywords

12 Molybdophosphoric acid; 12 Tungstophosphoric acid; Heteropolyacids; Hydrodesulfurization; MCM 41

Indexed keywords

ACTIVATION ANALYSIS; ATMOSPHERIC PRESSURE; CATALYSTS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDRODESULFURIZATION; THERMOGRAVIMETRIC ANALYSIS; THIOPHENE; TITRATION; VOLTAMMETRY; X RAY DIFFRACTION;

12-MOLYBDOPHOSPHORIC ACID; 12-TUNGSTOPHOSPHORIC ACID; HETEROPOLY ACIDS; PHYSICO-CHEMICAL CHARACTERIZATION; POTENTIOMETRIC TITRATIONS; THIOPHENE HYDRODESULFURIZATION; WEIGHT HOURLY SPACE VELOCITY; WIDE ANGLE XRAY DIFFRACTION;

CATALYST ACTIVITY;

EID: 84879056864     PISSN: 00162361     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuel.2012.11.021     Document Type: Article

References (74)

1. Knudsen KG, Cooper BH, Topsøe H. Catalyst and process technologies for ultra-low sulfur diesel. Appl Catal A 1999;189:205-15. (Pubitemid 129532988)
2. Song C. An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel. Catal Today 2003;86:211-63.
3. Yoshimura Y, Toba M, Farag H, Sakanishi K. Ultra deep hydrodesulfurization of gas oils over sulfide and/or noble metal catalysts. Catal Surv Asia 2004;8:47-60. (Pubitemid 38988046)
4. Kozhevnikov IV, Sinnema A, Jansen RJJ, Pamin K, van Bekkum H. New acid catalyst comprising heteropoly acid on a mesoporous molecular sieve MCM-41. Catal Lett 1995;30:241-52.
5. Kozhevnikov IV. Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions. Chem Rev 1998;98:171-98. (Pubitemid 128633426)
6. Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, et al. A new family of mesoporous molecular sieves prepared with liquid crystal template. J Am Chem Soc 1992;114:10834-43.
7. Zhao XS, Lu GQ, Millar GJ. Advances in mesoporous molecular sieve MCM-41. Ind Eng Chem Res 1996;35:2075-90.
8. Bhattacharyya S, Lelong G, Saboungi ML. Recent progress in the synthesis and selected applications of MCM-41: a short review. J Exp Nanosci 2006;1:375-95.
9. 3-MCM-41 catalyst for dibenzothiophene hydrodesulfurization. Catal Today 2008;130:309-19.
10. Schacht P, Ramírez S, Ancheyta J. CoMo/Ti-MCM-41/alumina catalysts: Properties and activity in the hydrodesulfurization (HDS) of dibenzothiophene (DBT). Energy Fuels 2009;23:4860-5.
11. Gao S, Moffat JB. Isomerization of 1-butene on supported and unsupported metal-oxygen cluster compounds (heteropoly oxometalates). Catal Lett 1996;42:105-11. (Pubitemid 126475849)
12. Vázquez PG, Blanco MN, Cáceres CV. Catalysts based on supported 12-molybdophosphoric acid. Catal Lett 1999;60:205-15. (Pubitemid 129555606)
13. Jaramillo H, Palacio LA, Sierra L. Characterization of a heteropolyacid supported on mesoporous silica and its application in the aromatization of α-pinene. Stud Surf Sci Catal 2002;142:1291-8.
14. Kuang W, Rives A, Fournier M, Hubaut R. Structure and reactivity of silica-supported 12-tungstophosphoric acid. Appl Catal A 2003;250:221-9.
15. Pizzio LR, Vázquez PG, Cáceres CV, Blanco MN. Supported Keggin type heteropolycompounds for ecofriendly reactions. Appl Catal A 2003;256:125-39.
16. 2-supported dodecatungstophosphoric acid and Nafion-H prepared by ball-milling for catalytic application. Appl Catal A 2005;282:255-65.
17. 2 in a self-generated acidic environment by evaporation-induced self-assembly. Mat Res Bull 2007;42:1905-13.
18. Abdollahi-Alibeik M, Mohammadpoor-Baltork I, Zaghaghi Z, Yousefi BH. Efficient synthesis of 1,5-benzodiazepines catalyzed by silica supported 12-tungstophosphoric acid. Catal Comm. 2008;9:2496-502.
19. 2 catalyst. J Fuel Chem Technol 2009;37:318-23.
20. Gong S, Liu L, Cui Q, Ding J. Liquid phase nitration of benzene over supported ammonium salt of 12-molybdophosphoric acid catalysts prepared by sol-gel method. J Hazard Mater 2010;178:404-8.
21. Griboval A, Blanchard P, Payen E, Fournier M, Dubois JL. Preparation of hydrodesulfurization catalysts by impregnation of alumina with new heteropolycompounds. Chem Lett 1997;12:1259-60.
22. Griboval A, Blanchard P, Payen E, Fournier M, Dubois JL. Alumina supported HDS catalysts prepared by impregnation with new heteropolycompounds. Comparison with catalysts prepared by conventional Co-Mo-P coimpregnation. Catal Today 1998;45:277-83. (Pubitemid 128411774)
23. Griboval A, Blanchard P, Payen E, Fournier M, Dubois JL, Bernard JR. Characterization and catalytic performances of hydrotreatment catalysts prepared with silicium heteropolymolybdates: Comparison with phosphorus doped catalysts. Appl Catal A 2001;217:173-83.
24. Palcheva R, Spojakina A, Tyuliev G, Jiratovaa K, Petrov L. Thiophene hydrodesulfurization activity of alumina supported heteropoly compounds: nickel effect. React Kinet Catal Lett 2006;89:285-92. (Pubitemid 44705193)
25. 40 supported on carbon. Catal Lett 1994;27:187-97.
26. Spojakina A, Damyanova S, Shopov D, Shokhireva TKh, Yurieva TM. Thiophene hydrodesulfurization on P-Mo, Si-Mo and Ti-Mo catalysts. React Kinet Catal Lett 1985;27:333-6.
27. Damyanova S, Fierro JLG. Surface properties of titania-supported 12-molybdophosphoric acid hydrodesulphurization catalysts. Appl Catal A 1996;144:59-77. (Pubitemid 126387576)
28. 2-supported 12-molybdophosphate catalysts. Catal Lett 1997;49:223-7.
29. Damyanova S, Fierro JLG. Structural features and thermal stability of titania-supported 12-molybdophosphoric heteropoly compounds. Chem Mater 1998;10:871-9. (Pubitemid 128485553)
30. Damyanova S, Gómez LM, Bañares MA, Fierro JLG. Thermal behavior of 12-molybdophosphoric acid supported on zirconium-loaded silica. Chem Mater 2000;12:501-10.
31. Pizzio L, Vázquez P, Cáceres C, Blanco M. Tungstophosphoric and molybdophosphoric acids supported on zirconia as esterification catalysts. Catal Lett 2001;77:233-9. (Pubitemid 33617971)
32. Narasimha-Rao K, Mohan-Reddy K, Lingaiah N, Suryanarayana I, Sai-Prasad PS. Structure and reactivity of zirconium oxide-supported ammonium salt of 12-molybdophosphoric acid catalysts. Appl Catal A 2006;300:139-46. (Pubitemid 43038607)
33. Mohan-Reddy K, Balaraju M, Sai-Prasad PS, Suryanarayana I, Lingaiah N. Synthesis and characterization of zirconia supported vanadium incorporated ammonium salt of 12-molybdophosphoric acid catalyst for aerobic oxidation of benzyl alcohol. Catal Lett 2007;119:304-10. (Pubitemid 350160407)
34. 12) on mesoporous molecular sieves (HMS and MCM-41) and their catalytic behavior. Catal Lett 1996;42:201-8.
35. Jalil PA, Al-Daous MA, Al-Arfaj ARA, Al-Amer AM, Beltramini J, Barri SAI. Characterization of tungstophosphoric acid supported on MCM-41 mesoporous silica using n-hexane cracking, benzene adsorption, and X-ray diffraction. Appl Catal A 2001;207:159-71.
36. Gulbinska M, Wojtowski M, Laniecki M. Mesoporous materials as supports for heteropolyacid based catalysts. Stud Surf Sci Catal 2002;142:1221-8.
37. Jalil PA. Investigations on polyethylene degradation into fuel oil over tungstophosphoric acid supported on MCM-41 mesoporous silica. J Anal Appl Pyrol 2002;65:185-95. (Pubitemid 35264318)
38. 40 supported on MCM-41 molecular sieves: An effective catalyst for acetal formation. Appl Catal A 2005;295:185-92.
39. El Ali B, Tijani J, Fettouhi M, El-Faer M, Al-Arfaj A. Rhodium(I) and rhodium(III)-heteropolyacids supported on MCM-41 for the catalytic hydroformylation of styrene derivatives. Appl Catal A 2005;283:185-96.
40. Juan JC, Zhang J, Yarmo MA. 12-Tungstophosphoric acid supported on MCM-41 for esterification of fatty acid under solvent-free condition. J Mol Catal A 2007;267:265-71. (Pubitemid 46441922)
41. Llanos A, Melo L, Avendaño F, Montes A, Brito JL. Synthesis and characterization of HPW/MCM-41(Si) and HPW/MCM-41(Si/Al) catalysts: activity for toluene alkylation with 1-dodecene. Catal Today 2008;133-135:20-7.
42. Carriazo D, Domingo C, Martín C, Rives V. PMo or PW heteropoly acids supported on MCM-41 silica nanoparticles: characterisation and FT-IR study of the adsorption of 2-butanol. J Sol State Chem 2008;181:2046-57.
43. Madhusudhan-Rao P, Landau MV, Wolfson A, Shapira-Tchelet AM, Herskowitz M. Cesium salt of a heteropolyacid in nanotubular channels and on the external surface of SBA-15 crystals: preparation and performance as acidic catalysts. Micro Meso Mater 2005;80:43-55.
44. 40 heteropolyacid catalyst in alumina-grafted silica-gel and mesostructured SBA-15 silica matrices. J Catal 2005;232:210-25.
45. 40. J Mol Catal A 2005;229:199-205.
46. Lizama L, Klimova T. Highly active deep HDS catalysts prepared using Mo and W heteropolyacids supported on SBA-15. Appl Catal B 2008;82:139-50.
47. Palcheva R, Spojakina A, Dimitrov L, Jiratova K. 12-Tungstophosphoric heteropolyacid supported on modified SBA-15 as catalyst in HDS of thiophene. Micro Meso Mater 2009;122:128-34.
48. 40 supported on various porous silica-based materials. Micro Meso Mater 1998;22:151-63.
49. Damyanova S, Dimitrov L, Mariscal R, Fierro JLG, Petrov L, Sobrados I. Immobilization of 12-molybdophosphoric and 12-tungstophosphoric acids on metal-substituted hexagonal mesoporous silica. Appl Catal A 2003; 256:183-97.
50. Pawelec B, Damyanova S, Mariscal R, Fierro JLG, Sobrados I, Sanz J, et al. HDS of dibenzothiophene over polyphosphates supported on mesoporous silica. J Catal 2004;223:86-97.
51. Boahene PE, Soni K, Dalai AK, Adjaye J. Hydrotreating of coker light gas oil on Ti-modified HMS supports using Ni/HPMo catalysts. Appl Catal B 2011;101:294-305.
52. Zeng S, Blanchard J, Breysse M, Shi Y, Su X, Nie H, Li D. Mesoporous materials from zeolite seeds as supports for nickel-tungsten sulfide active phases: Part 2. Catalytic properties for deep hydrodesulfurization reactions. Appl Catal A 2006; 298:88-93.
53. Llanos A, Melo L, Mediavilla M, Albornoz LA, Díaz Y, Brito JL. Estudio mediante XPS de la interacción del HPW con soportes del tipo MCM-41(Si). Choroní (Venezuela): XVII Encuentro Venezolano de Catálisis; 2009.
54. Méndez FJ. Estudio de catalizadores activos para hidrodesulfuración con molibdeno como fase activa y promovida con níquel soportados sobre silicatos y aluminosilicatos del tipo MCM-41. Cumaná (Venezuela): Trabajo Especial de Grado: Licenciado en Química. Universidad de Oriente.; 2006.
55. Méndez FJ, Bastardo-González E, Betancourt P, Paiva J, Brito JL. NiMo/MCM-41 catalysts for hydrotreating of polychlorinated biphenyls. Catalysis Letters. http://dx.doi.org/10.10071s10562-012-0933-y.
56. Cid R, Pecchi G. Potentiometric method for determining the number and relative strength of acid sites in colored catalysts. Appl Catal 1985;14:15-21. (Pubitemid 15461990)
57. Kresge C, Leonowicz M, Roth W, Vartuli J, Beck J. Ordered mesoporous molecular sieves synthesized by liquid crystal template mechanism. Nature 1992;359:710-2. (Pubitemid 23589384)
58. Mokaya R. Mesoporous materials: synthesis and properties. In: Encyclopedia of Physical Science and Technology. Florida: Academic Press 2002;369-81.
59. Souza MJB, Araujo AS, Pedrosa AMG, Marinkovic BA, Jardim PM, Morgado E. Textural features of highly ordered Al-MCM-41 molecular sieve studied by X-ray diffraction, nitrogen adsorption and transmission electron microscopy. Mat Lett 2006;60:2682-5.
60. Desplantier-Giscard D, Galarneau A, Di Renzo F, Fajula F. Mechanical strength of nanosized hexagonal silica honeycombs. Mater Sci Eng C 2003;23:727-32. (Pubitemid 37507265)
61. Hodnett BK, Moffat JB. Application of temperature-programmed desorption to the study of heteropoly compounds: desorption of water and pyridine. J Catal 1984;88:253-63.
62. Pizzio LR, Cáceres CV, Blanco MN. Acid catalysts prepared by impregnation of tungstophosphoric acid solutions on different supports. Appl Catal A 1998;167:283-94. (Pubitemid 128408560)
63. Ghanbari-Siahkali A, Philippou A, Dwyer J, Anderson MW. The acidity and catalytic activity of heteropoly acid on MCM-41 investigated by MAS NMR, FTIR and catalytic tests. Appl Catal A 2000;192:57-69.
64. 40. J Catal 2001;197:273-80.
65. Rocchiccioli-Deltcheff C, Fournier M, Frank R, Thouvenot R. Vibrational investigations of polyoxometalates. Part 2. Evidence for anion-anion interactions in molybdenum(VI) and tungsten(VI) compounds related to the Keggin structure. Inorg Chem 1983;22:207-16.
66. Bridgeman AJ. Density functional study of the vibrational frequencies of α-Keggin heteropolyanions. Chem Phys 2003;287:55-69.
67. Chen N, Yang RT. Activation of nitric oxide by heteropoly compounds: Structure of nitric-oxide linkages in tungstophosphoric acid with Keggin units. J Catal 1995;157:76-86.
68. Rocchiccioli-Deltcheff C, Amirouche M, Fournier M. Structure and catalytic properties of silica-supported polyoxomolybdates. Part. III: 12-molybdosilicic acid catalysts: vibrational study of the dispersion effect and nature of the Mo species in interaction with the silica support. J Catal 1992;138:445-56.
69. Schacht P, Noreña-Franco L, Ancheyta J, Ramírez S, Hernández-Pérez I, García LA. Characterization of hydrothermally treated MCM-41 and Ti-MCM-41 molecular sieves. Catal Today 2004;98:115-21.
70. Leofanti G, Padovan M, Tozzola G, Venturelli B. Surface area and pore texture of catalysts. Catal Today 1998;41:207-19.
71. Barret EP, Joyner LJ, Halenda P. The determination of pore volume and area distributions in porous substances. Part I: Computations from nitrogen isotherms. J Am Chem Soc 1951;73:373-80.
72. 40 supported on mesoporous MCM-41 and Al-MCM-41 materials: preparation and characterisation. J Mater Sci 2011;46:7114-20.
73. Laine J, Brito J, Severino F. Carbon deposition and hydrodesulfurization activity of nickel-molybdenum supported catalysts. Appl Catal 1985;15:333-8. (Pubitemid 15490075)
74. 2 hydrodesulfurization catalysts. J Catal 1991;131:385-93.