An investigation into the properties of the ochre from Sibudu, KwaZulu-Natal, South Africa

Southern African Humanities

Volumn 24, Issue 1, 2012, Pages 99-120

  Hodgskiss, Tammy ^a  

^a UNIVERSITY OF THE WITWATERSRAND   (South Africa)

Author keywords

Colour; Geological form; Grain size; Hardness; Mica; Ochre; Selection preferences; Utilisation

Indexed keywords

EID: 84879041947     PISSN: 16815564     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (87)

1. th ed. Midrand: Portland Cement Institute.
2. Audouin, F. & Plisson, H. 1982. Les ochres et leurs témoins au Paléolithique en France: Enquête et expériences sur leur validité archéologique. Cahiers du Centre de Recherches Préhistoriques 8:33-80.
3. Barham, L. S. 1998. Possible early pigment use in South-Central Africa. Current Anthropology 39(5):703-10.
4. Barham, L. S. 2000. The Middle Stone Age of Zambia, south central Africa. Bristol: Western Academic & Specialist Press.
5. Barham, L. S. 2002. Systematic pigment use in the Middle Pleistocene of South-Central Africa. Current Anthropology 43(1):181-90.
6. Bentsen, S. E. 2012. Size matters: preliminary results from an experimental approach to interpret Middle Stone Age hearths. Quaternary International 270:95-102.
7. Bikiaris, D., Daniilia, S., Sotiropoulou, S., Katsimbiri, O., Pavlidou, E., Moutsatsou, A. P & Chryssoulakis, Y 1999. Ochre-differentiation through micro-Raman and micro-FTIR spectroscopies: application on wall paintings at Meteora and Mount Athos, Greece. Spectrochimica Acta Part A 56:3-18.
8. Blanchard, M., Lazzeri, M., Mauri, F & Balan, E. 2008. First-principles calculation of the infrared spectrum of hematite. American Mineralogist 93:1019-27.
9. Bonneau, A., Pearce, D. G. & Pollard, A. M. 2012. A multi-technique characterization and provenance study of the pigments used in San rock art, South Africa. Journal of Archaeological Science 39(2):287-94.
10. Brabers, AJ. M. 1976. Mineral pigments. In: C. B. Coetzee, ed., Mineral resources of the Republic of South Africa, fifth edition: handbook 7 of the Geological Survey, Department of Mines, South Africa. Pretoria: The Government Printer, pp. 391-3.
11. Clark, J. & Ligouis, B. 2010. Burned bone in the Howieson's Poort and post-Howieson's Poort Middle Stone Age deposits at Sibudu (South Africa): behavioral and taphonomic implications. Journal of Archaeological Science 37:2650-61.
12. Clarke, B. M., Schoeman, P & Kota, M. W 2007. The geology of the Verulam area. Pretoria: Council for Geoscience.
13. Cornell, R. M. & Schwertmann, U. 2003. The iron oxides: structure, properties, reactions, occurrences and uses. Weinheim: Wiley-VCH.
14. Coventry, RJ & Robinson, PJ. 1981. Colour groups derived from numerical classification of the Munsell Soil Colour chips. Australian Journal of Soil Research 19:103-12.
15. d'Errico, F, Vanhaeren, M. & Wadley, L. 2008. Possible shell beads from the Middle Stone Age layers of Sibudu Cave, South Africa. Journal of Archaeological Science 35:2675-85.
16. d'Errico, F, Vanhaeren, M., Henshilwood, C., Lawson, G., Maureille, B., Gambier, D., Tillier, A.-M., Soressi, M & van Niekerk, IK 2009. From the origin of language to the diversification of languages: what can archaeology and palaeo-anthropology say? In: F d'Errico & J.-M. Hombert, eds, Becoming eloquent: advances in the emergence of language, human cognition, and modern cultures. Amsterdam: John Benjamins, pp. 13-68.
17. d'Errico, F, Moreno, R. G. & Rifkin, R. 2012 Technological, elemental and colorimetric analysis of an engraved ochre fragment from the Middle Stone Age levels of Klasies River Cave 1, South Africa. Journal of Archaeological Science 39(4):942-52.
18. Edwards, H. G. M., Newton, E. M. & Russ, J. 2000. Raman spectroscopic analysis of pigments and substrata in prehistoric rock art. Journal of Molecular Structure 550-551:245-56.
19. Elias, M., Chartier, C., Prévot, G., Garay, H. & Vignaud, C. 2006. The colour of ochres explained by their composition. Materials Science and Engineering B 127:70-80.
20. Elvery, R. H. 1958. Concrete practice, Vol 1. London: Hastings & Folkestone.
21. Erlandson, J, M., Robertson, J. D. & Descantes, C. 1999. Geochemical analysis of eight red ochres from western North America. American Antiquity 64(3):517-26.
22. Fiore, D., Maier, M., Parera, S. D., Orquera, L. & Piana, E. 2008. Chemical analyses of the earliest pigment residues from the uttermost part of the planet (Beagle Channel region, Tierra del Fuego, Southern South America). Journal of Archaeological Science 35(12):3047-56.
23. Fritsch, E., Morin, G., Bedidi, A., Bonnin, D., Balan, E., Caquineau, S. & Calas, G. 2005. Transformation of haematite and Al-poor goethite to AI-rich goethite and associated yellowing in a ferralitic clay soil profile of the middle Amazon Basin (Manaus, Brazil). European Journal of Soil Science 56:575-88.
24. Fysh, S. A. & Clark, P. E. 1982. Alulminous goethite: Mössbauer study. Physics and chemistry of minerals 8:180-7.
25. Fysh, S. A. & Fredericks, P. M. 1983. Fourier transform infrared studies of aluminous goethites and hematites. Clays and Clay Minerals 31(5):377-82.
26. Gialanella, S., Belli, R., Dalmeri, G., Lonardelli, I., Mattarelli, M., Montagna, M. & Toniutti, L. 2011. Artificial or natural origin of hematite-based red pigments in archaeological contexts: the case of Riparo Dalmeri (Trento, Italy). Archaeometry 53(5):950-62.
27. Gil, M., Carvalho, M. L., Seruya, A., Candeias, A. E., Miräo, J. & Queralt, I. 2007. Yellow and red ochre pigments from southern Portugal: elemental composition and characterization by WDXRF and XRD. Nuclear Instruments and Methods in Physics Research A 580:728-31.
28. Godfrey-Smith, D. I. & Ilani, S. 2004. Past thermal history of goethite and hematite fragments from Qafzeh Cave deduced from thermal activation characteristics of the 110°C TL peak of enclosed quartz grains. Revue d'Archéométrie 28:185-90.
29. Henshilwood, C. S., Sealy, J., Yates, R., Cruz-Uribe, K., Goldberg, R., Grine, F. E., Klein, R. G., Poggenpoel, C., van Niekerk, K. & Watts, I. 2001. Blombos Cave, southern Cape, South Africa: preliminary report on 1992-1999 excavations of the Middle Stone Age levels. Journal of Archaeological Science 28:421-48.
30. Henshilwood, C. S., d'Errico, F., Yates, R., Jacobs, Z., Tribolo, C., Duller, G. A. T., Mercier, N., Sealy, J. C., Valladas, H., Watts, I., Wintle, & A. G. 2002. The emergence of modern behavior: Middle Stone Age engravings from South Africa. Science 295:1278-80.
31. Henshilwood, C. S., d'Errico, F. & Watts, I. 2009. Engraved ochres from the Middle Stone Age levels at Blombos Cave, South Africa. Journal of Human Evolution 57(1):27-47.
32. Henshilwood, C. S., d'Errico, F., van Niekerk, K. L., Coquinot, Y, Jacobs, Z., Lauritzen, S. E., Menu, M. & Moreno, R. G. 2011. A 100, 000-year-old ochre-processing workshop at Blombos Cave, South Africa. Science 334:219-22.
33. Hodgskiss, T. 2010. Identifying grinding, scoring and rubbing use-wear on experimental ochre pieces. Journal of Archaeological Science 37:3344-58.
34. Hovers, E., Ilani, S., Bar-Yosef, O. & Vandermeersch, B. 2003. An early case of colour symbolism: ochre use by modern humans in Qafzeh Cave. Current Anthropology 44(4):491-522.
35. Hradil, D., Grygar, T., Hradilová, J. & Bezdieka, P. 2003. Clay and iron oxide pigments in the history of painting. Applied Clay Science 22:223-36.
36. Hughes, J. C. & Solomon, A. 2000. A preliminary study of ochre and pigmentaceous materials from KwaZulu-Natal, South Africa: towards an understanding of San pigment and paint use. Natal Museum Journal of Humanities 12:15-31.
37. Iriarte, E., Foyo, A., Sánchez, M. A., Tomillo, C. & Setién, J. 2009. The origin and geochemical characterization of red ochres from the Tito Bustillo and Monte Castillo caves (northern Spain). Archaeometry 51(2):231-51.
38. 4. Solid State Communications 11:209-12.
39. Jacobs, Z., Roberts, R. G., Galbraith, P. F., Deacon, H. J., Grün, R., Mackay, A., Mitchell, P. J., Vogelsang, R. & Wadley, L. 2008a. Ages for the Middle Stone Age of southern Africa: implications for human behavior and dispersal. Science 322:733-35.
40. Jacobs, Z., Wintle, A. G., Duller, G. A. T., Roberts, R. G. & Wadley, L. 2008b. New ages for the post-Howiesons Poort, late and final Middle Stone Age at Sibudu, South Africa. Journal of Archaeological Science 35(7):1790-1807.
41. Jercher, M., Pring, A., Jones, P. G. & Raven, M. D. 1998. Rietveld X-Ray Diffraction and X-Ray Flourescence analysis of Australian Aboriginal ochres. Archaeometry 40(2):383-401.
42. rd ed. Glasgow: Edward Arnold.
43. Lombard, M. 2004. Distribution patterns of organic residues on Middle Stone Age points from Sibudu Cave, KwaZulu-Natal, South Africa. South African Archaeological Bulletin 59:37-44.
44. Lombard, M. 2005. Evidence for hunting and hafting during the Middle Stone Age at Sibudu Cave, KwaZulu-Natal, South Africa: a multianalytical approach. Journal of Human Evolution 48:279-300.
45. Lombard, M. 2006. Direct evidence for the use of ochre in the hafting technology of Middle Stone Age tools from Sibudu Cave. Southern African Humanities 18(1):57-67.
46. Lombard, M. 2007. The gripping nature of ochre: the association of ochre with Howiesons Poort adhesives and Later Stone Age mastics from South Africa. Journal of Human Evolution 53:406-19.
47. Lombard, M. 2008. Finding resolution for the Howiesons Poort through the microscope: micro-residue analysis of segments from Sibudu Cave, South Africa. Journal of Archaeological Science 35:26-41.
48. Lombard, M. 2011. Quartz-tipped arrows older than 60 ka: further use-trace evidence from Sibudu, Kwazulu-Natal, South Africa. Journal of Archaeological Science 38(8):1918-30.
49. Marean, C. W, Bar-Matthews, M., Bernatchez, J., Fisher, E., Goldberg, P., Herries, A. I. R., Jacobs, Z., Jerardino, A., Karkanas, P., Minichillo, T., Nilssen, P., Thompson, E., Watts, I., Williams, H. M. 2007. Early human use of marine resources and pigment in South Africa during the Middle Pleistocene. Nature 449:905-8.
50. Marshack, A. 2003. Comment on Hovers, E., Ilani, S., Bar-Yosef, O. & Vandermeersch, B. 2003. An early case of color symbolism: ochre use by modern humans in Qafzeh Cave. Current Anthropology 44:514-16.
51. Mastrotheodoros, G., Beltsios, K. G. & Zacharias, N. 2010. Assessment of the production of antiquity pigments through experimental treatment of ochres and other iron based precursors. Mediterranean Archaeology and Archaeometry 10(1):37-59.
52. Maud, R. R. 1965. Laterite and lateritic soil in coastal Natal, South Africa. Journal of Soil Science 16(1):60-72.
53. Mazzocchin, G. A., Agnoli, F., Mazzocchin, S. & Colpo, I. 2003. Analysis of pigments from Roman wall paintings found in Vicenza. Talanta 61:565-72.
54. Minzoni-Deroche, A., Menu, M. & Walter, P. 1995. The working of pigment during the Aurignacian period: evidence from Üçagizli cave (Turkey). Antiquity 69:153-8.
55. Munsell Colour Company. 2000. Munsell soil color charts. Baltimore: Munsell.
56. Pomies, M-P., Morin, G. & Vignaud, C. 1998. XRD study of the goethite-hematite transformation: application to the identification of heated prehistoric pigments. European Journal of Solid State and Inorganic Chemistry 35:9-25.
57. Pomies, M-P., Menu, M. & Vignaud, C. 1999. Red Palaeolithic pigments: natural hematite or heated goethite. Archaeometry 41(2):275-85.
58. Popelka-Filcoff, R. S., Robertson, J. D., Glascock, M. D. & Descantes, Ch. 2007. Trace element characterization of ochre from geological sources. Journal of Radioanalytical and Nuclear Chemistry 272(1):17-27.
59. Popelka-Filcoff, R. S., Miksa, E. J., Robertson, J. D., Glascock, M. D. & Wallace, H. 2008. Elemental analysis and characterization of ochre sources from southern Arizona. Journal of Archaeological Science 35:752-62.
60. Rifkin, R. 2011. Assessing the efficacy of red ochre as a prehistoric hide tanning ingredient.. Journal of African Archaeology 9(2):131-58.
61. Ruan, H. D., Frost, R. L. & Kloprogge, J. T 2001 The behavior of hydroxyl units of synthetic goethite and its dehydroxylated product hematite. Spectrochimica Acta Part A 57:2575-86.
62. Ruan, H. D., Frost, R. L., Kloprogge, J. T. & Duong, L. 2002. Infrared spectroscopy of goethite dehydroxylation. II. Effect of aluminium substitution on the behaviour of hydroxylunits. Spectrochimica Acta Part A 58:479-91.
63. Schwertmann, U. & Cornell, R. M. 1991. Iron oxides in the laboratory: preparation and characterization. Weinheim: Verlagsgesellschaft.
64. Sievers, C. & Wadley, L. 2008. Going underground: experimental carbonization of fruiting structures under hearths. Journal of Archaeological Science 35:2909-17.
65. Singer, R. & Wymer, J. 1982. The Middle Stone Age at Klasies River Mouth in South Africa. Chicago: University of Chicago Press.
66. Tucker, M. E. 1982. The field description of sedimentary rocks. Milton Keynes: Open University Press.
67. rd ed. Oxford: Blackwell Science.
68. Turner, D. P. 2000. Soils of KwaZulu-Natal and Mpumalanga: recognition of natural soil bodies. PhD thesis, University of Pretoria.
69. Vempati, R. K., Loeppert, R. H., Sitterrtz-Bhatkar, H. & Burghardt, R. C. 1990. Infrared vibrations of hematite formed from aqueous-and dry-thermal incubation of Si-containing ferrihydrite. Clays and Clay Minerals: 38(3):294-8.
70. Wadley, L. 2005a. Ochre crayons or waste products? Replications compared with MSA 'crayons' from Sibudu Cave, South Africa. Before Farming 2005/3:1-12.
71. Wadley, L. 2005b. Putting ochre to the test: replication studies of adhesives that may have been used for hafting tools in the Middle Stone Age. Journal of Human Evolution 49:587-601.
72. Wadley, L. 2006a. Revisiting cultural modernity and the role of ochre in the Middle Stone Age. In: H. Soodyall, ed, The prehistory of Africa: tracing the lineage f modern man. Johannesburg: Jonathan Ball, pp 60-77.
73. Wadley, L. 2006b. Partners in grime: results of multi-disciplinary archaeology at Sibudu Cave. Southern African Humanities 18(1):315-41.
74. Wadley, L. 2007. Announcing a Still Bay industry at Sibudu Cave, South Africa. Journal of Human Evolution 52:681-89.
75. Wadley, L. 2009. Post-depositional heating may cause over-representation of red-coloured ochre in Stone Age sites. South African Archaeological Bulletin 64:166-71.
76. Wadley, L. 2010a. A taphonomic study of ochre demonstrates post-depositional color transformations. Journal of Taphonomy 8:243-54.
77. Wadley, L. 2010b. Cemented ash as a receptacle or work surface for ochre powder production at Sibudu, South Africa, 58, 000 years ago. Journal of Archaeological Science 37(10):2397-406.
78. Wadley, L. & Jacobs, Z. 2006. Sibudu Cave: background to the excavations, stratigraphy and dating. Southern African Humanities 18(1):1-26.
79. Wadley, L., Williamson, B. S. & Lombard, M. 2004. Ochre in hafting in the Middle Stone Age southern Africa: a practical role. Antiquity 78(301):661-75.
80. Wadley, L., Hodgskiss, T. P & Grant, M. 2009. Implications for complex cognition from the hafting of tools with compound adhesives in the Middle Stone Age, South Africa. Proceedings of the National Academy of Science 106(24):9590-94.
81. Wadley, L., Sievers, C., Bamford, M., Goldberg, P, Berna, F. & Miller, C. 2011. Middle Stone Age bedding construction and settlement patterns at Sibudu, South Africa. Science 334:1388-91.
82. 3 particles. Colloids and Surfaces A: Physicochemical and Engineering Aspects 134:281-97.
83. Watts, I. 1998. The origin of symbolic culture: the Middle Stone Age of southern Africa and Khoisan ethnography. PhD thesis, University of London.
84. Watts, I. 2002. Ochre in the Middle Stone Age of southern Africa: ritualized display or a hide preservative? South African Archaeological Bulletin 57:1-14.
85. Watts, I. 2009. Red ochre, body painting, and language: interpreting the Blombos ochre. In: R. Botha & C. Knight, eds, The cradle of language. Oxford: Oxford University Press, pp 62-92.
86. Watts, I. 2010. The pigments from Pinnacle Point Cave 13B, Western Cape, South Africa. Journal of Human Evolution 59:392-411.
87. Williamson, B. S. 2004. Middle Stone Age tool function from residue analysis at Sibudu Cave. South African Journal of Science 100:174-8.