Vibrational dynamics and hydrogen bond properties of β-CD nanosponges: An FTIR-ATR, Raman and solid-state NMR spectroscopic study

Journal of Inclusion Phenomena and Macrocyclic Chemistry

Volumn 75, Issue 3-4, 2013, Pages 247-254

  Castiglione, F ^a   Crupi, V ^b   Majolino, D ^b   Mele, A ^a,c   Panzeri, W ^c   Rossi, B ^d   Trotta, F ^e   Venuti, V ^b  

^a POLITECNICO DI MILANO   (Italy)

^b UNIVERSITY OF MESSINA   (Italy)

^c CNR   (Italy)

^d UNIVERSITY OF TRENTO   (Italy)

^e UNIVERSITY OF TURIN   (Italy)

Author keywords

Cyclodextrin nanosponges; FTIR ATR spectroscopy; O H stretching; Raman spectroscopy; Solid state NMR spectroscopy

Indexed keywords

EID: 84878489836     PISSN: 09230750     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10847-012-0106-z     Document Type: Conference Paper

References (29)

1. Bender, M.L.; Komiyama, M.: Cyclodextrin chemistry. Springer, New York (1978)
2. Trotta, F.; Tumiatti, W.: Patent WO 03/085002 (2003)
3. Li, D.; Ma, M.: New organic nanoporous polymers and their inclusion complexes. Chem. Mater. 11, 872-874 (1999)
4. Trotta, F.; Tumiatti, W.; Cavalli, R.; Zerbinati, O.; Roggero, C. M.; Vallero, R.: Ultrasound-assisted synthesis of cyclodextrin-based nanosponges. Patent number WO 06/002814 (2006)
5. Cavalli, R.; Trotta, F.; Tumiatti, W.: Cyclodextrin-based nanosponges for drug delivery. J. Incl. Phenom. Macrocycl. Chem. 56, 209-213 (2006)
6. Trotta, F.; Cavalli, R.: Characterization and applications of new hyper-cross-linked cyclodextrins. Compos. Interface 16, 39-48 (2009)
7. Mele, A.; Castiglione, F.; Malpezzi, L.; Ganazzoli, F.; Raffaini, G.; Trotta, F.; Rossi, B.; Fontana, A.; Giunchi, G.: HR MAS NMR, powder XRD and Raman spectroscopy study of inclusion phenomena in βCD nanosponges. J. Incl. Phenom. Macrocycl. Chem. 69, 403-409 (2011)
8. Arkas, M.; Allabashi, R.; Tsiourvas, D.; Mattausch, E.-M.; Perfler, R.: Organic/inorganic hybrid filters based on dendritic and cyclodextrin ''nanosponges'' for the removal of organic pollutants from water. Environ. Sci. Technol. 40, 2771-2777 (2006)
9. Mhlanga, S.D.; Mamba, B.B.; Krause, R.W.; Malefetse, T.J.: Removal of organic contaminants from water using nanosponge cyclodextrin polyurethanes. J. Chem. Technol. Biotechnol. 82, 382-388 (2007)
10. Mamba, B.B.; Krause, R.W.; Malefetse, T.J.; Nxumalo, E.N.: Monofunctionalized cyclodextrin polymers for the removal of organic pollutants fromwater. Environ. Chem. Lett. 5, 79-84 (2007)
11. Mamba, B.B.; Krause, R.W.; Malefetse, T.J.; Gericke, G.; Sithole, S.P.: Cyclodextrin nanosponges in the removal of organic matter to produce water for power generation. Water SA 34, 657-660 (2008)
12. Swaminathan, S.; Vavia, P.R.; Trotta, F.; Torne, S.: Formulation of beta-cyclodextrin based nanosponges of itraconazole. J. Incl. Phenom. Macrocycl. Chem. 57, 89-94 (2007)
13. Vyas, A.; Shailendra, S.; Swarnlata, S.: Cyclodextrin based novel drug delivery systems. J. Incl. Phenom. Macrocycl. Chem. 62, 23-42 (2008)
14. Ansari, K.A.; Vavia, P.R.; Trotta, F.; Cavalli, R.: Cyclodextrin-based nanosponges for delivery of resveratrol: in vitro characterisation, stability, cytotoxicity and permeation study. AAPS Pharm. Sci. Tech. 12, 279-286 (2011)
15. Pines, A.; Gibby, M.; Waugh, J.S.: Proton-enhanced NMR in dilute spins in solids. J. Chem. Phys. 59, 569-573 (1973)
16. Mehring, M.: High-Resolution NMR Spectroscopy in Solids. Springer, New York (1983)
17. Stejskal, E.O.; Memory, J.D.: High-Resolution NMR in the Solid State. Fundamental of CP/MAS. Oxford University Press, Oxford (1994)
18. Maréchal, Y.: Observing the water molecule in macromolecules and aqueous media using infrared spectrometry. J. Mol. Struct. 648, 27-47 (2003)
19. Bennett, A.E.; Rienstra, C.M.; Auger, M.; Lakshmi, K.V.; Griffin, R.G.: Heteronuclear decoupling in rotating solids. J. Chem. Phys. 103, 6951-6958 (1995)
20. Crupi, V.; Longo, F.; Majolino, D.; Venuti, V.: Vibrational properties of water molecules adsorbed in different zeolitic frameworks. J. Phys. Condens. Matter 18, 3563-3580 (2006)
21. Crupi, V.; Longo, F.; Majolino, D.; Venuti, V.: T dependence of vibrational dynamics of water in ion-exchanged zeolites A: a detailed Fourier transform infrared attenuated total reflection study. J. Chem. Phys. 123, 154702 (2005)
22. Mallamace, F.; Broccio, M.; Corsaro, C.; Faraone, A.; Majolino, D.; Venuti, V.; Liu, L.; Mou, C.Y.; Chen, S.H.: Evidence of the existence of the low-density liquid phase in supercooled, confined water. Proc. Natl. Acad. Sci. USA 104, 424-428 (2007)
23. Crupi, V.; Ficarra, R.; Guardo, M.; Majolino, D.; Stancanelli, R.; Venuti, V.: UV-vis and FTIR-ATR spectroscopic techniques to study the inclusion complexes of genistein with β-cyclodextrins. J. Pharm. Biomed. Anal. 44, 110-117 (2007)
24. Gavira, J.M.; Hernanz, A.; Bratu, I.: Dehydration of β-cyclodextrin: an IR ν(OH) band profile analysis. Vib. Spectrosc. 32, 137-146 (2003)
25. Bratu, I.; Veiga, F.; Fernandes, C.; Hernanz, A.; Gavira, J.M.: Infrared spectroscopic study of triacetyl-β-cyclodextrin and its inclusion complex with nicapiridine. Spectroscopy 18, 459-467 (2004)
26. Stancanelli, R.; Ficarra, R.; Cannavà, C.; Guardo, M.; Calabrò, M.L.; Ficarra, P.; Ottanà, R.; Maccari, R.; Crupi, V.; Majolino, D.; Venuti, V.: UV-vis and FTIR-ATR characterization of 9-fluorenon-2-carboxyester/(2-hydroxypropyl)-β-cyclodextrin inclusion complex. J. Pharm. Biomed. Anal. 47, 704-709 (2008)
27. Cannavà, C.; Crupi, V.; Ficarra, P.; Guardo, M.; Majolino, D.; Stancanelli, R.; Venuti, V.: Physicochemical characterization of coumestrol/β-cyclodextrins inclusion complexes by UV-vis and FTIR-ATR spectroscopies. Vib. Spectrosc. 48, 172-178 (2008)
28. Crini, G.; Cosentino, C.; Bertini, S.; Naggi, A.; Torri, G.; Vecchi, C.; Janus, L.; Morcellet, M.: Solid state NMR spectroscopy study of molecular motion in cyclomaltoheptanose (β-cyclodextrin) crosslinked with epichlorohydrin. Carbohydr. Res. 308, 37-45 (1998)
29. Kolodziejski, W.; Klinowski, J.: Kinetics of cross-polarization in solid-state NMR: a guide for chemists. Chem. Rev. 102, 613-628 (2002)