Copolymerization of styrene and methyl methacrylate mediated by iron wire/N,N,N′,N′-tetramethyl-1,2-ethanediamine as catalyst in the presence of air

Iranian Polymer Journal (English Edition)

Volumn 22, Issue 2, 2013, Pages 109-116

  Wang, Guo Xiang ^a   Lu, Mang ^b   Li, Jing ^c   Liu, Li Chao ^a   Luo, Bei Ping ^a   Wu, Hu ^a   Zhong, Ming ^a  

^a HUNAN INSTITUTE OF SCIENCE AND TECHNOLOGY   (China)

^b JINGDEZHEN CERAMIC INSTITUTE   (China)

^c Tianjin Entry Exit Inspection and Quarantine Bureau   (China)

Author keywords

Living polymerization; Methyl methacrylate; Single electron transfer living radical copolymerization; Styrene; TMEDA

Indexed keywords

ACRYLIC MONOMERS; BENZENE; CATALYSTS; CHLORINE COMPOUNDS; DIMETHYLFORMAMIDE; ELECTRON TRANSITIONS; ESTERS; FREE RADICAL REACTIONS; IRON; IRON COMPOUNDS; LIVING POLYMERIZATION; MOLAR RATIO; ORGANIC SOLVENTS; POLYDISPERSITY; RATE CONSTANTS; STYRENE; SYNTHESIS (CHEMICAL); WIRE;

APPARENT RATE CONSTANT; LIVING RADICAL COPOLYMERIZATION; METHYL METHACRYLATES; N ,N-DIMETHYLFORMAMIDE; POLYDISPERSITY INDICES; SINGLE ELECTRON TRANSFER; SINGLE ELECTRON TRANSFER-LIVING RADICAL POLYMERIZATION (SET-LRP); TMEDA;

COPOLYMERIZATION;

EID: 84878479027     PISSN: 10261265     EISSN: 17355265     Source Type: Journal    
DOI: 10.1007/s13726-012-0109-z     Document Type: Article

References (27)

1. Matyjaszewski K, Xia J (2001) Atom transfer radical polymerization. Chem Rev 101:2921-2990
2. Kamigaito M, Ando T, Sawamoto M (2001) Metal-catalyzed living radical polymerization. Chem Rev 101:3689-3746
3. Limer A, Haddleton DM (2006) Reverse atom transfer radical polymerisation (RATRP) of methacrylates using copper(I)/pyridinimine catalysts in conjunction with AIBN. Eur Polym J 42:61-68
4. Ozturk T, Cakmak I (2008) Synthesis of poly(ethylene glycol-b-styrene) block copolymers by reverse atom transfer radical polymerization. J Polym Res 15:241-247
5. 2. Macromolecules 42:2330-2332
6. Zhu G, Zhang L, Zhang Z, Zhu J, Tu Y, Cheng Z (2011) Iron-mediated ICAR ATRP of methyl methacrylate. Macromolecules 44:3233-3239
7. Gromada J, Matyjaszewski K (2001) Simultaneous reverse and normal initiation in atom transfer radical polymerization. Macromolecules 34:7664-7671
8. Mueller L, Jakubowski W, Matyjaszewski K, Pietrasik J, Kwiatkowski P, Chaladaj W, Jurczak J (2011) Synthesis of high molecular weight polystyrene using AGET ATRP under high pressure. Eur Polym J 47:730-734
9. Li WW, Matyjaszewski K (2011) Cationic surface-active monomers as reactive surfactants for AGET emulsion ATRP of n-butyl methacrylate. Macromolecules 44:5578-5585
10. Jonsson M, Nystrom D, Nordin O, Malmstrom E (2009) Surface modification of thermally expandable microspheres by grafting poly(glycidyl methacrylate) using ARGET ATRP. Eur Polym J 45:2374-2382
11. Dong H, Matyjaszewski K (2008) ARGET ATRP of 2-(dimethylamino)ethyl methacrylate as an intrinsic reducing agent. Macromolecules 41:6868-6870
12. Turan E, Caykara T (2011) SET-LRP of N-isopropylacrylamide in the presence of chain transfer agent. J Polym Sci, Part A: Polym Chem 49:2818-2822
13. Vlček P, Raus V, Janata M, Kříž J, Sikora A (2011) Controlled grafting of cellulose esters using SET-LRP process. J Polym Sci, Part A: Polym Chem 49:164-173
14. Nguyen NH, Percec V (2011) Acid dissolution of copper oxides as a method for the activation of Cu(0) wire catalyst for SET-LRP. J Polym Sci, Part A: Polym Chem 49:4241-4252
15. Percec V, Guliashvili T, Ladislaw JS, Wistrand A, Stjerndahl A, Sienkowska MJ, Monteiro MJ, Sahoo S (2006) Ultrafast synthesis of ultrahigh molar mass polymers by metal-catalyzed living radical polymerization of acrylates, methacrylates, and vinyl chloride mediated by SET at 25 C. J Am Chem Soc 128:14156-14165
16. 2-type amphiphilic block copolymers composed of poly(ethylene glycol) and poly(N-isopropylacrylamide) via single-electron transfer living radical polymerization: synthesis and characterization. J Polym Sci, Part A: Polym Chem 47:4420-4427
17. Whittaker MR, Urbani CN, Monteiro MJ (2008) Synthesis of linear and 4-arm star block copolymers of poly(methyl acrylate-b-solketal acrylate) by SET-LRP at 25 C. J Polym Sci, Part A: Polym Chem 46:6346-6357
18. 3B miktoarm star copolymers prepared via a combination of SET-LRP and RAFT polymerization. J Polym Sci, Part A: Polym Chem 48:4268-4278
19. Zhai S, Song X, Yang D, Chen W, Hu J, Lu G, Huang X (2011) Synthesis of well-defined pH-responsive PPEGMEA-g-P2VP double hydrophilic graft copolymer via sequential SET-LRP and ATRP. J Polym Sci, Part A: Polym Chem 49:4055-4064
20. Zhai S, Wang B, Feng C, Li Y, Yang D, Hu J, Lu G, Huang X (2010) Thermoresponsive PPEGMEA-g-PPEGEEMA well-defined double hydrophilic graft copolymer synthesized by successive SET-LRP and ATRP. J Polym Sci, Part A: Polym Chem 48:647-655
21. Liu DL, Chen H, Yin P, Ji NY, Zong GX, Qu RJ (2011) Synthesis of polyacrylonitrile by single-electron transfer-living radical polymerization using Fe(0) as catalyst and its adsorption properties after modification. J Polym Sci, Part A: Polym Chem 49:2916-2923
22. Wang GX, Lu M, Wu H (2012) SET LRP of MMA mediated by Fe(0)/EDTA in the presence of air. Polym Bull 69:417-427
23. Gao J, Zhang Z, Zhou N, Cheng Z, Zhu J, Zhu X (2011) Copper(0)-mediated living radical copolymerization of styrene and methyl methacrylate at ambient temperature. Macromolecules 44:3227-3232
24. Wang GX (2012) Copolymerization of styrene and methyl methacrylate mediated by copper (0)/2,2′-bipyridine in the presence and absence of phenol. J Macromol Sci Part A Pure Appl Chem 49:55-59
25. Zhang HW, Hong KL, Mays JW (2002) Synthesis of block copolymers of styrene and methyl methacrylate by conventional free radical polymerization in room temperature ionic liquids. Macromolecules 35:5738-5741
26. Lligadas G, Percec V (2008) A comparative analysis of SET-LRP of MA in solvents mediating different degrees of disproportionation of Cu(I)Br. J Polym Sci, Part A: Polym Chem 46:6880-6895
27. Bednarek M, Biedroń T, Kubisa P (2000) Studies of atom transfer radical polymerization (ATRP) of acrylates by MALDI TOF mass spectrometry. Macromol Chem Phys 201:58-66