Photocatalytic degradation of a widely used insecticide Thiamethoxam in aqueous suspension of TiO2: Adsorption, kinetics, product analysis and toxicity assessment

Science of the Total Environment

Volumn 458-460, Issue , 2013, Pages 388-398

  Mir, Niyaz A ^a   Khan, A ^a   Muneer, M ^a   Vijayalakhsmi, S ^b  

^a ALIGARH MUSLIM UNIVERSITY   (India)

^b INDIAN INSTITUTE OF TECHNOLOGY BOMBAY   (India)

Author keywords

GC MS; Photocatalysis; Semiconductor; Thiamethoxam; TiO2

Indexed keywords

EQUILIBRIUM ADSORPTION CONSTANT; GC-MS; PHOTO CATALYTIC DEGRADATION; PHOTOCATALYZED DEGRADATION; PSEUDO-FIRST ORDER KINETICS; SPECTRO-PHOTOMETRIC METHOD; THIAMETHOXAM; TIO;

ADSORPTION; CATALYSTS; DEGRADATION; INSECTICIDES; KINETICS; PHOTOCATALYSIS; PHOTODEGRADATION; SEMICONDUCTOR MATERIALS; TOXICITY;

TITANIUM DIOXIDE;

AMMONIUM PERSULPHATE; HYDROGEN PEROXIDE; INORGANIC SALT; INSECTICIDE; POTASSIUM BROMATE; THIAMETHOXAM; TITANIUM DIOXIDE; UNCLASSIFIED DRUG;

ADSORPTION; CATALYSIS; DEGRADATION; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; PHOTOCHEMISTRY; REACTION KINETICS; THIAMETHOXAM; TOXICITY;

ADSORPTION KINETICS; AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CONCENTRATION (PARAMETERS); CONTROLLED STUDY; DEGRADATION KINETICS; HUMAN; HUMAN CELL; IN VITRO STUDY; MASS FRAGMENTOGRAPHY; PH; PHOTOLYSIS; PRIORITY JOURNAL; TOXICITY TESTING; WASTE MANAGEMENT;

ADSORPTION; CATALYSIS; ERYTHROCYTES; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; HUMANS; INSECTICIDES; KINETICS; MOLECULAR STRUCTURE; NITRO COMPOUNDS; OXAZINES; PHOTOCHEMICAL PROCESSES; THIAZOLES; TITANIUM; WATER;

EID: 84877900476     PISSN: 00489697     EISSN: 18791026     Source Type: Journal    
DOI: 10.1016/j.scitotenv.2013.04.041     Document Type: Article

References (52)

1. 2 photocatalytic oxidation of metol. Identification of intermediates and reaction pathways. Water Res 2002, 36:3582-3592.
2. Ahmad M.K., Amani S., Mahmood R. Potassium bromate causes cell lysis and induces oxidative stress in human erythrocytes. Environ Toxicol 2011, 10.1002/tox.20780.
3. Ahmed S., Rasul M.G., Brown R., Hashib M.A. Influence of parameters on the heterogeneous photocatalytic degradation of pesticides and phenolic contaminants in wastewater: a short review. J Environ Manage 2011, 92:311-330.
4. Bahnemann D.W., Cunningham J., Fox M.A., Pelizzetti E., Pichat P., Serpone N. Aquatic surface photochemistry 1994, 261. Lewis Publishers, Boca Raton. R.G. Zeep, G.R. Helz, D.G. Crosby (Eds.).
5. Bahnemann W., Muneer M., Haque M.M. Titanium dioxide-mediated photocatalysed degradation of few selected organic pollutants in aqueous suspensions. Catal Today 2007, 124:133-148.
6. Bickley R.I., Carreno T.G., Lees J.S., Palmisano L., Tilley R.J.D. A structural investigation of titanium dioxide photocatalysts. J Solid State Chem 1991, 92:178-190.
7. Bijlsma L., Boix C., Niessen W.M.A., Ibáñez M., Sancho J.V., Hernándeza F. Investigation of degradation products of cocaine and benzoylecgonine in the aquatic environment. Sci Total Environ 2013, 443:200-208.
8. Bouzaida I., Ferronato C., Chevelon J.M., Rammah M.E., Herrmann J.M. Heterogeneous photocatalytic degradation of the anthraquinonic dye, Acid Blue 25 (AB25): a kinetic approach. J Photochem Photobiol A Chem 2004, 168:23-30.
9. Chitra S., Paramasivan K., Cheralathan M., Sinha P.K. Degradation of 1, 4-dioxane using advanced oxidation processes. Environ Sci Pollut Res 2012, 19:871-878.
10. 2 suspensions with the help of hydrogen peroxide by different near UV irradiations. Water Res 2004, 38:1037-1043.
11. De Urzedo A.P.F.M., Diniz M.E.R., Nascentes C.C., Catharino R.R., Eberlin M.N., Augusti R. Photolytic degradation of the insecticide thiamethoxam in aqueous medium monitored by direct infusion electrospray ionization mass spectrometry. J Mass Spectrom 2007, 42:1319-1325.
12. 4 composite. J Braz Chem Soc 2009, 20:51-56.
13. 2 photocatalysis. J Environ Manage 2012, 98:168-174.
14. Fielden R., Meth-Cohn O., Suschitgky H. Thermal and photolytic cyclisation, rearrangement, and denitration reactions of o-nitro-t-anilines. Tetrahedron Lett 1970, 11:1229-1234.
15. GOA Government of Australia National Registration Authority for Agricultural and Veterinary Chemicals 2001, Canberra, Australia. [http://www.apvma.gov.au/registration/assessment/docs/prs_thiamethoxam.pdf].
16. Gouvêa C.A.K., Wypych F., Moraes O.S.G., Durán W., Nagata N., Zamora P.P. Semiconductor-assisted photocatalytic degradation of reactive dyes in aqueous solution. Chemosphere 2000, 40:433-440.
17. Hanna K., de Brauer C., Germain P., Chovelon J.M., Ferronato C. Degradation of pentachlorophenol in cyclodextrin extraction effluent using a photocatalytic process. Sci Total Environ 2004, 332:51-60.
18. 2-mediated photocatalytic degradation of a textile dye derivative, bromothymol blue, in aqueous suspensions. Dyes Pigments 2007, 75:443-448.
19. HCPMRA Health Canada Pest Management Regulatory Agency, Regulatory Note REG2001-03 2001, Health Canada Pest Management Regulatory Agency, Ottawa, ON, [http://www.hc-sc.gc.ca/cps-spc/pubs/pest/_decisions/reg2001-03/index-eng.php].
20. Hiegendorff H. Untersuchungen zur Bedeutung der Adsorption in der Photokatalyse 1996, Department of Chemistry, University of Hannover, Hannover, Germany, [Ph.D. thesis].
21. Ho C.-H., Chen L., Yang C.L. Electrochemical decomposition of Reactive Blue 19. Environ Eng Sci 2011, 28:53-61.
22. 2 using EPR. J Phys Chem B 2003, 107:4545-4549.
23. Khan A., Haque M.M., Mir N.A., Muneer M., Boxall C. Heterogeneous photocatalysed degradation of an insecticide derivative acetamiprid in aqueous suspensions of semiconductor. Desalination 2010, 261:169-174.
24. 2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations: a review. Appl Catal B Environ 2004, 49:1-14.
25. 2 powders as highly active photocatalysts. J Sol Energy Eng 1997, 119:120-125.
26. Lopes R.P., De Urzedo A.P.F.M., Nascentes C.C., Augusti R. Degradation of the insecticides thiamethoxam and imidacloprid by zero-valent metals exposed to ultrasonic irradiation in water medium: electrospray ionization mass spectrometry monitoring. Rapid Commun Mass Spectrom 2008, 22:3472-3480.
27. 2. Sep Purif Technol 2008, 62:423-436.
28. Maienfisch P., Angst M., Brandl F., Fischer W., Hofer D., Kayser H., et al. Chemistry and biology of thiamethoxam: a second generation neonicotinoids. Pest Manag Sci 2001, 57:906-913.
29. 2, photoreactivity and size quantization. J Chem Soc Faraday Trans 1994, 90:3315-3322.
30. 2 photocatalysts-a review. Environ Sci Pollut Res 2012, 19:3676-3687.
31. Muccio A.D., Fidente P., Barbini D.A., Dommarco R., Seccia S., Morrica P. Application of solid-phase extraction and liquid chromatography-mass spectrometry to the determination of neonicotinoid pesticide residues in fruit and vegetables. J Chromatogr A 2006, 1108:1-6.
32. Muneer M., Bahnemann D. Semiconductor-mediated photocatalyzed degradation of two selected pesticide derivatives, terbacil and 2, 4, 5-tribromoimidazole, in aqueous suspension. Appl Catal B Environ 2002, 36:95-111.
33. 2-suspension. Sol Energy Mater Sol Cells 2004, 81:439-457.
34. Neadle D.J., Pollitt R.J. The photolysis of N-2,4-dinitrophenylamino-acids to give 2-substituted 6-nitrobenzimidazole-1-oxides. J Chem Soc C 1967, 1764-1766.
35. Ollis D.F., Pelizzetti E., Serpone N. Photocatalyzed destruction of water contaminants. Environ Sci Technol 1991, 25:1522-1529.
36. 2 suspensions. Environ Sci Pollut Res 2010, 17:1158-1166.
37. 2 based catalysts. Catal Today 2005, 101:211-218.
38. Preston P.N., Tennant G. Synthetic methods involving neighboring group interaction in ortho-substitute nitrobenzene derivatives. Chem Rev 1972, 72:627-677.
39. Qamar M., Muneer M., Bahnemann D. Heterogeneous photocatalysed degradation of two selected pesticide derivatives, triclopyr and daminozid in aqueous suspensions of titanium dioxide. J Environ Manage 2006, 80:99-106.
40. Rauer S. Untersunchung von kommerziell erhaltlichen Titandioxiden hinsichtlich ihrer photokatalytischen Aktivtat 1998, fachhochschule Hannover, Fachbereich Maschinenbau Vertiefung Umwelt-und Verfahrenstechnil, Hannover, Germany, [Diplomarbeit].
41. Robinson P. Evaluation of the new active Thiamethoxam in the product Cruiser 350 FS insecticide seed treatment 2001, National Registration Authority for Agricultural and Veterinary Chemicals, Australia.
42. Rosenfeldt E.J., Chen P.J., Kullman S., Linden K.G. Destruction of estrogenic activity in water using UV advanced oxidation. Sci Total Environ 2007, 377:105-113.
43. 2 photocatalyst. Chemosphere 2007, 67:1010-1017.
44. So C.M., Cheng M.Y., Yu J.C., Wong P.K. Degradation of azo dye Procion Red MX-5B by photocatalytic oxidation. Chemosphere 2002, 46:905-912.
45. 3 hybrid processes: kinetics, degradation intermediates and toxicity. J Hydrol 2012, 472-473:314-327.
46. 2 nanoarray films: preparation and photocatalytic activity. J Alloy Compd 2010, 494:372-377.
47. 2 nanotube film photocatalysts prepared by liquid-phase deposition. Int J Photoenergy 2012, [Article ID 702940]. 10.1155/2012/702940.
48. Wardman P. Reduction potentials of one-electron couples involving free radicals in aqueous solution. J Phys Chem Ref Data 1989, 18:1637-1717.
49. 2-photocatalyzed degradation of acetophenone under different light intensity. J Photochem Photobiol A Chem 2000, 133:67-71.
50. 2 of three selected neonicotinoid insecticides: imidacloprid, thiamethoxam and clothianidin. Chemosphere 2012, 89:293-301.
51. Zheng L.-Q., Liu G.-G., Sun D.-Z. Study on the hydrolysis and photolysis of thiamethoxam. J Harbin Inst Technol 2006, 38:1005-1008.
52. 2. J Environ Manage 2012, 101:1-6.