Separating catalytic activity at edges and terraces on platinum: Hydrogen dissociation

Journal of Physical Chemistry C

Volumn 117, Issue 18, 2013, Pages 9266-9274

  Groot, I M N ^a,b   Kleyn, A W ^a,b,c   Juurlink, L B F ^a  

^a LEIDEN UNIVERSITY   (Netherlands)

^b FOM INSTITUTE DIFFER   (Netherlands)

^c UNIVERSITY OF AMSTERDAM   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

ACCURATE PREDICTION; CATALYTIC ABILITY; CATALYTIC SURFACES; ESSENTIAL FEATURES; HYDROGEN DISSOCIATION; LOCAL ENVIRONMENTS; REACTION CROSS-SECTIONS; REACTION DYNAMICS;

CATALYSIS; CATALYST ACTIVITY; PLATINUM; REACTION KINETICS; SEPARATION;

DISSOCIATION;

EID: 84877689637     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp401355c     Document Type: Article

References (45)

1. Ertl, G. Reactions at Surfaces: From Atoms to Complexity (Nobel Lecture) Angew. Chem., Int. Ed. 2008, 47, 3524-3535
2. Somorjai, G. A.; Li, Y. M. Impact of Surface Chemistry Proc. Natl. Acad. Sci. U.S.A. 2011, 108, 917-924
3. Bernasek, S. L.; Siekhaus, W. J.; Somorjai, G. A. Molecular-Beam Study of Hydrogen-Deuterium Exchange on Low-Miller-Index Platinum Single-Crystal Surfaces Phys. Rev. Lett. 1973, 30, 1202-1204
4. Bernasek, S. L.; Somorjai, G. A. Molecular Beam Study of Mechanism of Catalyzed Hydrogen-Deuterium Exchange on Platinum Single-Crystal Surfaces J. Chem. Phys. 1975, 62, 3149-3161
5. Gale, R. J.; Salmeron, M.; Somorjai, G. A. Variation of Surface-Reaction Probability with Reactant Angle of Incidence: A Molecular Beam Study of Asymmetry of Stepped Platinum Crystal Surfaces for H-H Bond Breaking Phys. Rev. Lett. 1977, 38, 1027-1029
6. 2 Exchange-Reaction on Stepped Platinum Crystal Surfaces: Dependence of Reactant Angle of Incidence J. Chem. Phys. 1977, 67, 5324-5334
7. 2 Exchange-Reaction on Pt(111) and Pt(332) Crystal Surfaces J. Chem. Phys. 1979, 70, 2807-2818
8. 2 Dissociation on Stepped Platinum Angew. Chem., Int. Ed. 2011, 50, 5174-5177
9. Vattuone, L.; Savio, L.; Rocca, M. Bridging the Structure Gap: Chemistry of Nanostructured Surfaces at Well-Defined Defects Surf. Sci. Rep. 2008, 63, 101-168
10. Norskov, J. K.; Abild-Pedersen, F.; Studt, F.; Bligaard, T. Density Functional Theory in Surface Chemistry and Catalysis Proc. Natl. Acad. Sci. U.S.A. 2011, 108, 937-943
11. Norskov, J. K.; Bligaard, T.; Hvolbaek, B.; Abild-Pedersen, F.; Chorkendorff, I.; Christensen, C. H. The Nature of the Active Site in Heterogeneous Metal Catalysis Chem. Soc. Rev. 2008, 37, 2163-2171
12. Vanhove, M. A.; Somorjai, G. A. New Microfacet Notation for High-Miller-Index Surfaces of Cubic Materials with Terrace, Step and Kink Structures Surf. Sci. 1980, 92, 489-518
13. Hellman, A.; Honkala, K.; Remediakis, I. N.; Logadottir, A.; Carlsson, A.; Dahl, S.; Christensen, C. H.; Norskov, J. K. Ammonia Synthesis and Decomposition on a Ru-Based Catalyst Modeled by First-Principles Surf. Sci. 2009, 603, 1731-1739
14. Honkala, K.; Hellman, A.; Remediakis, I. N.; Logadottir, A.; Carlsson, A.; Dahl, S.; Christensen, C. H.; Norskov, J. K. Ammonia Synthesis from First-Principles Calculations Science 2005, 307, 555-558
15. Jones, G.; Jakobsen, J. G.; Shim, S. S.; Kleis, J.; Andersson, M. P.; Rossmeisl, J.; Abild-Pedersen, F.; Bligaard, T.; Helveg, S.; Hinnemann, B. First Principles Calculations and Experimental Insight into Methane Steam Reforming over Transition Metal Catalysts J. Catal. 2008, 259, 147-160
16. 4 Angew. Chem., Int. Ed. 2011, 50, 4601-4605
17. Van Hardeveld, R.; Van Montoort, A. Influence of Crystallite Size on Adsorption of Molecular Nitrogen on Nickel, Palladium and Platinum: An Infrared and Electron-Microscopic Study Surf. Sci. 1966, 4, 396-430
18. 2 Dissociative Adsorption on the Pt(211) Stepped Surface J. Chem. Phys. 2005, 122, 044701
19. 2 Dissociative Adsorption on the Pt(211) Stepped Surface J. Chem. Phys. 2008, 128, 194715
20. Gee, A. T.; Hayden, B. E.; Mormiche, C.; Nunney, T. S. The Role of Steps in the Dynamics of Hydrogen Dissociation on Pt(533) J. Chem. Phys. 2000, 112, 7660-7668
21. Groot, I. M. N.; Schouten, K. J. P.; Kleyn, A. W.; Juurlink, L. B. F. Dynamics of Hydrogen Dissociation on Stepped Platinum J. Chem. Phys. 2008, 129, 224707
22. 2 from a Metal Surface is Electronically Adiabatic Science 2006, 312, 86-89
23. 2 Dissociative Chemisorption on Pt(111) J. Chem. Phys. 1990, 93, 5240-5246
24. Samson, P.; Nesbitt, A.; Koel, B. E.; Hodgson, A. Deuterium Dissociation on Ordered Sn/Pt(111) Surface Alloys J. Chem. Phys. 1998, 109, 3255-3264
25. Poelsema, B.; Lenz, K.; Comsa, G. The Dissociative Adsorption of Hydrogen on Defect-'Free' Pt(111) J. Phys.: Condens. Mat. 2010, 22, 304006
26. Poelsema, B.; Lenz, K.; Comsa, G. The Dissociative Adsorption of Hydrogen on Pt(111): Actuation and Acceleration by Atomic Defects J. Chem. Phys. 2011, 134, 074703
27. Riedmüller, B.; Giskes, F.; van Loon, D. G.; Lassing, P.; Kleyn, A. W. A Compact Molecular Beam Line Meas. Sci. Technol. 2002, 13, 141-149
28. Backus, E. H. G.; Eichler, A.; Grecea, M. L.; Kleyn, A. W.; Bonn, M. Adsorption and Dissociation of NO on Stepped Pt(533) J. Chem. Phys. 2004, 121, 7946-7954
29. Gohndrone, J. M.; Masel, R. I. A TPD Study of Nitric-Oxide Decomposition on Pt(100), Pt(411) and Pt(211) Surf. Sci. 1989, 209, 44-56
30. Mukerji, R. J.; Bolina, A. S.; Brown, W. A. An Investigation of the Effect of Pre-Dosed O Atoms on the Adsorption of NO on Pt{211} Surf. Sci. 2003, 547, 27-44
31. Mukerji, R. J.; Bolina, A. S.; Brown, W. A. The Influence of Steps on the Dissociation of NO on Pt Surfaces: Temperature-Programmed Desorption Studies of NO Adsorption on Pt{211} J. Chem. Phys. 2003, 119, 10844-10852
32. Mukerji, R. J.; Bolina, A. S.; Brown, W. A. A RAIRS and TPD Investigation of the Adsorption of CO on Pt{211} Surf. Sci. 2003, 527, 198-208
33. Sugisawa, T.; Shiraishi, J.; Machihara, D.; Irokawa, K.; Miki, H.; Kodama, C.; Kuriyama, T.; Kubo, T.; Nozoye, H. Adsorption and Decomposition of NO on Pt(112) Appl. Surf. Sci. 2001, 169, 292-295
34. Xu, J. Z.; Yates, J. T. Terrace Width Effect on Adsorbate Vibrations: A Comparison of Pt(335) and Pt(112) for Chemisorption of CO Surf. Sci. 1995, 327, 193-201
35. 2 Single Crystals Surf. Sci. 1968, 11, 82-98
36. Henzler, M. LEED-Investigations of Step Arrays on Cleaved Germanium (111) Surfaces Surf. Sci. 1970, 19, 159-171
37. King, D. A.; Wells, M. G. Reaction-Mechanism in Chemisorption Kinetics: Nitrogen on {100} Plane of Tungsten Proc. R. Soc. London,. Ser. A 1974, 339, 245-269
38. 2 on Single-Crystal Surfaces of Platinum Surf. Sci. 1974, 45, 677-695
39. Groot, I. M. N. The Fight for a Reactive Site; Leiden University: Leiden, The Netherlands, 2009.
40. Tully, J. C. Chemical Dynamics at Metal Surfaces Annu. Rev. Phys. Chem. 2000, 51, 153-178
41. Kindt, J. T.; Tully, J. C. Simulations of Collision-Induced Absorption of Hydrogen on Ni(111) J. Chem. Phys. 1999, 111, 11060-11069
42. Maynard, K. J.; Johnson, A. D.; Daley, S. P.; Ceyer, S. T. A New Mechanism for Absorption: Collision-Induced Absorption Faraday Discuss. 1991, 91, 437-449
43. 4 on Ni(111) by Inert-Gas Atoms: The Mechanism for Chemistry with a Hammer J. Chem. Phys. 1989, 91, 5756-5777
44. 2 Dissociative Adsorption on Ru(0001) ChemPhysChem 2008, 9, 2372-2378
45. Rostrup-Nielsen, J.; Norskov, J. K. Step Sites in Syngas Catalysis Top. Catal. 2006, 40, 45-48