High capacity cobalt boride prepared via vacuum freeze-drying method and used as anode material for alkaline secondary battery

Journal of Renewable and Sustainable Energy

Volumn 5, Issue 2, 2013, Pages

  Bai, Ying ^a   Pang, Chunhui ^a   Hu, Wenlong ^a   Wu, Feng ^a   Wu, Chuan ^a   Yang, Liwei ^a   Bao, Li Ying ^a  

^a BEIJING INSTITUTE OF TECHNOLOGY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ALKALINE SECONDARY BATTERIES; CHARGE-DISCHARGE TESTS; CHEMICAL REDUCTION METHODS; ELECTROCHEMICAL ACTIVITIES; FREEZE DRYING METHOD; HIGH SPECIFIC SURFACE AREA; HIGH-TEMPERATURE SOLID-PHASE; NITROGEN ADSORPTION-DESORPTION;

ALKALINITY; ANODES; BALL MILLING; CHEMICAL STABILITY; COBALT; CYCLIC VOLTAMMETRY; LOW TEMPERATURE DRYING; PARTICLE SIZE ANALYSIS; SCANNING ELECTRON MICROSCOPY; SECONDARY BATTERIES; SPECIFIC SURFACE AREA; VACUUM; X RAY DIFFRACTION;

BORIDES;

EID: 84877253414     PISSN: 19417012     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.4798422     Document Type: Conference Paper

References (16)

1. C. Wu, Y. Bai, F. Wu, X. Wang, J. Y. Lu, and C. Qiao, Novel ternary metal boride Mg-Co-B alloys as anode materials for alkaline secondary batteries., Electrochem. Commun. 11, 2173-2176 (2009). 10.1016/j.elecom.2009.09.023
2. Y. Liu, Y. J. Wang, and L. L. Wang, Structure and electrochemical behaviors of a series of Co-B alloys. Electrochim. Acta 53, 2265-2271 (2008). 10.1016/j.electacta.2007.09.052
3. X. P. Gao and H. X. Yang, Multi-electron reaction materials for high energy density batteries., Energy Environ. Sci. 3, 165-240 (2010).
4. C. Wu, Y. Bai, and X. Wang, Comparisons of Co-B alloys synthesized via different methods for secondary alkaline batteries., Solid State Ionics 179, 924-927 (2008). 10.1016/j.ssi.2008.01.077
5. C. Wu, Y. Bai, F. Wu, L. W. Dong, X. Wang, and L. X. Yang, Structural evolutions and electrochemical behaviors of Co-B alloys as anode materials for alkaline secondary batteries., Electrochim. Acta 53, 4715-4720 (2008). 10.1016/j.electacta.2008.01.082
6. D. G. Tong, D. Wang, and W. Chu, Cobalt-boron amorphous alloy prepared in water/cetyl-trimethyl-ammonium bromide/n-hexanol microemulsion as anode for alkaline secondary batteries., Electrochim. Acta 55, 2299-2305 (2010). 10.1016/j.electacta.2009.11.082
7. D. G. Tong, W. Chu, Y. Y. Luo, H. Chen, and X. Y. Ji, Preparation and characterization of amorphous Co-B catalysts with mesoporous structure., J. Mol. Catal. A: Chem. 269, 149-157 (2007). 10.1016/j.molcata.2007.01.016
8. 4 solution for in situ hydrogen supply of portable fuel cells., Catal. Today 170, 33-39 (2011). 10.1016/j.cattod.2011.01.046
9. 4 catalyzed with cobalt boride., Int. J. Hydrogen Energy 36, 2145-2153 (2011). 10.1016/j.ijhydene.2010.11.036
10. V. I. Simagina, O. V. Komova, A. M. Ozerova, O. V. Netskina, G. V. Odegova, Cobalt oxide catalyst for hydrolysis of sodium borohydride and ammonia borane., Appl. Catal. A-Gen. 394, 86-92 (2011). 10.1016/j.apcata.2010.12.028
11. A. M. Ozerova, V. I. Simagina, O. V. Komova, Cobalt borate catalysts for hydrogen production via hydrolysis of sodium borohydride., J. Alloys Compd. 513, 266-272 (2012). 10.1016/j.jallcom.2011.10.033
12. X. L. Ding, X. X. Yuan, C. Jia, and Z. F. Ma, Hydrogen generation from catalytic hydrolysis of sodium borohydride solution using cobalt-copper-boride (Co-Cu-B) catalysts., Int. J. Hydrogen Energy 35, 11077-11084 (2010). 10.1016/j.ijhydene.2010.07.030
13. C. Wu, C. H. Pang, F. Wu, Y. Bai, C. Chen, and Y. Zhong, Effects of the pre-freezing time on the structures and electrochemical performances of Co-B alloys., Adv. Mater. Res. 391-392, 1085-1089 (2012). 10.4028/www.scientific.net/ AMR.391-392.1085
14. C. Wu, F. Wu, Y. Bai, B. L. Yi, and H. M. Zhang, Cobalt boride catalysts for hydrogen generation from alkaline NaBH4 solution., Mater. Lett. 59, 1748-1751 (2005). 10.1016/j.matlet.2005.01.058
15. Y. D. Wang, X. P. Ai, and H. X. Yang, Electrochemical hydrogen storage behaviors of ultrafine amorphous Co-B alloy., Chem. Mater. 16, 5194-5197 (2004). 10.1021/cm049252f
16. Y. Bai, C. Wu, F. Wu, L. X. Yang, and B. R. Wu, Investigation of FeB alloy prepared by an electric arc method and used as the anode material for alkaline secondary batteries., Electrochem. Commun. 11, 145-148 (2009). 10.1016/j.elecom.2008.09.038