2-Mercaptobenzimidazole as a copper corrosion inhibitor: Part I. Long-term immersion, 3D-profilometry, and electrochemistry

Corrosion Science

Volumn 72, Issue , 2013, Pages 82-89

  Finšgar, Matjaž ^a  

^a UNIVERSITY OF MARIBOR   (Slovenia)

Author keywords

A. Copper; B. EIS; B. Polarization; B. Weight loss; C. Neutral inhibition

Indexed keywords

2-MERCAPTO-BENZIMIDAZOLE; AQUEOUS NACL SOLUTIONS; B. EIS; CORROSION INHIBITION PERFORMANCE; DIFFUSION-CONTROLLED PROCESS; NEUTRAL INHIBITIONS; SEMI-INFINITE DIFFUSION; WEIGHT LOSS;

CHARGE TRANSFER; COPPER CORROSION; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; METAL IONS; PROFILOMETRY; THREE DIMENSIONAL COMPUTER GRAPHICS;

CORROSION INHIBITORS;

EID: 84877081857     PISSN: 0010938X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.corsci.2013.03.011     Document Type: Article

References (69)

1. Sastri V.S. Corrosion Inhibitors: Principles and Applications 2001, John Wiley & Sons, Chichester, p. 759.
2. Finšgar M., Milošev I. Inhibition of copper corrosion by 1,2,3-benzotriazole: a review. Corros. Sci. 2010, 52:2737-2749.
3. Finšgar M., Milošev I. Corrosion study of copper in the presence of benzotriazole and its hydroxy derivative. Mater. Corro. - Werks. Korro. 2011, 62:956-966.
4. Kokalj A., Kovačević N., Peljhan S., Finšgar M., Lesar A., Milošev I. Triazole, benzotriazole, and naphthotriazole as copper corrosion inhibitors: I. Molecular electronic and adsorption properties. ChemPhysChem 2011, 12:3547-3555.
5. Kuznetsov Y.I., Kazansky L.P. Physicochemical aspects of metal protection by azoles as corrosion inhibitors. Russ. Chem. Rev. 2008, 77:219.
6. Antonijević M.M., Petrović M.B. Copper corrosion inhibitors. A review. Int. J. Electrochem. Sci. 2008, 3:1-28.
7. Milić S.M., Antonijević M.M. Some aspects of copper corrosion in presence of benzotriazole and chloride ions. Corros. Sci. 2009, 51:28-34.
8. Antonijević M.M., Milić S.M., Petrović M.B. Films formed on copper surface in chloride media in the presence of azoles. Corros. Sci. 2009, 51:1228-1237.
9. Kazansky L.P., Selyaninov I.A., Kuznetsov Y.I. Adsorption of 2-mercaptobenzothiazole on copper surface from phosphate solutions. Appl. Surf. Sci. 2012, 258:6807-6813.
10. Chadwick D., Hashemi T. Electron spectroscopy of corrosion inhibitors: surface films formed by 2-mercaptobenzothiazole and 2-mercaptobenzimidazole on copper. Surf. Sci. 1979, 89:649-659.
11. Perrin F.X., Pagetti J. Characterization and mechanism of direct film formation on a Cu electrode through electro-oxidation of 2-mercaptobenzimidazole. Corros. Sci. 1998, 40:1647-1662.
12. Trachli B., Keddam M., Takenouti H., Srhiri A. Protective effect of electropolymerized 2-mercaptobenzimidazole upon copper corrosion. Prog. Org. Coat. 2002, 44:17-23.
13. Xue G., Huang X.-Y., Dong J., Zhang J. The formation of an effective anti-corrosion film on copper surfaces from 2-mercaptobenzimidazole solution. J. Electroanal. Chem. Interfacial Electrochem. 1991, 310:139-148.
14. Sun S., Geng Y., Tian L., Chen S., Yan Y., Hu S. Density functional theory study of imidazole, benzimidazole and 2-mercaptobenzimidazole adsorption onto clean Cu(111) surface. Corros. Sci. 2012, 63:140-147.
15. Izquierdo J., Santana J.J., González S., Souto R.M. Scanning microelectrochemical characterization of the anti-corrosion performance of inhibitor films formed by 2-mercaptobenzimidazole on copper. Prog. Org. Coat. 2012, 74:526-533.
16. Wang L. Evaluation of 2-mercaptobenzimidazole as corrosion inhibitor for mild steel in phosphoric acid. Corros. Sci. 2001, 43:2281-2289.
17. Wang L., Pu J.-X., Luo H.-C. Corrosion inhibition of zinc in phosphoric acid solution by 2-mercaptobenzimidazole. Corros. Sci. 2003, 45:677-683.
18. Niamien P.M., Essy F.K., Trokourey A., Yapi A., Aka H.K., Diabate D. Correlation between the molecular structure and the inhibiting effect of some benzimidazole derivatives. Mater. Chem. Phys. 2012, 136:59-65.
19. Altaf F., Qureshi R., Ahmed S. Surface protection of copper by azoles in borate buffers-voltammetric and impedance analysis. J. Electroanal. Chem. 2011, 659:134-142.
20. Santana J.J., Pähler M., Schuhmann W., Souto R.M. Investigation of copper corrosion inhibition with frequency-dependent alternating-current scanning electrochemical microscopy. ChemPlusChem 2012, 77:707-712.
21. Finšgar M. 2-Mercaptobenzimidazole as a copper corrosion inhibitor: part II. Surface analysis using X-ray photoelectron spectroscopy. Corros. Sci. 2013, 72:90-98.
22. Assouli B., Ait Chikh Z.A., Idrissi H., Srhiri A. Electrosynthesis of adherent poly(2-mercaptobenzimidazole) films on brass prepared in nonaqueous solvents. Polymer 2001, 42:2449-2454.
23. Zhang D.-q., Gao L.-x., Zhou G.-d., Inhibition of copper corrosion in aerated hydrochloric acid solution by heterocyclic compounds containing a mercapto group Corros. Sci. 2004, 46:3031-3040.
24. Guo S., Xue G., Qian Y. Interfacial modification of polymer/metal joints by a two-component coupling system of polybenzimidazole and 2-mercaptobenzimidazole. Appl. Surf. Sci. 1995, 84:351-356.
25. Carron K.T., Lewis M.L., Dong J., Ding J., Xue G., Chen Y. Surface-enhanced Raman scattering and cyclic voltammetry studies of synergetic effects in the corrosion inhibition of copper by polybenzimidazole and mercaptobenzimidazole at high temperature. J Mater. Sci. 1993, 28:4099-4103.
26. Hosseini M., Tavakoli H., Shahrabi T. Synergism in copper corrosion inhibition by sodium dodecylbenzenesulphonate and 2-mercaptobenzoimidazole. J. Appl. Electrochem. 2008, 38:1629-1636.
27. Popova A., Sokolova E., Raicheva S., Christov M. AC and DC study of the temperature effect on mild steel corrosion in acid media in the presence of benzimidazole derivatives. Corros. Sci. 2003, 45:33-58.
28. Finšgar M., Kovač J., Milošev I. Surface analysis of 1-hydroxybenzotriazole and benzotriazole adsorbed on Cu by X-ray photoelectron spectroscopy. J. Electrochem. Soc. 2010, 157:C52-C60.
29. Finšgar M., Milošev I. Corrosion behaviour of stainless steels in aqueous solutions of methanesulfonic acid. Corros. Sci. 2010, 52:2430-2438.
30. 2O thickness on BTAH-inhibited copper by reconstruction of auger electron spectra. J. Electrochem. Soc. 2010, 157:C295-C301.
31. Kokalj A., Peljhan S., Finšgar M., Milošev I. What determines the inhibition effectiveness of ATA, BTAH, and BTAOH corrosion inhibitors on copper?. J. Am. Chem. Soc. 2010, 132:16657-16668.
32. G 61-86 Conducting Cyclic Potentiodynamic Polarization Measurements for Localized Corrosion Susceptibility of Iron-, Nickel-, or Cobalt-Based Alloys, in: ASTM International, 2003.
33. Massart D.L., Vandeginste B.G.M., Buydens L.M.C., Jong S.D., Lewi P.J., Smeyers-Verbeke J. Handbook of Chemometrics and Qualimetrics: Part A 1997, Elsevir, Amsterdam.
34. Van Ingelgem Y., Tourwé E., Vereecken J., Hubin A. Application of multisine impedance spectroscopy, FE-AES and FE-SEM to study the early stages of copper corrosion. Electrochim. Acta 2008, 53:7523-7530.
35. Orazem E.M., Tribollet B. Electrochemical Impedance Spectroscopy 2008, John Wiley & Sons, Inc., Hoboken, New Jersey.
36. Cicileo G.P., Rosales B.M., Varela F.e., Vilche J.R. Comparative study of organic inhibitors of coppercorrosion. Corros. Sci. 1999, 41:1359-1375.
37. 2O film and a natural corrosion scale as corrosion inhibitors. Corros. Sci. 2000, 42:1801-1822.
38. Trachli B., Keddam M., Takenouti H., Srhiri A. Protective effect of electropolymerized 3-amino 1,2,4-triazole towards corrosion of copper in 0.5 M NaCl. Corros. Sci. 2002, 44:997-1008.
39. Rahmouni K., Keddam M., Srhiri A., Takenouti H. Corrosion of copper in 3% NaCl solution polluted by sulphide ions. Corros. Sci. 2005, 47:3249-3266.
40. Tüken T., Yazi{dotless}ci{dotless} B., Erbil M. The use of polyindole for prevention of copper corrosion. Surf. Coat. Technol. 2006, 200:4802-4809.
41. Diard J.P., Le Canut J.M., Le Gorrec B., Montella C. Copper electrodissolution in 1M HCl at low current densities. II. Electrochemical impedance spectroscopy study. Electrochim. Acta 1998, 43:2485-2501.
42. Fenelon A.M., Breslin C.B. The electrochemical synthesis of polypyrrole at a copper electrode: corrosion protection properties. Electrochim. Acta 2002, 47:4467-4476.
43. Badawy W.A., Ismail K.M., Fathi A.M. Effect of Ni content on the corrosion behavior of Cu-Ni alloys in neutral chloride solutions. Electrochim. Acta 2005, 50:3603-3608.
44. Valcarce M.B., Sánchez S.R., Vázquez M. A comparative analysis of copper and brass surface films in contact with tap water. J. Mater. Sci. 2006, 41:1999-2007.
45. F. Brizuela, R. Procaccini, S. Cer, M. zquez, Anodically grown films on copper and coppernickel alloys in slightly alkaline solutions, J. Appl. Electrochem. 36 583-590.
46. Srivastava A., Balasubramaniam R. Microstructural characterization of copper corrosion in aqueous and soil environments. Mater. Charact. 2005, 55:127-135.
47. Sherif E.M., Park S.-M. Inhibition of copper corrosion in 3.0% NaCl solution by N-phenyl-1,4-phenylenediamine. J. Electrochem. Soc. 2005, 152:B428-B433.
48. Metikoš-Huković M., Babić R., Paić I. Copper corrosion at various pH values with and without the inhibitor. J. Appl. Electrochem. 2000, 30:617-624.
49. Metikoš-Huković M., Babić R., Marinović A. Spectrochemical characterization of benzotriazole on copper. J. Electrochem. Soc. 1998, 145:4045-4051.
50. Babić R., Metikoš-Huković M. Spectroelectrochemical studies of protective surface films against copper corrosion. Thin Solid Films 2000, 359:88-94.
51. Babić R., Metikoš-Huković M., Lončar M. Impedance and photoelectrochemical study of surface layers on Cu and Cu-10Ni in acetate solution containing benzotriazole. Electrochim. Acta 1999, 44:2413-2421.
52. Hayon J., Yarnitzky C., Yahalom J., Bettelheim A. Surface processes characterization for the corrosion of copper in borate solutions - I. The effect of sodium dodecylsulfate. J. Electrochem. Soc. 2002, 149:B314-B320.
53. Lukács Z. The numerical evaluation of the distortion of EIS data due to the distribution of parameters. J. Electroanal. Chem. 1997, 432:79-83.
54. Lukács Z. Evaluation of model and dispersion parameters and their effects on the formation of constant-phase elements in equivalent circuits. J. Electroanal. Chem. 1999, 464:68-75.
55. Macdonald J.R. Power-law exponents and hidden bulk relation in the impedance spectroscopy of solids. J. Electroanal. Chem. 1994, 378:17-29.
56. Macdonald J.R. Generalizations of "universal dielectric response" and a general distribution-of-activation-energies model for dielectric and conducting systems. J. Appl. Phys. 1985, 58:1971-1978.
57. Macdonald J.R. Frequency response of unified dielectric and conductive systems involving an exponential distribution of activation energies. J. Appl. Phys. 1985, 58:1955-1970.
58. Macdonald J.R. Linear relaxation: distributions, thermal activation, structure, and ambiguity. J. Appl. Phys. 1987, 62:R51-R62.
59. Hurt R.L., Macdonald J.R. Distributed circuit elements in impedance spectroscopy: a unified treatment of conductive and dielectric systems. Solid State Ionics 1986, 20:111-124.
60. Lebrini M., Lagrenée M., Vezin H., Gengembre L., Bentiss F. Electrochemical and quantum chemical studies of new thiadiazole derivatives adsorption on mild steel in normal hydrochloric acid medium. Corros. Sci. 2005, 47:485-505.
61. de Souza F.S., Spinelli A. Caffeic acid as a green corrosion inhibitor for mild steel. Corros. Sci. 2009, 51:642-649.
62. Amin M.A., Abd El-Rehim S.S., El-Sherbini E.E.F., Bayoumi R.S. The inhibition of low carbon steel corrosion in hydrochloric acid solutions by succinic acid: part I. Weight loss, polarization, EIS, PZC, EDX and SEM studies. Electrochim. Acta 2007, 52:3588-3600.
63. McCafferty E., Hackerman N. Double layer capacitance of iron and corrosion inhibition with polymethylene diamines. J. Electrochem. Soc. 1972, 119:146-154.
64. Poling G.W. Reflection infra-red studies of films formed by benzotriazole on Cu. Corros. Sci. 1970, 10:359-370.
65. Silverman D.C. Practical corrosion prediction using electrochemical techniques. Uhlig Corrosion Handbook 2000, 1179-1225. John Wiley and Sons, NY. R.W. Revie (Ed.).
66. Mansfeld F., Kendig M. Technical note: concerning the choice of scan rate in polarization measurements. Corrosion 1981, 37:545-546.
67. Tromans D., Sun R.h. Anodic polarization behavior of copper in aqueous chloride/benzotriazole solutions. J. Electrochem. Soc. 1991, 138:3235-3244.
68. Bacarella A.L., Griess J.C. The anodic dissolution of copper in flowing sodium chloride solutions between 25 and 175 °C. J. Electrochem. Soc. 1973, 120:459-465.
69. Finšgar M., Lesar A., Kokalj A., Milošev I. A comparative electrochemical and quantum chemical calculation study of BTAH and BTAOH as copper corrosion inhibitors in near neutral chloride solution. Electrochim. Acta 2008, 53:8287-8297.