Quantum critical point and spin fluctuations in lower-mantle ferropericlase

Proceedings of the National Academy of Sciences of the United States of America

Volumn 110, Issue 18, 2013, Pages 7142-7147

  Lyubutin, Igor S ^a   Struzhkin, Viktor V ^b   Mironovich, A A ^c   Gavriliuk, Alexander G ^a,b,c   Naumov, Pavel G ^a   Lin, Jung Fu ^d   Ovchinnikov, Sergey G ^e,f   Sinogeikin, Stanislav ^g   Chow, Paul ^g   Xiao, Yuming ^g   Hemley, Russell J ^b  

^a SHUBNIKOV INSTITUTE OF CRYSTALLOGRAPHY   (Russian Federation)

^b GEOPHYSICAL LABORATORY   (United States)

^c RUSSIAN ACADEMY OF SCIENCES   (Russian Federation)

^d UNIVERSITY OF TEXAS AT AUSTIN   (United States)

^e KIRENSKY INSTITUTE OF PHYSICS   (Russian Federation)

^f SIBERIAN FEDERAL UNIVERSITY   (Russian Federation)

^g CARNEGIE INSTITUTION OF WASHINGTON   (United States)

Author keywords

Diamond anvil cell; Mott insulator; Spin crossover; Synchrotron radiation

Indexed keywords

FERROPERICLASE; FERROUS ION; IRON; IRON DERIVATIVE; UNCLASSIFIED DRUG;

ACCELERATION; ARTICLE; CALCULATION; CONTROLLED STUDY; ELECTRONICS; LOW TEMPERATURE; MAGNETISM; MOSSBAUER SPECTROSCOPY; PHYSICAL CHEMISTRY; PRIORITY JOURNAL; QUANTUM MECHANICS; SYNCHROTRON MOSSBAUER SPECTROSCOPY; THEORETICAL MODEL; TRANSMISSION ELECTRON MICROSCOPY;

EID: 84876932877     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.1304827110     Document Type: Article

References (52)

1. Pushcharovskii DY (2002) Minerals of the deep geospheres. Phys Usp 45(4):439-444.
2. Jeanloz R, Knittle E (1989) Density and composition of the lower mantle. Philos Trans R Soc London Ser A 328(1599):377-389.
3. Shearman DM (1991) The high-pressure electronic structure of magnesiowustite (Mg,Fe)O: Applications to the physics and chemistry of the lower mantle. J Geophys Res 96(B9):14299-14312.
4. Pushcharovskii DY (1980) The earth's deep minerals. Rus J Nature (Priroda) 11:119-120.
5. Lee KKM, et al. (2004) Equations of state of the high-pressure phases of a natural peridotite and implications for the earth's lower mantle. Earth Planet Sci Lett 223(3-4):381-393. (Pubitemid 38889303)
6. Chalabov RI, Lyubutin IS, Zhmurova ZI, Dodokin AP, Dmitrieva TV (1982) Mossbauer study of the non-stoichiometry defects in wustite crystals. Sov Phys Crystallogr 27(3):312-315.
7. Lin JF, et al. (2006) Pressure-induced electronic spin transition of iron in magnesio-wustite-(Mg,Fe)O. Phys Rev B 73(11):113107.
8. Kantor IY, Dubrovinsky LS, McCommon CA (2006) Spin crossover in (Mg,Fe)O: A Mossbauer effect study with an alternative interpretation of x-ray emission spectroscopy. Phys Rev B 73(10):100101.
9. Gavriliuk AG, Lin JF, Lyubutin IS, Struzhkin VV (2006) Optimization of the conditions of synchrotron Mossbauer experiment for studying electronic transitions at high pressure by the example of (Mg, Fe)O magnesiowustite. JETP Lett 84(3):161-166. (Pubitemid 44505721)
10. Lin JF, Struzhkin VV, Gavriliuk AG, Lyubutin IS (2007) Comment on "Spin crossover in (Mg,Fe)O: A Mossbauer effect study with an alternative interpretation of x-ray emission spectroscopy data. Phys Rev B 75(17):177102.
11. Li J (2007) Post-Perovskite: The Last Mantle Phase Transition, eds Hirose JBK, Lay T, Yuen D (American Geophysical Union, Washington, DC).
12. Lin JF, Jacobsen SD, Wentzcovitch RM (2007) Electronic spin transition of iron in the earth's deep mantle. Eos 88:13-24.
13. Lin JF, et al. (2009) Synchrotron Mössbauer spectroscopic study of ferropericlase at high pressures and temperatures. Am Mineral 94(4):594-599.
14. 0.25O magnesiowustite at high pressures under hydrostatic conditions. JETP Lett 90(9):617-622.
15. Goncharov AF, Struzhkin VV, Jacobsen SD (2006) Reduced radiative conductivity of low-spin (Mg,Fe)O in the lower mantle. Science 312(5777):1205-1208. (Pubitemid 43801144)
16. Keppler H, Kantor IY, Dubrovinsky LS (2007) Optical absorption of spectra ferropericlase to 84 GPa. Am Mineral 92(2-3):433-436. (Pubitemid 46416369)
17. Lin JF, Weir ST, Jackson DD, Evans WJ, Yoo CS (2007) Electrical conductivity of the lower-mantle ferropericlase across the electronic spin transition. Geophys Res Lett 34(16):L16305.
18. Lin JF, et al. (2005) Spin transition of iron in magnesiowüstite in the earth's lower mantle. Nature 436(7049):377-380.
19. Fei Y, et al. (2007) Spin transition and equation of state of (Mg,Fe)O solid solutions. Geophys Res Lett 34(17):17307.
20. Lin JF, et al. (2005) Sound velocities of hot dense iron: Birch's law revisited. Science 308(5730):1892-1894.
21. Speziale S, et al. (2005) Iron spin transition in Earth's mantle. Proc Natl Acad Sci USA 102(50):17918-17922. (Pubitemid 41798477)
22. 3. JETP Lett 77(12):676-679.
23. Ovchinnikov SG (2005) The mechanism of the electronic transition in ferroborates under high pressure. J Phys Condens Matter 17(11):S743-S751.
24. Wertheim GK ed (1964) Mossbauer Effect. Principles and Applications (Academic, New York).
25. Rusakov VS (2000) Mössbauer Spectroscopy of Locally Heterogeneous Systems [Messbauerovskaya Spektroskopiya Lokal'no Neodnorodnykh Sistem]. (Nuclear Physics Institute, Almaty, Kazakhstan). Russian.
26. Roth WL (1960) Defects in the crystal and magnetic structures of ferrous oxides. Acta Crystallogr 13(2):140-149.
27. Ziman JM (1979) Models of Disorder (Cambridge Univ Press, Cambridge, UK).
28. Cotton E (1960) Emission and absorption of gamma-rays without recoil of the emitting nucleus, held in a crystal lattice (Mossbauer effect). J Phys Radium 21(5):265-287.
29. Smirnov GV (1999) General properties of nuclear resonant scattering. Hyperfine Interact 123-124(1-4):31-77.
30. Shyd'ko YV (1999) Nuclear resonant forward scattering of x-rays: Time and space picture. Phys Rev B 59(14):9132-9143.
31. Sachdev S (2001) Quantum Phase Transition (Cambridge Univ Press, Cambridge, UK).
32. Nesterov AI, Ovchinnikov SG (2009) Spin crossover: The quantum phase transition induced by high pressure. JETP Lett 90(7):530-534.
33. 4 Heisenberg magnet. JETP Lett 84(9):518-523.
34. Lyubutin IS, Gavriliuk AG (2009) Research on phase transformations in 3d-metal oxides at high and ultrahigh pressure: State of the art. Phys. Usp 52(10):989-1017.
35. Gavriliuk AG, et al. (2008) Another mechanism for the insulator-metal transition observed in Mott insulators. Phys Rev B 77(15):155112.
36. Lin JF, et al. (2007) Spin transition zone in Earth's lower mantle. Science 317(5845):1740-1743.
37. 3 at high pressures. Sov Phys JETP 99(3):566-573.
38. Tanabe Y, Sugano S (1954) On the absorption spectra of complex ions II. J Phys Soc Jpn 9:766-779.
39. 3. Phys Rev B 67(17):172401.
40. 3 studied using soft x-ray absorption spectroscopy and magnetic circular dichroism. Phys Rev Lett 97(17):176405.
41. 3 taking into account strong electron correlations. Sov Phys JETP 112(1):140-151.
42. Sturhahn W, Jackson JM, Lin JF (2005) The spin state of iron in mineral of Earth's lower mantle. Geophys Res Lett 32:L12307.
43. Tsuchiya T, Wentzcovitch RM, da Silva CRS, de Gironcoli S (2006) Spin transition in magnesiowüstite in earth's lower mantle. Phys Rev Lett 96(19):198501.
44. Wu Z, et al. (2009) Anomalous thermodynamical properties of ferropericlase throughout its spin crossover transition. Phys Rev B 80(1):014409.
45. Wentzcovitch RM, et al. (2009) Anomalous compressibility of ferropericlase throughout the iron spin cross-over. Proc Natl Acad Sci USA 106(21):8447-8452.
46. Hsu H, Umemoto K, Wu Z, Wentzcovitch RM (2010) Spin-state crossover of iron in lower-mantle mineral: Results of DFT+U investigations. Rev Mineral Geochem 71:169-199.
47. Xu Y, Shankland TJ, Poe BT (2000) Laboratory-based electrical conductivity in the earth's mantle. J Geophys Res 105(B12):27865.
48. Zerr A, Boehler R (1994) Constraints on the melting temperature of the lower mantle from high-pressure experiments on MgO and magnesiowustite. Nature 371:506-508.
49. Vocadlo L, Price GD (1996) The melting of MgO - Computer calculations via molecular dynamics. Phys Chem Miner 23:42-49.
50. Cohen RE, Gong Z (1994) Melting and melt structure of MgO at high pressures. Phys Rev B 50(17):12301-12311.
51. 1-xO). Am Mineral 83(7-8):794-798.
52. Gavriliuk AG, Mironovich AA, Struzhkin VV (2009) Miniature diamond anvil cell for broad range of high pressure measurements. Rev Sci Instrum 80(4):043906.