Carbamoyl anion addition to N -sulfinyl imines: Highly diastereoselective synthesis of α-amino amides

Journal of the American Chemical Society

Volumn 135, Issue 15, 2013, Pages 5565-5568

  Reeves, Jonathan T ^a   Tan, Zhulin ^a   Herbage, Melissa A ^a   Han, Zhengxu S ^a   Marsini, Maurice A ^a   Li, Zhibin ^a   Li, Guisheng ^a   Xu, Yibo ^a   Fandrick, Keith R ^a   Gonnella, Nina C ^a   Campbell, Scot ^a   Ma, Shengli ^a   Grinberg, Nelu ^a   Lee, Heewon ^a   Lu, Bruce Z ^a   Senanayake, Chris H ^a  

^a BOEHRINGER INGELHEIM PHARMACEUTICALS INC   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANION STRUCTURES; CARBONYL GROUPS; COMPUTATIONAL STUDIES; DIASTEREO-SELECTIVITY; DIASTEREOSELECTIVE SYNTHESIS; LITHIUM DIISOPROPYLAMIDE; STEREOSELECTIVE SYNTHESIS; SULFINYL IMINES;

AMIDES; CHEMICAL COMPOUNDS; ITERATIVE METHODS; LITHIUM; NEGATIVE IONS; STEREOCHEMISTRY;

STEREOSELECTIVITY;

ALPHA AMINO AMIDE; AMIDE; ANION; CARBAMOYL ANION; CARBONYL DERIVATIVE; FORMAMIDE DERIVATIVE; IMINE; LITHIUM; N SULFINYL IMINE; NUCLEOPHILE; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CHIRALITY; CONTROLLED STUDY; SPECTROSCOPY; STEREOCHEMISTRY;

AMIDES; CHEMISTRY TECHNIQUES, SYNTHETIC; DIPEPTIDES; IMINES; MODELS, MOLECULAR; MOLECULAR CONFORMATION; STEREOISOMERISM; SUBSTRATE SPECIFICITY;

EID: 84876486629     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja402647m     Document Type: Article

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