Infinite dilution activity coefficients and Henry's law constants of compounds in water using the inert gas stripping method

Fluid Phase Equilibria

Volumn 348, Issue , 2013, Pages 45-51

  Brockbank, Sarah A ^a   Russon, Jenna L ^a   Giles, Neil F ^a   Rowley, Richard L ^a   Wilding, W Vincent ^a  

^a Brigham Young University   (United States)

Author keywords

Henry's law constant; Inert gas stripping; Infinite dilution activity coefficient

Indexed keywords

ACTIVITY COEFFICIENTS; DILUTION;

1-BUTANOL; AMBIENT PRESSURES; FUGACITY RATIO; GAS STRIPPING; HEAT OF FUSION; HENRY'S LAW CONSTANT; INFINITE DILUTION ACTIVITY COEFFICIENTS; SOLID SOLUTES;

INERT GASES;

EID: 84876457650     PISSN: 03783812     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fluid.2013.03.023     Document Type: Article

References (39)

1. Chemistry Assistance Manual for Premanufacture Notification Submitters, in: U.S. Environmental Protection Agency (Ed.), 1997.
2. Nielsen, F., Olsen, E., Fredenslund, A., Henry's law constants and infinite dilution activity coefficients for volatile organic compounds in water by a validated batch air stripping method. Environ. Sci. Technol. 28 (1994), 2133–2138.
3. Yaws, C., Yang, H.-C., Pan, X., Henry's law constants for 362 organic compounds in water. Chem. Eng. 98 (1991), 179–185.
4. Dearden, J.C., Schüürmann, G., Quantitative structure–property relationships for predicting Henry's law constant from molecular structure. Environ. Toxicol. Chem. 22 (2003), 1755–1770.
5. Moore, R.C., Henry's law constant for environmentally significant compounds. Appl. Biochem. Biotechnol. 34-5 (1992), 671–680.
6. Smith, F.L., Harvey, A.H., Avoid common pitfalls when using Henry's law. Chem. Eng. Prog. 103 (2007), 33–39.
7. Prausnitz, J.M., Lichtenthaler, R.N., Gomes de Azevedo, E., Molecular Thermodynamics of Fluid-Phase Equilibria. third ed., 1999, Prentice Hall PTR, Upper Sadle River.
8. Mackay, D., Shiu, W.Y., A critical review of Henry's law constants for chemicals of environmental interest. J. Phys. Chem. Ref. Data 10 (1981), 1175–1199.
9. Staudinger, J., Roberts, P.V., A critical review of Henry's law constants for environmental applications. Crit. Rev. Environ. Sci. Technol. 26 (1996), 205–297.
10. Leroi, J.C., Masson, J.C., Renon, H., Fabries, J.F., Sannier, H., Accurate measurement of activity coefficients at infinite dilution by inert gas stripping and gas chromatography. Ind. Eng. Chem., Process Des. Dev. 16 (1977), 139–144.
11. Mackay, D., Shiu, W.Y., Sutherland, R.P., Determination of air–water Henry's law constants for hydrophobic pollutants. Environ. Sci. Technol. 13 (1979), 333–337.
12. Krummen, M., Gruber, D., Gmehling, J., Measurement of activity coefficients at infinite dilution in solvent mixtures using the dilutor technique. Ind. Eng. Chem. Res. 39 (2000), 2114–2123.
13. Smith, J.M., Van Ness, H.C., Abbott, M.M., Introduction to chemical engineering thermodynamics. seventh ed., 2005, McGraw-Hill, New York.
14. ® Data Compilation of Pure Chemical Properties. 2011, Design Institute for Physical Properties, AIChE, New York, NY.
15. Lei, Y.D., Shunthirasingham, C., Wania, F., Comparison of headspace and gas-stripping techniques for measuring the air–water partitioning of normal alkanols (C4 to C10): effect of temperature, chain length, and adsorption to the water surface. J. Chem. Eng. Data 52 (2007), 168–179.
16. Sanemasa, I., Araki, M., Deguchi, T., Nagai, H., Solubility measurements of benzene and the alkylbenzenes in water by making use of solute vapor. Bull. Chem. Soc. Jpn. 55 (1982), 1054–1062.
17. Dohányosová P., Fenclová D., Vrbka, P., Dohnal, V., Measurement of aqueous solubility of hydrophobic volatile organic compounds by solute vapor absorption technique: toluene, ethylbenzene, propylbenzene, and butylbenzene at temperatures from 273 K to 328 K. J. Chem. Eng. Data 46 (2001), 1533–1539.
18. Sanemasa, I., Araki, M., Deguchi, T., Nagai, H., Solubilities of benzene and the alkylbenzenes in water. Method for obtaining aqueous solutions saturated with vapors in equilibrium with organic liquids. Chem. Lett., 1981, 225–228.
19. Buttery, R.G., Ling, L., Guadagni, D.G., Food volatiles. Volatilities of aldehydes, ketones, and esters in dilute water solution. J. Agric. Food Chem. 17 (1969), 385–389.
20. Vrbka, P., Fenclová D., Laštovka, V., Dohnal, V., Measurement of infinite dilution activity coefficients of 1-alkanols (C1–C5) in water as a function of temperature (273–373 K). Fluid Phase Equilib. 237 (2005), 123–129.
21. Butler, J.A.V., Reid, W.S., The solubility of non-electrolytes. Part III. The entropy of hydration. J. Chem. Soc., 1936, 1171–1173.
22. Hofstee, T., Kwantes, A., Rijnders, G.W.A., Determination of activity coefficients at infinite dilution by gas–liquid chromatography. Proc. Intern. Symposium Distillation, Brighton, England, 1960, 105–109.
23. Hovorka, Š., V. r. Dohnal, Roux, A.H., Roux-Desgranges, G., Determination of temperature dependence of limiting activity coefficients for a group of moderately hydrophobic organic solutes in water. Fluid Phase Equilib. 201 (2002), 135–164.
24. Dewulf, J., Van Langenhove, H., Everaert, P., Determination of Henry's law coefficients by combination of the equilibrium partitioning in closed systems and solid-phase microextraction techniques. J. Chromatogr. A 830 (1999), 353–363.
25. Yalkowsky, S.H., Orr, R.J., Valvani, S.C., Solubility and Partitioning. 3. The Solubility of Halobenzenes in Water. Ind. Eng. Chem. Fundam. 18 (1979), 351–353.
26. Dreisbach, R.R., Physical Properties of Chemical Compounds. 1961, American Chemical Society, 3–523.
27. Shiu, W.-Y., Wania, F., Hung, H., Mackay, D., Temperature dependence of aqueous solubility of selected chlorobenzenes, polychlorinated biphenyls, and dibenzofuran. J. Chem. Eng. Data 42 (1997), 293–297.
28. Ma, J.H.Y., Hung, H., Shiu, W.-Y., Mackay, D., Temperature dependence of the aqueous solubility of selected chlorobenzenes and chlorotoluenes. J. Chem. Eng. Data 46 (2001), 619–622.
29. Li, J., Carr, P.W., Measurement of water–hexadecane partition coefficients by headspace gas chromatography and calculation of limiting activity coefficients in water. Anal. Chem. 65 (1993), 1443–1450.
30. Booth, H.S., Everson, H.E., Hydrotropic solubilities: solubilities in 40 per cent sodium xylenesulfonate, J. Ind. Eng. Chem. 40 (1948), 1491–1493.
31. Vesala, A., Thermodynamics of transfer of nonelectrolytes from light to heavy water. I. Linear free energy correlations of free energy of transfer with solubility and heat of melting of a nonelectrolyte. Acta Chem. Scand., Ser. A A28 (1974), 839–845.
32. Stephenson, R.M., Mutual solubilities: water–ketones, water–ethers, and water–gasoline–alcohols. J. Chem. Eng. Data 37 (1992), 80–95.
33. Ten Hulscher, T.E.M., van der Velde, L.E., Bruggeman, W.A., Temperature dependence of Henry's law constants for selected chlorobenzenes, polychlorinated biphenyls and polycyclic aromatic hydrocarbons. Environ. Toxicol. Chem. 11 (1992), 1595–1603.
34. Shiu, W.-Y., Mackay, D., Henry's law constants of selected aromatic hydrocarbons, alcohols, and ketones. J. Chem. Eng. Data 42 (1997), 27–30.
35. Banerjee, S., Solubility of organic mixtures in water. Environ. Sci. Technol. 18 (1984), 587–591.
36. Chin, Y.P., Weber, W.J. Jr., Voice, T.C., Determination of partition coefficients and aqueous solubilities by reverse phase chromatography. II. Evaluation of partitioning and solubility models. Water Res. 20 (1986), 1443–1450.
37. Finizio, A., Di Guardo, A., Estimating temperature dependence of solubility and octanol–water partition coefficient for organic compounds using RP-HPLC. Chemosphere 45 (2001), 1063–1070.
38. Miller, M.M., Ghodbane, S., Wasik, S.P., Tewari, Y.B., Martire, D.E., Aqueous solubilities, octanol/water partition coefficients, and entropies of melting of chlorinated benzenes and biphenyls. J. Chem. Eng. Data 29 (1984), 184–190.
39. Boyd, E.M., Meharg, A.A., Wright, J., Killham, K., Toxicity of chlorobenzenes to a lux-marked terrestrial bacterium, Pseudomonas fluorescens. Environ. Toxicol. Chem. 17 (1998), 2134–2140.