Thermodynamics of the basic copper sulfates antlerite, posnjakite, and brochantite

Chemie der Erde

Volumn 73, Issue 1, 2013, Pages 39-50

  Zittlau, Arne H ^a   Shi, Quan ^b   Boerio Goates, Juliana ^b   Woodfield, Brian F ^b   Majzlan, Juraj ^a  

^a FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

^b Brigham Young University   (United States)

Author keywords

Antlerite; Brochantite; Entropy; Formation enthalpy; Posnjakite; Stability

Indexed keywords

CHEMICAL WEATHERING; COPPER; ENTHALPY; ENTROPY; EXPERIMENTAL MINERALOGY; GIBBS FREE ENERGY; SULFATE GROUP; THERMODYNAMICS;

EID: 84876412942     PISSN: 00092819     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemer.2012.12.002     Document Type: Article

References (83)

1. Akselrud N.V., Fialkov Ja.A. Determination of solubility of metal hydroxides. Ukr. Khim. Zh. 1950, 26:283-295. (in Russian).
2. Allison, J.A., Brown, D.S., Novo-Gradac, K.J., 1991. MINTEQA2/PRODEFA2, A geochemical assessment model for environmental systems: Version 3.0 user's manual. US Environmental Protection Agency, EPA/600/3-91/021, 106 pp.
3. 2O. Transit. Met. Chem. 1979, 4:319.
4. 2O. Z. Kristallogr. 1975, 141:330-341.
5. Barton P.B., Bethke P.M. Thermodynamic properties of some synthetic zinc and copper minerals. Am. J. Sci. 1960, 258-A:21-34.
6. Binder O. The definition of the basic sulfates of copper. Ann. Chim. 1936, 11:337-409.
7. Bissengaliyeva M.R., Ogorodova L.P., Mel'chakova L.V., Vigasina M.F. Thermochemical investigation of natural antlerite. J. Therm. Anal. Calorim. 2011, 10.1007/s10973-011-1763-7.
8. Bowell R.J., Parshley J.V. Control of pit-lake water chemistry by secondary minerals, Summer Camp pit, Getchell mine, Nevada. Chem. Geol. 2005, 215:373-385.
9. Britton H.T.S. An electrometric and a phase rule study of some basic salts of copper. J. Chem. Soc. 1925, 12:2796-2807.
10. Cannon C.G. Infrared frequencies of amide, urea, and urethane groups. J. Phys. Chem. 1976, 80(11):1247-1248.
11. Charykova M.V., Krivovichev V.G., Depmeier W. Thermodynamics of arsenates, selenites, and sulfates in the weathering zone of sulfide ores. I. Thermodynamic constants at standard conditions. Zapiski RMO 2009, 6:105-117.
12. 2O. Pure Appl. Chem. 2008, 80:1317-1323.
13. Dobrokhotov G.N. The magnitude of pH in the precipitation process of metal hydroxides from sulphuric acidic solution. Zhurnal Prikladnoi Chimii 1954, 27:1056-1066. (in Russian).
14. Dunn P.J., Rouse R.C. Wroewolfeite, a new copper sulfate hydroxide hydrate. Mineral. Mag. 1975, 40(309):1-5.
15. 4] tetrahedra in inorganic compounds. Monatshefte für Chemie 1985, 116:927-931.
16. Fatyanov A.V., Yurgenson G.A., Glotova Ye.V. Effect of the features of the mineral composition and conditions of formations of oxidized copper ores of the Udokan deposit on their beneficiation technology. J. Mining Sci. 2000, 36:185-193.
17. Fitzgerald K.P., Nairn J., Atrens A. The chemistry of copper patination. Corrosion 1998, 40:2029-2050.
18. Garrels R.M., Dreyer R.M. Mechanism of limestone replacement at low temperatures and pressures. Bull. Geol. Soc. Am. 1952, 63:325-380.
19. 2O. Acta Crystallogr. 1984, C40:1309-1311.
20. Grevel K.-D., Majzlan J. Thermodynamics of divalent metal sulfates. Chem. Geol. 2011, 286:301-306.
21. 2O. Zhurnal Prikladnoii Khimii 1948, 21:260-272. (in Russian).
22. Hammerstrom J.M., Seal R.R., Meier A.L., Kornfeld J.M. Secondary sulfate minerals associated with acid drainage in the eastern US: recycling of metals and acidity in surficial environments. Chem. Geol. 2005, 215:407-431.
23. 4, a heteropolyhedral wallpaper structure. Can. Mineral. 1989, 27:205-209.
24. Kheifets V.L., Rotinyan A.L. Isobaric potentials of formation of sparingly soluble oxide hydrates and basic salts and the pH of solutions in equilibrium with the solid phase. Zhurnal Obshchei Khimii (J. Gen. Chem. UdSSR) 1954, 24:930-936.
25. Koga N., Mako A., Kimizu T., Tanaka Y. Thermal decomposition of synthetic antlerite prepared by microwave-assisted hydrothermal method. Thermochim. Acta 2008, 467:11-19.
26. Komkov A.I., Nefedov E.I. Posnjakite, a new mineral. Zap. Vses. Mineralog. Obschch. 1967, 96:58-62. (abstracted in Am. Min. 52 (1967) 1582-1583).
27. Lattanzi P., Da Pelo S., Musu E., Atzei D., Elsener B., Fantauzzi M., Rossi A. Enargite oxidation: a review. Earth Sci. Rev. 2008, 86:62-88.
28. Laux J.H., Lindenmeyer Z.G., Guimarães Teixeira J.B., Neto A.B. Ore genesis at the Camaquã copper mine, a Neoproterozoic sediment-hosted deposit in Southern Brazil. Ore Geol. Rev. 2005, 26:71-89.
29. Lin'ko I.V., Kulikov A.B., Venskovskii N.U., Lobanov N.N., Rudnitskaya O.V. Synthesis and thermal study of antlerite. Russ. J. Inorg. Chem. 2001, 46:1469-1471.
30. Lin'ko I.V., Kulikov A.B., Venskovskii N.U., Lobanov N.N., Zaitsev B.E., Ezhov A.I. Deposition of copper(II) hydroxosulfates by urea. Russ. J. Inorg. Chem. 2001, 46:298-301.
31. Livingston R.A. Influence of the environment on the patina of the Statue of Liberty. Environ. Sci. Technol. 1991, 25:1400-1408.
32. Lytle D.A., Nadagouda M.N. A comprehensive investigation of copper pitting corrosion in a drinking water distribution system. Corros. Sci. 2010, 52:1927-1938.
33. Majzlan J., Navrotsky A., Neil J.M. Energetics of anhydrite, barite, celestine, and anglesite: a high-temperature and differential scanning calorimetry study. Geochim. Cosmochim. Acta 2002, 66:1839-1850.
34. Marani D., Patterson J.W., Anderson P.R. Alkaline precipitation and aging of Cu(II) in the presence of sulfate. Water Res. 1995, 29:1317-1326.
35. Margulis E.V., Beisekeeva L.I., Maletina E.D., Kopylov N.I. Hydrolytic precipitation of copper hydroxide sulphate. Russ. J. Inorg. Chem. 1965, 10:972-977.
36. McDonald A.M., Chao G.Y. Martinite, a new hydrated sodium calcium fluorborosilicate species from Mont Saint-hilaire, Quebec: description, structure determination and genetic implications. Can. Miner. 2007, 45:1281-1292.
37. 2O)O] octahedral sheets in its structure. Z. Kristallogr. 1979, 149:249-257.
38. 6: OD character, polytypism and crystal structures. Eur. J. Mineral. 2003, 15:267-275.
39. 3+ member of the olivenite group, from the Black Pine mine, Montana, USA. Mineral. Petrol. 2010, 99:113-120.
40. Mrose M.E. Vernadskite discredited: pseudomorphs of antlerite after dolerophanite. Am. Mineral. 1961, 46:146-154.
41. Näsänen R., Tamminen V. The equilibrium of cupric hydroxysalts in mixed aqueous solutions of cupric and alkali salts at 25°. J. Am. Chem. Soc. 1949, 71:1994-1998.
42. Naumov, G.B., Ryzhenko, B.N., Khodakovsky, I.L., 1974. Handbook of Thermodynamic Data. Moscow, Atomizdat, 1974 (English translation of the Russian original from 1971).
43. Nord A.G., Tronner K., Boyce A.J. Atmospheric bronze and copper corrosion as an environmental indicator. Water Air Soil Pollut. 2001, 127:193-204.
44. Nordstrom D.K., Munoz J.L. Geochemical Thermodynamics 1994, Blackwell Scientific Publications. 2nd edition.
45. Orlandi P., Bonaccorsi E. Montetrisaite, a new hydroxy-hydrated copper sulfate species from Monte Trisa, Vicenza, Italy. Can. Mineral. 2009, 47:143-151.
46. Palache C., Berman H., Frondel C. The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana 1951, Vol. II. John Wiley, New York, pp. 583-585. 7th ed.
47. Parker, V.B., 1965. Thermal properties of uni-univalent electrolytes. National Standard Reference Data Service, NBS 2, 66 pp.
48. Parkhurst D.L. User's Guide to PHREEQC-A Computer Program for Speciation, Reaction-path, Advective-Transport, and Inverse Geochemical Calculations 1995, US Geological Survey Water-Resources Investigations Report, pp. 95-4227.
49. Pierrot R., Sainfield P. Sur la langite des vosges. Bull. Soc. Franç. Miner. Crist. 1958, 81:257-260.
50. 2O, a new mineral from Caldbeck Fells, Cumbria, England: description and crystal structure. Mineral. Mag. 2005, 69:973-980.
51. Pollard A.M., Spencer M.S., Thomas R.G., Williams P.A. Georgeite and azurite as precursors in the preparation of co-precipitated copper/zinc oxide catalysts. Appl. Catal. A: Gen. 1992, 85:1-11.
52. Posnjak E., Tunell G. The system, cupric oxide-sulfur trioxide-water. Am. J. Sci. 1929, 18:1-33.
53. Rabadjieva D., Tepavitcharova S., Tihomir T., Dassenakis M., Paraskevopoulou V., Petrov M. Chemical speciation in mining affected waters: the case study of Asarel-Medet mine. Environ. Monit. Assess. 2009, 159:353-366.
54. 2+ in brochantite. Phys. Status Solidi 1987, 139:K145-K150.
55. Reich M., Placios C., Vargas G., Shangde L., Cameron E.M., Leybourne M.I., Prada M.A., Zúñiga A., You C.-F. Supergene enrichment of copper deposits since the onset of modern hyperaridity in the Atacama Desert, Chile. Miner. Deposita 2009, 44:497-504.
56. Řídkošil T., Povondra P. The relation between posnjakite and langite. Neues Jahrbuch für Mineralogie Monatshefte 1982, 1:16-28.
57. 5 Pascal) pressure and at higher temperatures. U. S. Geol. Surv. Bull. 1978, 1452.
58. 5Pascal) pressure and at higher temperatures. U. S. Geol. Surv. Bull. 1995, 2131:461.
59. Schwab G.-M., Polydoropoulos K. Zur Alkali-Fällung von Schwermetall-Gemischen. Z. Anorg. Allg. Chem. 1953, 274:234-249.
60. 4. Can. J. Chem. 1988, 66:329.
61. Sekanina J. To the problem of langite and posnjakite. Casopis Mineral. Geol. 1975, 20:349-358.
62. Shi Q., Snow C.L., Boerio-Goates J., Woodfield B.F. Accurate heat capacity measurements on powdered samples using a Quantum Design physical property measurement system. J. Chem. Thermodyn. 2010, 42:1107-1115.
63. Shi Q., Boerio-Goates J., Woodfield B.F. An improved technique for accurate heat capacity measurements on powdered samples using a commercial relaxation calorimeter. J. Chem. Thermodyn. 2011, 43:1263-1269.
64. Silman, J.F.B., 1958. The stabilities of some oxidized copper minerals in aqueous solution at 25°C and 1 Atmosphere total pressure. Ph.D. Thesis, Harvard University, Cambridge, Massachusetts.
65. Smith R.M., Martell A.E. Critical Stability Constants 1976, Plenum, New York.
66. Tanaka H., Koga N. Preparation and thermal decomposition of basic copper(II) sulfates. Thermochim. Acta 1988, 133:221-226.
67. 4 solution. Thermochim. Acta 1991, 182:281-292.
68. Vilminot S., Richard-Plouet M., André G., Swierczynski D., Bourée-Vigneron F., Marino E., Guillot M. Synthesis, structure and magnetic properties of copper hydroxysulfates. Cryst. Eng. 2002, 5:177-186.
69. 4. Dalton Trans. 2006, 11:1455-1462.
70. 4 made of triple chains of spins s=1/2. J. Solid State Chem. 2003, 170:255-264.
71. 4, X=Se or S: cycloidal versus collinear antiferromagnetic structure. Inorg. Chem. 2007, 46:10079-10086.
72. Wagman, D.D., Evans, W.H., Parker, V.B., Halow, L., Bailey, S.M., Schumm, R.H., 1968. Technical Note 270-3, National Bureau of Standards, U.S. Dept. of Commerce, U.S. Govt. Printing Office, Washington D.C.
73. Wagman, D.D., Evans, W.H., Parker, V.B., Halow, L., Bailey, S.M., Schumm, R.H., 1969. Technical Note 270-4, National Bureau of Standards, U.S. Dept. of Commerce, U.S. Govt. Printing Office, Washington D.C.
74. Wagman, D.D., Evans, W.H., Parker, V.B., Schumm, R.H., Halow, I., Bailey, S.M., Churney, K.L., Nuttall, R.L., 1982. The NBS table of chemical thermodynamic properties - selected values for inorganic and C1 and C2 organic substances in SI units. National Bureau of Standards, Washington, DC 20234, Vol. 11, supplement no. 2, 1982.
75. 2O. Berichte der Deutschen Gesellschaft Geologische Wissenschaften Reihe B 1971, 16:175-203.
76. Woods T.L., Garrels R.M. Thermodynamic Values at Low Temperature for Natural Inorganic Materials: An Uncritical Summary 1987, Oxford University Press.
77. Wyckoff R.W.G. Crystal Structures 1 1963, Interscience Publishers, New York, NY, pp. 85-237. second ed.
78. Yeriomin O.V., Vinnichneko S.V., Yurgenson G.A. Evaluation of standard Gibbs potentials for copper hydroxosulfates from solutions of dual linear programming problems. Doklady Earth Sci. 2006, 409A:909-911.
79. Yoder C.H., Agee T.M., Ginion K.E., Hofmann A.E., Ewanichak J.E., Schaeffer C.D., Carroll M.J., Schaeffer R.W., McCaffrey P.F. The relative stabilities of the copper hydroxyl sulphates. Mineral. Mag. 2007, 71:571-577.
80. Yoder C.H., Gotlieb N.R., Rowand A.L. The relative stability of stoichiometrically related natural and synthetic double salts. Am. Mineral. 2010, 95:47-51.
81. Yokokawa H. Tables of thermodynamic properties of inorganic compounds. J. Natl. Chem. Lab. Ind. 1988, 83(Special Issue):27-121.
82. Young S.W., Stearn A.E. The basic copper sulfates. J. Am. Chem. Soc. 1916, 38:1947-1953.
83. Zamana L.V., Usmanov M.T. Thermodynamic and hydrogeochemical formation condition of brochantite as a crystalline hydrate: a case of the Udokan copper deposit. Doklady Earth Sci. 2006, 413:269-271.