Kinetics of soybean oil hydrolysis in subcritical water

Fuel

Volumn 108, Issue , 2013, Pages 277-281

  Milliren, Amber L ^a   Wissinger, Joshua C ^a   Gottumukala, Vasudev ^a   Schall, Constance A ^a,b  

^a Toledo   (United States)

^b UNIVERSITY OF TOLEDO   (United States)

Author keywords

Autocatalytic hydrolysis; Biofuel; Soybean oil hydrolysis; Subcritical water

Indexed keywords

BIOFUELS; HYDROLYSIS; KINETIC PARAMETERS; KINETIC THEORY; KINETICS; SOYBEAN OIL;

ADDITIONAL REACTIONS; AUTOCATALYTIC; HYDROLYSIS REACTION; KINETIC MODELING; MODEL PREDICTION; SUB-CRITICAL WATER; SUM OF SQUARED ERRORS; TEMPERATURE RANGE;

FATTY ACIDS;

EID: 84876399475     PISSN: 00162361     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuel.2012.12.068     Document Type: Article

References (26)

1. Lui L, Cheng SY, Li JB, Huang YF. Mitigating environmental pollution and impacts from fossil fuels: the role of alternative fuels. Energy Sources 2007;29:1069-80. (Pubitemid 47147941)
2. Xu L, Brilman DWF, Withag JAM, Brem G, Kersten V. Assessment of a dry and a wet route for the production of biofuels from microalgae: energy balance analysis. Bioresource Technol 2011;102:5113-22.
3. Minami E, Saka S. Kinetics of hydrolysis and methyl esterification for biodiesel production in two-step supercritical methanol process. Fuel 2006; 85:2479-83. (Pubitemid 44128471)
4. Levine RB, Pinnarat T, Savage PE. Biodiesel production from wet algal biomass through in situ lipid hydrolysis and supercritical transesterification. Energy Fuels 2010;24:5236-43.
5. Lixiong L, Coppola E, Rine J, Miller JL, Walker D. Catalytic hydrothermal conversion of triglycerides to non-ester biofuels. Energy Fuels 2010;24:1305-15.
6. Kalnes TN, Koers KP, Marker T, Shonnard DR. A technoeconomic and environmental life cycle comparison of green diesel to biodiesel and syndiesel. Environ Prog Sust Energy 2009;28:111-20.
7. Lixiong L, Coppola E, Rine J, Miller JL, Walker D. Catalytic hydrothermal conversion of triglycerides to non-ester biofuels. Energy Fuels 2010;24:1305-15.
8. Holliday RL, King JW, List GR. Hydrolysis of vegetable oils in sub- and supercritical water. Ind Eng Chem Res 1997;36:932-5.
9. Alenezi R, Leeke GA, Santos RCD, Khan AR. Hydrolysis kinetics of sunflower oil under subcritical water conditions. Chem Eng Res Des 2009;87:867-73.
10. Carr AG, Mammucari R, Foster NR. A review of subcritical water as a solvent and its utilisation for the processing of hydrophobic organic compounds. Chem Eng J 2011;172:1-17.
11. Herrero M, Cifuentes A, Ibañez E. Sub- and supercritical fluid extraction of functional ingredients from different natural sources: plants, food-byproducts, algae and microalgae a review. Food Chem 2006;98:136-48.
12. Khuwijitjaru P, Adachi S, Matsuno R. Solubility of saturated fatty acids in water at elevated temperatures. Biosci Biotechnol Biochem 2002;66:1723-6. (Pubitemid 39246832)
13. King JW. Determination of the solubility parameter of soybean oil by inverse gas chromatography. Food Sci Technol 1995;28:190-5.
14. Herrero M, Cifuentes A, Ibanez E. Sub- and supercritical fluid extraction of functional ingredients from different natural sources: plants, food-byproducts, algae and microalgae. Food Chem 2006;98:136-48.
15. Krammer P, Vogel H. Hydrolysis of esters in subcritical and supercritical water. J Supercrit Fluid 2000;16:189-206.
16. Miller DJ, Hawthorne SB. Solubility of liquid organic flavor and fragrance compounds in subcritical (hot/liquid) water from 298 K to 473 K. J Chem Eng Data 2000;45:315-8. (Pubitemid 30596890)
17. Changi S, Pinnarat T, Savage PE. Modeling hydrolysis and esterification kinetics for biofuel processes. Ind Eng Chem Res 2011;50:3206-11.
18. Krammer P, Vogel H. Hydrolysis of esters in subcritical and supercritical water. J Supercrit Fluid 2000;16:189-206.
19. Diasakou M, Louloudi A, Papyannakos N. Kinetics of the non-catalytic transesterification of soybean oil. Fuel 1998;77:1297-302. (Pubitemid 128400511)
20. Burgess DR. Thermochemical data in NIST chemistry webbook, NIST standard reference database number 69, National Institute of Standards and Technology, Gaithersburg MD, 20899. (retrieved September 1, 2011).
21. Oka H, Yamago S, Yoshida J, Kajimoto O. Evidence for a hydroxide ion catalyzed pathway in ester hydrolysis in supercritical water. Angew Chem Int Ed 2002;41:623-5. (Pubitemid 34174797)
22. Ravens DAS. The chemical reactivity of poly(ethylene terephthalate): heterogeneous hydrolysis by hydrochloric acid. Polymer 1960:375-85.
23. Comisar C, Hunter S, Walton A, Savage PE. Effect of pH on ether, ester and carbonate hydrolysis in high-temperature water. Ind Eng Chem Res 2008;47:577-84. (Pubitemid 351269498)
24. Changi S, Pinnart T, Savage PE. Mechanistic modeling of hydrolysis and esterification for biofuel processes. Ind Eng Chem Res 2011;50:12471-8.
25. Aranda DAG, Santos RTP, Tapanes NCO, Ramos ALD, Antunes OAC. Acid-catalyzed homogenous esterification reaction for biodiesel production from palm fatty acids. Catal Lett 2008;122:20-5.
26. Day JNE, Ingold CK. Mechanism and kinetics of carboxylic ester hydrolysis and carboxyl esterification. Trans Faraday Soc 1941;37:685-705.