Electrode reaction induced pH change at the Pt electrode/electrolyte interface and its impact on electrode processes

Journal of Electroanalytical Chemistry

Volumn 688, Issue , 2013, Pages 207-215

  Liao, Ling Wen ^a   Li, Ming Fang ^a   Kang, Jing ^a   Chen, Dong ^a   Chen, Yan Xia ^a   Ye, Shen ^b  

^a UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA   (China)

^b HOKKAIDO UNIVERSITY   (Japan)

Author keywords

Cyclic voltammetry; Electrode processes; Oxygen reduction reaction; pH effect; Pt electrode; Unbuffered solution

Indexed keywords

CYCLIC VOLTAMMETRY; ELECTROLYTIC REDUCTION; PH EFFECTS; REACTION KINETICS;

ELECTRODE PROCESS; ELECTRODE/ELECTROLYTE INTERFACES; OXYGEN REDUCTION REACTION; POLARIZATION CURVES; POTENTIAL SCAN RATES; PT ELECTRODE; THERMODYNAMIC EQUILIBRIA; UNDERPOTENTIAL DEPOSITION;

PLATINUM;

EID: 84876041228     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jelechem.2012.08.031     Document Type: Article

References (47)

1. R. Adzic J. Lipkowsky, P.N. Ross, Electrocatalysis 1998 VCH Publishers New York 197 242
2. S. Gottesfeld M.T.M. Koper, Fuel Cell Catalysis 2009 John Wiley & Sons, Inc. Hoboken 1 31
3. N.M. Markovic, and P.N. Ross Surf. Sci. Rep. 45 2002 121 229
4. A. Hamnett W. Schmickler, E. Santos, Interfacial Electrochemistry: Accomplishments and Challenges 1999 Marcel Dekker Inc. New York 843 883
5. E. Herrero, and J.M. Feliu A.J. Bard, M. Stratmann, E.J. Calvo, J. Encyclopedia Electrochemistry-Interfacial Kinetics and Mass Transport 2003 VCH Weinheim, Germany 443 465
6. T. Iwasita, and F.C. Nart Prog. Surf. Sci. 55 1997 271 340
7. Y.X. Chen, M.F. Li, L.W. Liao, J. Xu, and S. Ye Electrochem. Commun. 11 2009 1434 1436
8. A. Kuzume, E. Herrero, and J.M. Feliu J. Electroanal. Chem. 599 2007 333 343
9. M. Wakisaka, H. Suzuki, S. Mitsui, H. Uchida, and M. Watanabe Langmuir 25 2009 1897 1900
10. V.R. Stamenkovic, B.S. Mun, M. Arenz, K.J.J. Mayrhofer, C.A. Lucas, G.F. Wang, P.N. Ross, and N.M. Markovic Nat. Mater. 6 2007 241 247
11. G. Garcia, and M.T.M. Koper Phys. Chem. Chem. Phys. 10 2008 3802 3811
12. S.X. Liu, L.W. Liao, Q. Tao, Y.X. Chen, and S. Ye Phys. Chem. Chem. Phys. 13 2011 9725 9735
13. V.R. Stamenkovic, B. Fowler, B.S. Mun, G.F. Wang, P.N. Ross, C.A. Lucas, and N.M. Markovic Science 315 2007 493 497
14. N. Garcia, V. Climent, J.M. Orts, J.M. Feliu, and A. Aldaz Chem. Phys. Chem. 5 2004 1221 1227
15. B. Braunschweig, and W. Daum Langmuir 25 2009 11112 11120
16. A.R. Kucernak, and G.J. Offer Phys. Chem. Chem. Phys. 10 2008 3699 3711
17. D. Chen, Q. Tao, L.W. Liao, S.X. Liu, Y.X. Chen, and S. Ye Electrocatalysis 2 2011 207 219
18. N. Garcia-Araez, V. Climent, and J.M. Feliu J. Electroanal. Chem. 649 2010 69 82
19. V. Climent, R. Gomez, J.M. Orts, and J.M. Feliu J. Phys. Chem. B 110 2006 11344 11351
20. N.M. Markovic, T.J. Schmidt, B.N. Grgur, H.A. Gasteiger, R.J. Behm, and P.N. Ross J. Phys. Chem. B 103 1999 8568 8577
21. B. Geng, J. Cai, S.Z. Liang, S.X. Liu, M.F. Li, and Y.X. Chen Phys. Chem. Chem. Phys. 12 2010 10888 10895
22. Q.Y. Peng, and J.J. Breen Electrochim. Acta. 43 1998 2619 2626
23. K. Aljaafgolze, D.M. Kolb, and D. Scherson J. Electroanal. Chem. 200 1986 353 362
24. H. Kita, S. Ye, A. Aramata, and N. Furuya J. Electroanal. Chem. 295 1990 317 331
25. S. Ye, H. Kita, and A. Aramata J. Electroanal. Chem. 333 1992 299 312
26. M. Tadjeddine, J.P. Flament, A. Le Rille, and A. Tadjeddine Surf. Sci. 600 2006 2138 2153
27. Y.G. Kim, S.L. Yau, and K. Itaya J. Am. Chem. Soc 118 1996 393 400
28. S. Tanaka, S.L. Yau, and K. Itaya J. Electroanal. Chem. 396 1995 125 130
29. Y.F. Yang, and G. Denuault J. Electroanal. Chem. 418 1996 99 107
30. D. Pletcher, and S. Sotiropoulos J. Chem. Soc. Faraday Trans. 90 1994 3663 3668
31. K. Ashley, D.L. Feldheim, D.B. Parry, M.G. Samant, and M.R. Philpott J. Electroanal. Chem. 373 1994 201 209
32. K. Ashley, M.G. Samant, H. Seki, and M.R. Philpott J. Electroanal. Chem. 270 1989 349 364
33. M.A. Climent, M.J. Valls, J.M. Feliu, A. Aldaz, and J. Clavilier J. Electroanal. Chem. 326 1992 113 127
34. K. Franaszczuk, and J. Sobkowski J. Electroanal. Chem. 261 1989 223 227
35. V.B. Paulissen, and C. Korzeniewski J. Electroanal. Chem. 96 1992 4563 4567
36. N. Ramaswamy, and S. Mukerjee J. Phys. Chem. C 115 2011 18015 18026
37. Y.F. Yang, and G. Denuault J. Chem. Soc. Faraday Trans. 92 1996 3791 3798
38. B. Macdouga, B.E. Conway, and Kozlowsk.Ha J. Electroanal. Chem. 32 1971 A15 A20
39. V. Lazarescu, and J. Clavilier Electrochim. Acta. 44 1998 931 941
40. 2 produced in previous negative-going scan at E < ca. -0.5 V.
41. From the residue acid left on the wall of the glass cell used in previous experiments in acidic solution which has not been rinsed carefully then after.
42. V.B. Paulissen, and C. Korzeniewski J. Phys. Chem. 96 1992 4563 4567
43. S. Strbac Electrochim. Acta. 56 2011 1597 1604
44. M.F. Li, L.W. Liao, D.F. Yuan, Y.X. Chen, S.L. Chen, S. Ye, in preparation.
45. 4, only 0.1 mM/4 is consumed by ORR through reaction (8) in the limiting current region.
46. M.R. Tarasevich, Sadkowski, and E. Yeager B.E. Conway, J.O. Bockris, E. Yeager, S.U.M. Khan, R.E. White, Comprehensive Treatise of Electrochemistry 1983 Plenum Press New York 301 398
47. J.A. Keith, and T. Jacob Angew. Chem. Int. Ed. 49 2010 9521 9525