Anomalous solubility of oxygen in acetonitrile/water mixture containing tetra-n-butylammonium perchlorate supporting electrolyte; The solubility and diffusion coefficient of oxygen in anhydrous acetonitrile and aqueous mixtures

Journal of Electroanalytical Chemistry

Volumn 688, Issue , 2013, Pages 328-335

  Li, Qian ^a   Batchelor Mcauley, Christopher ^a   Lawrence, Nathan S ^b   Hartshorne, Robert S ^b   Compton, Richard G ^a  

^a UNIVERSITY OF OXFORD   (United Kingdom)

^b SCHLUMBERGER CAMBRIDGE RESEARCH   (United Kingdom)

Author keywords

Acetonitrile water mixture; Diffusion coefficient; Diffusional activation energy; Electrochemical oxygen reduction; Solubility; Temperature

Indexed keywords

ACETONITRILE; ACTIVATION ENERGY; CHRONOAMPEROMETRY; DIFFUSION; DISSOLUTION; ELECTRODES; ELECTROLYTIC REDUCTION; GLASS MEMBRANE ELECTRODES; HYDROGEN BONDS; INORGANIC COMPOUNDS; MIXING; MIXTURES; SOLUBILITY; SOLVATION; TEMPERATURE;

ACETONITRILE/WATER MIXTURES; CONCENTRATION OF DISSOLVED OXYGEN; DOUBLE POTENTIAL STEP CHRONOAMPEROMETRY; ELECTROCHEMICAL OXYGEN REDUCTION; GLASSY CARBON ELECTRODES; OXYGEN ELECTRO REDUCTIONS; STOKES EINSTEIN RELATIONSHIPS; SUPEROXIDE RADICAL ANIONS;

DISSOLVED OXYGEN;

EID: 84876037040     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jelechem.2012.07.039     Document Type: Article

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