Examining hysteresis in composite x Li2MnO3· (1-x)LiMO2 cathode structures

Journal of Physical Chemistry C

Volumn 117, Issue 13, 2013, Pages 6525-6536

  Croy, Jason R ^a   Gallagher, Kevin G ^a   Balasubramanian, Mahalingam ^b   Chen, Zonghai ^a   Ren, Yang ^b   Kim, Donghan ^a,c   Kang, Sun Ho ^a,d   Dees, Dennis W ^a   Thackeray, Michael M ^a  

^a ARGONNE NATIONAL LABORATORY   (United States)

^b ARGONNE NATIONAL LABORATORY   (United States)

^c Samsung Corning Co Ltd   (South Korea)

^d Samsung SDI   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE-DISCHARGE PROFILES; CRYSTALLOGRAPHIC SITES; ELECTROCHEMICAL ACTIVATION; ELECTROCHEMICAL MEASUREMENTS; INTERCALATION MATERIALS; INTERCALATION MECHANISMS; STRUCTURAL DIFFERENCES; STRUCTURAL REORGANIZATION;

CATHODES; ELECTRIC DISCHARGES; EXTRACTION; HYSTERESIS; MANGANESE; MANGANESE OXIDE; OPEN CIRCUIT VOLTAGE;

LITHIUM;

EID: 84875869842     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp312658q     Document Type: Article

References (66)

1. y) Solid Solutions Chem. Mater. 2007, 19, 3067-3073 (Pubitemid 46998474)
2. 2 Nanomaterials by a Molten-Salt Method: Towards a High Capacity and High Power Cathode for Rechargeable Lithium Batteries J. Mater. Chem. 2012, 22, 25380-25387
3. 3-Based Composite Cathodes for Lithium Batteries: A Novel Synthesis Approach and New Structures Electrochem. Commun. 2011, 13, 1063-1066
4. Whittingham, M. S. Lithium Batteries and Cathode Materials Chem. Rev. 2004, 104, 4271-4301
5. 2 (M = Mn, Ni, Co) Electrodes for Lithium-Ion Batteries J. Mater. Chem. 2007, 17, 3112-3125 (Pubitemid 47179626)
6. 2 J. Electrochem. Soc. 2002, 149, A778-A791
7. 2 Electrodes Electrochem. Commun. 2004, 6, 1085-1091
8. 3 Component. Manuscript in preparation, 2013.
9. 2 Chem. Mater. 2011, 23, 2039-2050
10. 2 by Analytical Electron Microscopy J. Power Sources 2008, 178, 422-433
11. 2 for Lithium-Ion Batteries J. Phys. Chem. C 2012, 116, 25242-25247
12. 2 J. Am. Chem. Soc. 2011, 133, 4404-4419
13. 2 Cells Using In Situ X-ray Diffraction and Electrochemical Studies J. Electrochem. Soc. 2002, 149, A815-A822
14. 2 J. Am. Chem. Soc. 2006, 128, 8694-8698
15. 2 System Chem. Mater. 2008, 20, 4815-4825
16. -1 J. Mater. Chem. 2011, 21, 10179-10188
17. 2 Prepared by a Simple Combustion Method J. Mater. Chem. 2004, 14, 1424-1429
18. 2 J. Power Sources 2011, 196, 6828-6834
19. Balasubramanian, M.; McBreen, J.; Davidson, I. J.; Whitfield, P. S.; Kargina, I. In Situ X-ray Absorption Study of a Layered Manganese-Chromium Oxide-Based Cathode Material J. Electrochem. Soc. 2002, 149, A176-A184
20. 4 to Achieve High Energy Density and Pulse Power Capability J. Power Sources 2011, 196, 9702-9707
21. 2 "Composite" Layered Cathode Material for Lithium-Ion Batteries RSC Adv. 2012, 2, 8797-8807
22. Zhu, Y.; Li, Y.; Bettge, M.; Abraham, D. P. Positive Electrode Passivation by LiDFOB Electrolyte Additive in High-Capacity Lithium-Ion Cells. J. Electrochem. Soc. 2012, 159.
23. +-Ion Batteries J. Electrochem. Soc. 2012, 159, A781-A790
24. Kim, D.; Sandi, G.; Croy, J. R.; Gallagher, K.; Kang, S.-H.; Lee, E.; Slater, M. D.; Johnson, C. S.; Thackeray, M. M. Composite "Layered-Layered- Spinel" Cathode Structures for Lithium-Ion Batteries. J. Electrochem. Soc. 2013, 160.
25. Zheng, T.; McKinnon, W. R.; Dahn, J. R. Hysteresis During Lithium Insertion in Hydrogen-Containing Carbons J. Electrochem. Soc. 1996, 143, 2137-2145 (Pubitemid 126599423)
26. 6. J. Electrochem. Soc. 2012, 159.
27. Key, B.; Morcrette, M.; Tarascon, J. M.; Grey, C. P. Pair Distribution Function Analysis and Solid State NMR Studies of Silicon Electrodes for Lithium Ion Batteries: Understanding the (De)lithiation Mechanisms J. Am. Chem. Soc. 2011, 133, 503-512
28. Sethuraman, V. A.; Chon, M. J.; Shimshak, M.; Srinivasan, V.; Guduru, P. R. In Situ Measurements of Stress Evolution in Silicon Thin Films During Electrochemical Lithiation and Delithiation J. Power Sources 2010, 195, 5062-5066
29. Ahn, D.; Raj, R. Thermodynamic Measurements Pertaining to the Hysteretic Intercalation of Lithium in Polymer-Derived Silicon Oxycarbide J. Power Sources 2010, 195, 3900-3906
30. Tang, M.; Carter, W. C.; Chiang, Y.-M. Modeling the Competing Phase Transition Pathways in Nanoscale Olivine Electrodes Ann. Rev. Mater. Res. 2010, 40, 501
31. Dreyer, W.; Jamnik, J.; Guhlke, C.; Huth, R.; Moskon, J.; Gaberscek, M. The Thermodynamic Origin of Hysteresis in Insertion Batteries Nat. Mater. 2010, 9, 448-453
32. 8 as Cathodes for High-Rate Secondary Li Batteries Solid State Ionics 1984, 13, 311-318 (Pubitemid 14649834)
33. 2 Cells Electrochim. Acta 1991, 36, 1469-1474
34. 2 Cells Electrochim. Acta 1991, 36, 489-498
35. 2 for Lithium-Ion Batteries J. Power Sources 1997, 68, 646-651 (Pubitemid 127396224)
36. 2 Prepared at Low Temperatures J. Electrochem. Soc. 1993, 140, 3396-3401
37. 2 J. Electrochem. Soc. 1998, 145, 2672-2677
38. 2 J. Mater. Chem. 1999, 9, 193-198
39. Ta, K. P.; Newman, J. Proton Intercalation Hysteresis in Charging and Discharging Nickel Hydroxide Electrodes J. Electrochem. Soc. 1999, 146, 2769-2779
40. Srinivasan, V.; Weidner, J. W.; Newman, J. Hysteresis During Cycling of Nickel Hydroxide Active Material J. Electrochem. Soc. 2001, 148, A969-A980
41. Everett, D. F.; Whitton, W. I. A General Approach to Hysteresis Trans. Faraday Soc. 1952, 48, 749-757
42. Everett, D. F.; Smith, F. W. A General Approach to Hysteresis, Part 2: Development of the Domain Theory Trans. Faraday Soc. 1954, 50, 187-197
43. Everett, D. F. a General Approach to Hysteresis, Part 3: A Formal Treatment of the Independent Domain Model of Hysteresis Trans. Faraday Soc. 1954, 50, 1077-1096
44. Everett, D. F. A General Approach to Hysteresis, Part 4: An Alternative Formulation of the Domain Model Trans. Faraday Soc. 1955, 51, 1551-1557
45. Kraft, S.; Stumpel, J.; Becker, P.; Kuetgens, U. High Resolution X-ray Absorption Spectroscopy with Absolute Energy Calibration for the Determination of Absorption Edge Energies Rev. Sci. Instrum. 1996, 67, 681-687 (Pubitemid 126579767)
46. Ravel, B.; Newville, M. Athena, Artemis, Hephaestus: Data Analysis for X-ray Absorption Spectroscopy Using IFEFFIT J. Synchrotron Rad. 2005, 12, 537-541 (Pubitemid 41557599)
47. Croy, J. R.; Balasubramanian, M.; Kim, D.; Kang, S. H.; Thackeray, M. M. Designing High-Capacity, Lithium-Ion Cathodes Using X-ray Absorption Spectroscopy Chem. Mater. 2011, 23, 5415-5424
48. 2 Electrode System by Combination of Soft and Hard X-ray Absorption Spectroscopy J. Am. Chem. Soc. 2005, 127, 17479-17487 (Pubitemid 41794063)
49. 2 Cathode Material J. Electrochem. Soc. 2000, 147, 2903-2909
50. 2 Systems J. Power Sources 1997, 68, 536-539 (Pubitemid 127396200)
51. 2 Particles During Testing of High-Power Lithium-Ion Cells Electrochem. Commun. 2002, 4, 620-625
52. Thackeray, M. M. Manganese Oxides for Lithium Batteries Prog. Solid State Chem. 1997, 25, 1-71 (Pubitemid 127427736)
53. 2 Chem. Mater. 2004, 16, 3106-3118
54. 2: Combined Neutron, NMR, and Electrochemical Study Chem. Mater. 2007, 19, 1016-1023 (Pubitemid 46424136)
55. 2 R 3 m for 4 V Secondary Lithium Cells J. Electrochem. Soc. 1993, 140, 1862-1870 (Pubitemid 23676829)
56. 2 Solid State Ionics 1993, 67, 123-130
57. 2 J. Electrochem. Soc. 2002, 149, A1604-A1609
58. 2 Phys. Rev. B 1998, 58, 2975-2987 (Pubitemid 128476941)
59. 2 Compounds J. Electrochem. Soc. 2004, 151, A720-A727
60. Xu, B.; Fell, C. R.; Chi, M. F.; Meng, Y. S. Identifying Surface Structural Changes in Layered Li-Excess Nickel Manganese Oxides in High Voltage Lithium Ion Batteries: A Joint Experimental and Theoretical Study Energy Environ. Sci. 2011, 4, 2223-2233
61. 4 for Secondary Lithium Batteries J. Electrochem. Soc. 1996, 143, 1607-1613 (Pubitemid 126607940)
62. 4 Spinels for High-Power Lithium-Ion Batteries J. Electrochem. Soc. 2006, 153, A1345-A1352
63. 4/Li Electrochemical Cells Phys. Rev. B 1997, 56, 3800-3805
64. 2 Electrochem. Solid State Lett. 2001, 4, A78-A81
65. 2 Compounds Upon Alkali De-intercalation Phys. Chem. Chem. Phys. 2012, 14, 15571-15578
66. 2: A Joint Experimental and Theoretical Study Chem. Mater. 2006, 18, 4768-478