What factors affect the 5D0 energy of Eu 3+? An investigation of nephelauxetic effects

Journal of Physical Chemistry A

Volumn 117, Issue 13, 2013, Pages 2771-2781

  Tanner, Peter A ^a   Yeung, Yau Yuen ^a   Ning, Lixin ^b  

^a THE EDUCATION UNIVERSITY OF HONG KONG   (Hong Kong)

^b ANHUI NORMAL UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL FIELD CALCULATION; CRYSTAL FIELD PARAMETER; LINEAR RELATIONSHIPS; LOW-SYMMETRY SYSTEMS; NEPHELAUXETIC EFFECT; SPIN-ORBIT COUPLING CONSTANTS; SPIN-ORBIT COUPLINGS; SPIN-ORBIT PARAMETERS;

BERYLLIUM COMPOUNDS; CHLORINE COMPOUNDS; EUROPIUM; FLUORINE COMPOUNDS; MIXING; PARAMAGNETIC RESONANCE;

LIGANDS;

EID: 84875843388     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/jp400247r     Document Type: Article

References (58)

1. Wybourne, B. G. Spectroscopic Properties of Rare Earths; Interscience: London, 1965; p 44.
2. Jørgensen, C. K. The Nephelauxetic Series. Progress in Inorganic Chemistry; Cotton, F. A., Ed.; Wiley: New York, 1962; Vol. 4, p 73-124.
3. Newman, D. J. Ligand Ordering Parameters Aust. J. Phys. 1977, 30, 315-323
4. Schäffer, C. E.; Jørgensen, C. K. The Nephelauxetic Series of Ligands J. Inorg. Nucl. Chem. 1958, 8, 143-148
5. 3+ in Ternary MYX Compounds Phys. Rev. B 1995, 52, 12618-12626
6. Newman, D. J. Slater Parameter Shifts in Substituted Lanthanide Ions J. Phys. Chem. Solids 1973, 34, 541-545
7. 0 Transition Frequency in Europium(III) Chelates Inorg. Chem. 1985, 24, 895-900
8. Amberger, H.-D.; Reddmann, H.; Hagen, C. Electronic Structures of Highly Symmetrical Compounds of f-Elements. XXXIX. Do More Covalent Europium(III) Compounds Exhibit an Anti-Nephelauxetic Behavior? Inorg. Chim. Acta 2005, 358, 3745-3752
9. 3+ Complexes with the Sum of the "Nephelauxetic" Parameters for all of the Coordinating Atoms Inorg. Chim. Acta 1995, 229, 383-390
10. Bünzli, J.-C.; Chauvin, A.-S.; Kim, H. K.; Deiters, E.; Eliseeva, S. V. Lanthanide Luminescence Efficiency in Eight- and Nine-Coordinate Complexes: Role of the Radiative Lifetime Coord. Chem. Rev. 2010, 254, 2623-2633
11. Puntus, L. N.; Lyssenko, K. A.; Antipin, M. Y.; Bünzli, J.-C. Role of Inner- and Outer-Sphere Bonding in the Sensitization of Eu-Luminescence Deciphered by Combined Analysis of Experimental Electron Density Distribution Function and Photophysical Data Inorg. Chem. 2008, 47, 11095-11107
12. Piguet, C.; Bünzli, J.-C.; Bernardinelli, G.; Hopfgartner, G.; Petoud, S.; Schaad, O. Lanthanide Podates with Predetermined Structural and Photophysical Properties: Strongly Luminescent Self-Assembled Heterodinuclear d-f Complexes with a Segmental Ligand Containing Heterocyclic Imines and Carboxamide Binding Units J. Am. Chem. Soc. 1996, 118, 6681-6697
13. Petoud, S.; Bünzli, J.-C.; Schenk, K. J.; Piguet, C. Luminescent Properties of Lanthanide Nitrato Complexes with Substituted Bis(benzimidazolyl) pyridines Inorg. Chem. 1997, 36, 1345-1353
14. 0 Transition Frequency in Europium Complexes Inorg. Chem. 1997, 36, 249-252
15. Malta, O. L.; Batista, H. J.; Carlos, L. D. Overlap Polarizability of a Chemical Bond: a Scale of Covalency and Application to Lanthanide Compounds Chem. Phys. 2002, 282, 21-30
16. Souza, A. P.; Rodrigues, L. C. V.; Brito, H. F.; Alves, S., Jr.; Malta, O. L. Novel Europium and Gadolinium Complexes with Methaneseleninate as Ligand: Synthesis, Characterization and Spectroscopic Study Inorg. Chem. Commun. 2012, 15, 97-101
17. Hölsä, J.; Leskelä, T.; Leskelä, M. Luminescence Properties of Europium(3+)-Doped Rare-Earth Oxyhydroxides Inorg. Chem. 1985, 24, 1539-1542
18. 2 Glass J. Lumin. 1979, 18/19, 661-664
19. 2+ in solids Phys. Rev. B 2002, 65, 195118 (1-6)
20. 2+ Ions in Glasses J. Lumin. 2002, 100, 73-88
21. 3+ Ions in Several Host Matrices Phys. Rev. B 1994, 49, 16917-16925
22. 2S Crystal and Polyvinyl Alcohol J. Lumin. 1991, 48&49, 473-476
23. Dexpert-Ghys, J.; Piriou, B.; Jacquet-Francillon, N.; Sombret, C. Europium Site Selective Spectroscopy of Aluminoborosilicate Glasses: Structural Approach and Influence of Phosphorus on the Environment of the Lanthanide J. Non-Cryst. Solids 1990, 125, 117-128
24. 3+ in Fluoride Glasses J. Lumin. 1994, 59, 81-87
25. 3+ Ion in Oxides J. Alloys Compd. 1995, 228, 41-44
26. 3:Eu and Connection to Temperature Stimulus J. Alloys Compd. 2011, 509, 3613-3616
27. 2 J. Alloys Compd. 2011, 509, 3441-3451
28. Görller-Walrand, C.; Binnemans, K. In Handbook on the Physics and Chemistry of Rare Earths; Gschneidner, K. A., Jr.; Eyring, L., Eds.; Elsevier Science B. V.: 1996; Vol. 23, p 164.
29. 3 J. Less-Common Met. 1989, 148, 181-186
30. N en Phase Solide J. Phys. (Paris) 1976, 37, 671-676
31. Dexpert-Ghys, J.; Faucher, M.; Caro, P. Site-Selective Excitation, Crystal-Field Analysis, and Energy transfer in Europium-Doped Monoclinic Gadolinium Sesquioxide. A Test of the Electrostatic Model Phys. Rev. B 1981, 23, 607-617
32. Judd, B. R. Three-Particle Operators for Equivalent Electrons Phys. Rev. 1966, 141, 4-14
33. Duan, C.-K.; Tanner, P. A. What Use are Crystal Field Parameters? A Chemist's Viewpoint J. Phys. Chem. A 2010, 114, 6055-6062
34. 3+ Doped Lead Borate Glass J. Appl. Phys. 2011, 110, 033536 (1-8)
35. 3+-Doped Yttrium Aluminium Garnet Phys. Rev. B 2003, 68, 01401
36. de Sagey, G. T.; Porcher, P.; Garon, G.; Caro, P. In The Rare Earths in Modern Science and Technology; McCarthy, G. J.; Silber, H. B.; Rhyne, J. J., Eds.; Plenum: 1982; Vol. 3, pp 127-130.
37. 3+ (Ln = Pr, Nd, Er). submitted.
38. Morosin, B. Crystal Structures of Anhydrous Rare-Earth Chlorides J. Chem. Phys. 1968, 49, 3007-3012
39. 2O J. Phys.: Condens. Matter 1996, 8, 1267-1279
40. Thorne, J. R. G.; Jones, M.; McCaw, C. S.; Murdoch, K. M.; Khaidukov, N. M. Two-Photon Spectroscopy of Europium(III) Elpasolites J. Phys:. Condens. Matter 1999, 11, 7851-7866
41. 3- J. Phys.: Condens. Matter 1997, 9, 7817-7836
42. 4 J. Phys.: Condens. Matter 1993, 5, 8359-8374
43. 3 J. Phys.: Condens. Matter 2003, 15, 2169-2181
44. 3 Nanophosphors: Electronic Structure and Optical Characterization J. Phys. Chem. C 2010, 114, 9314-9321
45. 12 (YGG) J. Phys.: Condens. Matter 1997, 9, 1637-1648
46. 12 (YAG) J. Chem. Soc., Faraday Trans. 2 1996, 92, 2487-2493
47. 2O Inorg. Chem. 1996, 35, 5347-5355
48. 2O system J. Phys. Chem. 1983, 87, 2544-2556
49. Görller-Walrand, C.; Hendrickx, I.; Fluyt, L.; Gos, M. P.; D'Olieslager, J.; Blasse, G. Optical Spectra and Crystal-Field Analysis of Europium Double Nitrates J. Chem. Phys. 1992, 96, 5650
50. 4 J. Phys.: Condens. Matter 1994, 6, 7797-7812
51. 2O Systems J. Less-Common Met. 1989, 148, 311-319
52. 2O Chem. Phys. 1988, 122, 105-124
53. 6 Configuration in Europium(III) Triacetate Tetrahydrate Chem. Phys. 2008, 354, 86-93
54. 2O J. Alloys Compd. 1997, 250, 326-331
55. 3 Systems J. Less-Common Met. 1989, 148, 289-296
56. n Configurations Calculations J. Lumin. 2008, 128, 421-427
57. 3+ Crystal Radiochemistry 2000, 42, 53-60
58. Li, W.; Ning, L.; Tanner, P. A. Double Perovskite Structure: a Vibrational and Luminescence Investigation Providing a Perspective on Crystal Field Strength J. Phys. Chem. A 2012, 116, 7337-7344