Mechanistic investigations on significantly improved hydrogen storage performance of the Ca(BH4)2-added 2LiNH 2/MgH2 system

International Journal of Hydrogen Energy

Volumn 38, Issue 12, 2013, Pages 5030-5038

  Li, Bo ^a   Liu, Yongfeng ^a   Gu, Jian ^a   Gu, Yingjie ^a   Gao, Mingxia ^a   Pan, Hongge ^a  

^a ZHEJIANG UNIVERSITY   (China)

Author keywords

Amide; Borohydrides; Hydrogen storage; Kinetics; Mechanisms

Indexed keywords

BOROHYDRIDES; HYDROGEN STORAGE PROPERTIES; METATHESIS REACTIONS; ONSET TEMPERATURE; OPERATING TEMPERATURE; STORAGE PERFORMANCE;

AMIDES; BALL MILLING; ENZYME KINETICS; HYDROGEN; HYDROGEN STORAGE; LITHIUM; MECHANISMS;

CALCIUM;

EID: 84875756121     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2013.02.011     Document Type: Article

References (47)

1. L. Schlapbach, and A. Züttel Hydrogen-storage materials for mobile applications Nature 414 2001 353 358
2. S.I. Orimo, Y. Nakamori, J.R. Eliseo, A. Züttel, and C.M. Jensen Complex hydrides for hydrogen storage Chem Rev 107 2007 4111 4132
3. P. Chen, and M. Zhu Recent progress in hydrogen storage Mater Today 11 2008 36 43
4. U. Eberle, M. Felderhoff, and F. Schüth Chemical and physical solutions for hydrogen storage Angew Chem Int Ed 48 2009 6608 6630
5. J. Graetz New approaches to hydrogen storage Chem Soc Rev 38 2009 73 82
6. P. Jena Materials for hydrogen storage: past, present, and future J Phys Chem Lett 2 2011 206 211
7. P. Chen, Z.T. Xiong, J.Z. Luo, J.Y. Lin, and K.L. Tan Interaction of hydrogen with metal nitrides and imides Nature 420 2002 302 304
8. 2): a viable hydrogen storage system J Alloys Compd 381 2004 284 287
9. 2NH-MgNH combination system Dalton Trans 40 2011 8179 8186
10. Z.T. Xiong, G.T. Wu, J.J. Hu, and P. Chen Ternary imides for hydrogen storage Adv Mater 16 2004 1522 1525
11. 2 and LiH for hydrogen storage J Phys Chem B 108 2004 8763 8765
12. B. Li, Y.F. Liu, Y. Zhang, M.X. Gao, and H.G. Pan Reaction pathways for hydrogen uptake of the Li-Mg-N-based hydrogen storage system J Phys Chem C 116 2012 13551 13558
13. 2: an electronic structure viewpoint Appl Phys A 79 2004 1765 1767
14. US Department of Energy. Targets for onboard hydrogen storage systems for light-duty vehicles, http://www1.eere.energy.gov/hydrogenandfuelcells/storage/ pdfs/targets-onboard-hydro-storage-explanation.pdf [accessed 15.06.11].
15. S. Nayebossadri Kinetic rate-limiting steps in dehydrogenation of Li-N-H and Li-Mg-N-H systems-effects of elemental Si and Al Int J Hydrogen Energy 36 2011 8335 8343
16. 2) Int J Hydrogen Energy 37 2012 6646 6652
17. J. Yang, A. Sudik, D.J. Siegel, D. Halliday, A. Drews, and R.O. Carter A self-catalyzing hydrogen storage materials Angew Chem Int Ed 47 2008 882 887
18. 4 as a hydrogen storage material Chem Mater 20 2008 7089 7094
19. 4 Chem Mater 20 2008 4398 4402
20. 4-added Li-Mg-N-H system Phys Chem Chem Phys 13 2011 314 321
21. 2 nano-composites: intermediate and optimized hydrogenation properties Phys Chem Chem Phys 14 2012 2857 2863
22. 2 Eur J Inorg Chem 2006 4368 4373
23. 2 J Alloys Compd 432 2007 298 302
24. 2 J Power Sources 159 2006 116 119
25. Y. Kojima, and Y. Kawai IR characterizations of lithium imide and amide J Alloys Compd 395 2005 236 239
26. Z.T. Xiong, J.J. Hu, G.T. Wu, P. Chen, W.F. Luo, and K. Gross Thermodynamic and kinetic investigations of the hydrogen storage in the Li-Mg-N-H system J Alloys Compd 398 2005 235 239
27. 4 on hydrogen storage properties of the Li-Mg-N-H system. http://dx.doi.org/10.1002/asia.201200938.
28. 2 Appl Phys A 83 2006 277 279
29. T. Ichikawa, and S. Isobe The structural properties of amides and imides as hydrogen storage materials Z Kristallogr 223 2008 660 665
30. 3 Chem Commun 2006 2439 2441
31. 4 crystals (M = Li, Na, K): a combined DFT, Infrared, and Raman study J Phys Chem C 115 2011 18890 18900
32. H.L. Chu, G.T. Wu, Y. Zhang, Z.T. Xiong, J.P. Guo, and T. He Improved dehydrogenation properties of calcium borohydride combined with alkaline-earth metal amides J Phys Chem C 115 2011 18035 18041
33. 2 with favorable dehydrogenation J Phys Chem C 114 2010 4733 4737
34. 2 system Chem Asian J 5 2010 1594 1599
35. 2-2LiH system with NaOH additive Int J Hydrogen Energy 36 2011 2137 2144
36. 2. http://dx.doi.org/10.1039/c2dt32266h.
37. 2 system Int J Hydrogen Energy 31 2006 1236 1240
38. Z.T. Xiong, G.T. Wu, J.J. Hu, P. Chen, W.F. Luo, and J. Wang Investigations on hydrogen storage over Li-Mg-N-H complex-the effect of compositional changes J Alloys Compd 417 2006 190 194
39. J.J. Hu, Y.F. Liu, G.T. Wu, Z.T. Xiong, and P. Chen Structural and compositional changes during hydrogenation/dehydrogenation of the Li-Mg-N-H system J Phys Chem C 111 2007 18439 18443
40. 2 system Dalton Trans 39 2010 9100 9107
41. H.E. Kissinger Reaction kinetics in differential thermal analysis Anal Chem 29 1957 1702 1706
42. 2- and LiH-containing systems for hydrogen storage applications Int J Hydrogen Energy 33 2008 3915 3924
43. 10 Inorg Chem 45 2006 1433 1435
44. M. Matsuo, and S. Orimo Lithium fast-ionic conduction in complex hydrides:review and prospects Adv Energy Mater 1 2011 161 172
45. 2 and hydrogen storage mechanisms in amide-hydride system J Am Chem Soc 130 2008 6515 6522
46. Y.F. Liu, K. Zhong, K. Luo, M.X. Gao, H.G. Pan, and Q.D. Wang Size-dependent kinetic enhancement in hydrogen absorption and desorption of the Li-Mg-N-H system J Am Chem Soc 31 2009 1862 1870
47. P.A. Anderson, P.A. Chater, D.R. Hewett, and P.R. Slater Hydrogen storage and ionic mobility in amide-halide systems Faraday Discuss 151 2011 271 284