Applicability of non-isothermal model-free predictions for assessment of conversion vs. time curves for complex processes in isothermal and quasi-isothermal conditions

Thermochimica Acta

Volumn 558, Issue , 2013, Pages 67-73

  Budrugeac, P ^a  

^a NATIONAL INSTITUTE FOR RESEARCH AND DEVELOPMENT IN MICROTECHNOLOGIES   (Romania)

Author keywords

Heterogeneous kinetics; Model based prediction; Model free prediction; Polymer degradation

Indexed keywords

HETEROGENEOUS KINETICS; HIGH DENSITY POLYETHYLENE(HDPE); MATERIALS AND PRODUCTS; MODEL FREE; MODEL-BASED PREDICTION; POLY (VINYL ALCOHOL) (PVA); POLYMER DEGRADATION; THERMO-OXIDATIVE DEGRADATION;

DEGRADATION; ERRORS; FORECASTING; SOFTWARE PACKAGES;

ISOTHERMS;

EID: 84875698642     PISSN: 00406031     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tca.2013.02.001     Document Type: Article

References (40)

1. D.J. Topp The use of thermogravimetric analysis as a rapid screening test for large number of electrical insulations IEEE Trans. Electr. Insul. EI-6 1971 2 14
2. D.J. Topp Contribution of differential thermal analysis to the estimation of thermal endurance of insulation IEEE Trans. Electr. Insul. EI-7 1971 25 32
3. J.H. Flynn Degradation kinetics applied to lifetime prediction of polymers S.W. Shalaby, Thermal Methods in Polymer Analysis 1977 The Franklin Inst Press Philadelphia 163-186
4. J.H. Flynn, and B. Dickens Application of new kinetics techniques to the lifetime prediction of polymers from weight-loss data. Durability of macromolecular materials R. Eby, ACS Symposium Series vol. 95 1979 97 115
5. J.H. Flynn The role of thermal analysis in the lifetime prediction of polymers D. Dollimore, Proceedings of Second European Symposium on Thermal Analysis 1981 Heyden London 223 226
6. J.H. Flynn Lifetime prediction for polymers from thermal analytical experiments-problems and how to deal with some of them Thermochim. Acta 134 1988 115 120
7. J.H. Flynn A critique of lifetime prediction of polymers by thermal analysis J. Therm. Anal. Calorim. 44 1995 499 512
8. P. Budrugeac, and E. Segal Thermal analysis in the evaluation of thermal lifetime of solid polymeric materials Thermochim. Acta 211 1992 131 136
9. G.C. Montanari, and Y. Zhang Notes on the thermogravimetric point slope procedure for thermal endurance characterization of insulating materials IEEE Trans. Dielectr. Electr. Insul. 1 1994 1026 1033
10. P. Budrugeac Thermal degradation of glass reinforced epoxy resin and polychloroprene rubber: the correlation of kinetic parameters of isothermal accelerated aging with those obtained from non-isothermal data Polym. Degrad. Stab. 74 2001 125 132
11. A.K. Burnham, and L.N. Dinh A comparison of isoconversional and model-fitting approaches to kinetic parameter estimation and application predictions J. Therm. Anal. Calorim. 89 2007 479 490
12. S. Vyazovkin, A.K. Burnham, J.M. Criado, L.A. Pérez-Maqueda, C. Popescu, and N. Sbirrazzuoli ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data Thermochim. Acta 520 2011 1 19
13. S. Vyazovkin A unified approach to kinetic processing of nonisothermal data Int. J. Chem. Kinet. 28 1996 95 101
14. B. Roduit, P. Folly, B. Berger, J. Mathieu, A. Sarbach, H. Andres, M. Ramin, and B. Vogelsanger Evaluating SADT by advanced kinetics-based simulation approach J. Therm. Anal. Calorim. 93 2008 153 161
15. ASTM E698-05 standard test method for Arrhenius kinetic constants for thermally unstable materials Annual Book of ASTM Standards vol. 14.02 2005 ASTM International West Conshohocken, PA p. 226
16. ASTM E1641-07 standard test method for decomposition kinetics by thermogravimetry Annual Book of ASTM Standards vol. 14.02 2007 ASTM International West Conshohocken, PA
17. ASTM E698-11: Standard Test Method for Arrhenius Kinetic Constants for Thermally Unstable Materials Using Differential Scanning Calorimetry and the Flynn/Wall/Ozawa Method. Annual Book of ASTM Standards, vol. 14.02, ASTM International, West Conshohocken, PA, 2011.
18. P. Budrugeac Kinetics of the complex process of thermo-oxidative degradation of poly(vinyl alcohol) J. Therm. Anal. Calorim. 92 2008 291 296
19. P. Budrugeac, and E. Segal Application of isoconversional and multivariate non-linear regression methods for evaluation of the degradation mechanism and kinetic parameters of an epoxy resin Polym. Degrad. Stab. 93 2008 1073 1080
20. P. Budrugeac Theory and practice in the thermoanalytical kinetics of complex processes: application for the isothermal and non-isothermal thermal degradation of HDPE Thermochim. Acta 500 2010 30 37
21. S. Vyazovkin, I. Dranca, X. Fan, and R. Advincula Kinetics of the thermal and thermo-oxidative degradation of a polystyrene-clay nanocomposite Macromol. Rapid Commun. 25 2004 498 503
22. N. Sbirrazzuoli, L. Vincent, A. Mija, and N. Guigo Integral, differential and advanced isoconversional methods, complex mechanisms and isothermal predicted conversion-time curves Chemometr. Intell. Lab. 96 2009 219 226
23. J. Farjas, and P. Roura Isoconversional analysis of solid-state transformations. A critical review. Part III. Isothermal and non isothermal predictions J. Therm. Anal. Calorim. 109 2012 183 191
24. H.L. Anderson, A. Kemmler, and R. Strey Comparison of different non-linear evaluation methods in thermal analysis Thermochim. Acta 271 1996 23 29
25. J. Opfermann Kinetic analysis using multivariate non-linear regression. I. Basic concepts J. Therm. Anal. Calorim. 60 2000 641 658
26. A.K. Burnham, and R.L. Braun Global kinetic analysis of complex materials Energy & Fuels 13 1999 1 22
27. B. Roduit Computational aspects of kinetic analysis. Part E: the ICTAC kinetic project-numerical techniques and kinetics of solid state processes Thermochim. Acta 355 2000 171 180
28. B. Roduit, Ch. Borgeat, B. Berger, P. Folly, B. Alonso, J.N. Aebischer, and F. Stoessel Advanced kinetics tools for the evaluation of decomposition reactions: determination of thermal stability of energetic materials J. Therm. Anal. Calorim. 80 2005 229 236
29. S. Vyazovkin, and W. Linert False isokinetic relationships found in the nonisothermal decomposition of solids Chem. Phys. 193 1995 109 118
30. See for example T. Hatakeyama, and F.X. Quin Thermal Analysis. Fundamentals and Applications to Polymer Science 1999 John Wiley & Sons Chichister/New York/Weinheim/Brisbane/Toronto/Singapore (Chapter 5.3)
31. H.L. Friedman Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenolic plastic J. Polym. Sci. Part C6 1964 183 195
32. J. Farjas, and P. Roura Isoconversional analysis of solid state transformations. A critical review. Part II. Complex transformations J. Therm. Anal. Calorim. 105 2011 767 773
33. P. Budrugeac, D. Homentcovschi, and E. Segal Critical considerations on the isoconversional methods for evaluating the activation energy. III, On the evaluation of the activation energy from non-isothermal data J. Therm. Anal. Calorim. 66 2001 557 565
34. S. Vyazovkin Modification of the integral isoconversional method to account for variation in the activation energy J. Comput. Chem. 22 2001 178 183
35. T. Wanjun, and C. Donghua An integral method to determine variation in activation energy with extent of conversion Thermochim. Acta 433 2005 72 76
36. P. Budrugeac An iterative model-free method to determine the activation energy of non-isothermal heterogeneous processes Thermochim. Acta 511 2010 8 16
37. P. Budrugeac An iterative model-free method to determine the activation energy of heterogeneous processes under arbitrary temperature programs Thermochim. Acta 523 2011 84 89
38. G.I. Senum, and R.T. Yang Rational approximations of the integral of the Arrhenius function J. Therm. Anal. 11 1977 445 447
39. S. Vyazovkin, and C.A. Wight Isothermal and nonisothermal reaction kinetics in solids: in search of ways toward consensus J. Phys. Chem. A 101 1997 8279 8284
40. J.M. Criado, P.E. Sánchez-Jiménez, and L.A. Pérez-Maqueda Critical study of the isoconversional methods of kinetic analysis J. Therm. Anal. Calorim. 92 2008 199 203