The molybdenum isotopic composition of the modern ocean

Geochemical Journal

Volumn 46, Issue 2, 2012, Pages 131-141

  Nakagawa, Yusuke ^a   Takano, Shotaro ^a   Firdaus, M Lutfi ^b   Norisuye, Kazuhiro ^a   Hirata, Takafumi ^a   Vance, Derek ^c   Sohrin, Yoshiki ^a  

^a KYOTO UNIVERSITY   (Japan)

^b UNIVERSITY OF BENGKULU   (Indonesia)

^c UNIVERSITY OF BRISTOL   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84875633418     PISSN: 00167002     EISSN: None     Source Type: Journal    
DOI: 10.2343/geochemj.1.0158     Document Type: Article

References (51)

1. Anbar, A. D., Knab, K. A. and Barling, J. (2001) Precise determination of mass-dependent variations in the isotopic composition of molybdenum using MC-ICPMS. Anal. Chem. 73, 1425-1431.
2. Archer, C. and Vance, D. (2008) The isotopic signature of the global riverine molybdenum flux and anoxia in the ancient oceans. Nature Geosci. 1, 597-600.
3. Arnold, G. L., Anbar, A. D., Barling, J. and Lyons, T. W. (2004) Molybdenum isotope evidence for widespread anoxia in mid-Proterozoic oceans. Science 304, 87-90.
4. Barling, J. and Anbar, A. D. (2004) Molybdenum isotope fractionation during adsorption by manganese oxides. Earth Planet. Sci. Lett. 217, 315-329.
5. Barling, J., Arnold, G. L. and Anbar, A. D. (2001) Natural mass-dependent variations in the isotopic composition of molybdenum. Earth Planet. Sci. Lett. 193, 447-457.
6. Bertine, K. K. (1972) The deposition of molybdenum in anoxic waters. Mar. Chem. 1, 43-53.
7. Collier, R. W. (1985) Molybdenum in the Northeast Pacific Ocean. Limnol. Oceanogr. 30, 1351-1354.
8. de Laeter, J. R., Böhlke, J. K., de Bièvre, P., Hidaka, H., Peiser, H. S., Rosman, K. J. R. and Taylor, P. D. P. (2003) Atomic weights of the elements: Review 2000. Pure Appl. Chem. 75, 683-799.
9. Dellwig, O., Beck, M., Lemke, A., Lunau, M., Kolditz, K., Schnetger, B. and Brumsack, H. J. (2007) Non-conservative behaviour of molybdenum in coastal waters: Coupling geochemical, biological, and sedimentological processes. Geochim. Cosmochim. Acta 71, 2745-2761.
10. Duan, Y., Anbar, A. D., Arnold, G. L., Lyons, T. W., Gordon, G. W. and Kendall, B. (2010) Molybdenum isotope evidence for mild environmental oxygenation before the Great Oxidation Event. Geochim. Cosmochim. Acta 74, 6655-6668.
11. Emery, W. J. (2001) Water types and water masses. Encyclopedia of Ocean Sciences, 6 (Steele, J. H., Thorpe, S. A. and Turekian, K. K., eds.), 3179-3187, Academic Press, San Diego.
12. Firdaus, M. L., Norisuye, K., Nakagawa, Y., Nakatsuka, S. and Sohrin, Y. (2008) Dissolved and labile particulate Zr, Hf, Nb, Ta, Mo and W in the western North Pacific Ocean. J. Oceanogr. 64, 247-257.
13. Goldberg, T., Archer, C., Vance, D. and Poulton, S. W. (2009) Mo isotope fractionation during adsorption to Fe (oxyhydr)oxides. Geochim. Cosmochim. Acta 73, 6502-6516.
14. Hannah, J. L., Stein, H. J., Wieser, M. E., de Laeter, J. R. and Varner, M. D. (2007) Molybdenum isotope variations in molybdenite: Vapor transport and Rayleigh fractionation of Mo. Geology 35, 703-706.
15. Head, P. C. and Burton, J. D. (1970) Molybdenum in some ocean and estuarine waters. J. Mar. Biol. Ass. U. K. 50, 439-448.
16. Helz, G. R., Miller, C. V., Charnock, J. M., Mosselmans, J. F. W., Pattrick, R. A. D., Garner, C. D. and Vaughan, D. J. (1996) Mechanism of molybdenum removal from the sea and its concentration in black shales: EXAFS evidence. Geochim. Cosmochim. Acta 60, 3631-3642.
17. Helz, G. R., Bura-Nakic, E., Mikac, N. and Ciglenecki, I. (2011) New model for molybdenum behavior in euxinic waters. Chem. Geol. 284, 323-332.
18. Kendall, B., Gordon, G. W., Poulton, S. W. and Anbar, A. D. (2011) Molybdenum isotope constraints on the extent of late Paleoproterozoic ocean euxinia. Earth Planet. Sci. Lett. 307, 450-460.
19. Liermann, L. J., Mathur, R., Wasylenki, L. E., Nuester, J., Anbar, A. D. and Brantley, S. L. (2011) Extent and isotopic composition of Fe and Mo release from two Pennsylvania shales in the presence of organic ligands and bacteria. Chem. Geol. 281, 167-180.
20. McManus, J., Nägler, T. F., Siebert, C., Wheat, C. G. and Hammond, D. E. (2002) Oceanic molybdenum isotope fractionation: Diagenesis and hydrothermal ridge-flank alteration. Geochem. Geophys. Geosyst. 3, 1078.
21. Nägler, T. F., Siebert, C., Lüschen, H. and Böttcher, M. E. (2005) Sedimentary Mo isotope record across the Holocene fresh-brackish water transition of the Black Sea. Chem. Geol. 219, 283-295.
22. Nakagawa, Y., Firdaus, M. L., Norisuye, K., Sohrin, Y., Irisawa, K. and Hirata, T. (2008) Precise isotopic analysis of Mo in seawater using multiple collector-inductively coupled mass spectrometry coupled with a chelating resin column preconcentration method. Anal. Chem. 80, 9213-9219.
23. Neubert, N., Nägler, T. F. and Böttcher, M. E. (2008) Sulfidity controls molybdenum isotope fractionation into euxinic sediments: Evidence from the modern Black Sea. Geology 36, 775-778.
24. Neubert, N., Heri, A. R., Voegelin, A. R., Nägler, T. F., Schlunegger, F. and Villa, I. M. (2011) The molybdenum isotopic composition in river water: Constraints from small catchments. Earth Planet. Sci. Lett. 304, 180-190.
25. Pearce, C. R., Cohen, A. S. and Parkinson, I. J. (2009) Quantitative separation of molybdenum and rhenium from geological materials for isotopic determination by MC-ICP-MS. Geostand. Geoanal. Res. 33, 219-229.
26. Pearce, C. R., Burton, K. W., von Strandmann, P. A. E. P., James, R. H. and Gíslason, S. R. (2010a) Molybdenum isotope behaviour accompanying weathering and riverine transport in a basaltic terrain. Earth Planet. Sci. Lett. 295, 104-114.
27. Pearce, C. R., Coe, A. L. and Cohen, A. S. (2010b) Seawater redox variations during the deposition of the Kimmeridge Clay Formation, United Kingdom (Upper Jurassic): Evidence from molybdenum isotopes and trace metal ratios. Paleoceanography 25, PA4213.
28. Pietruszka, A. J., Walker, R. J. and Candela, P. A. (2006) Determination of mass-dependent molybdenum isotopic variations by MC-ICP-MS: An evaluation of matrix effects. Chem. Geol. 225, 121-136.
29. Poulson, R. L., Siebert, C., McManus, J. and Berelson, W. M. (2006) Authigenic molybdenum isotope signatures in marine sediments. Geology 34, 617-620.
30. Poulson Brucker, R. L., McManus, J., Severmann, S. and Berelson, W. M. (2009) Molybdenum behavior during early diagenesis: Insights from Mo isotopes. Geochem. Geophys. Geosyst. 10, Q06010.
31. Rahaman, W., Singh, S. K. and Raghav, S. (2010) Dissolved Mo and U in rivers and estuaries of India: Implication to geochemistry of redox sensitive elements and their marine budgets. Chem. Geol. 278, 160-172.
32. Scheiderich, K., Helz, G. R. and Walker, R. J. (2010) Century-long record of Mo isotopic composition in sediments of a seasonally anoxic estuary (Chesapeake Bay). Earth Planet. Sci. Lett. 289, 189-197.
33. Siebert, C., Nägler, T. F. and Kramers, J. D. (2001) Determination of molybdenum isotope fractionation by double-spike multicollector inductively coupled plasma mass spectrometry. Geochem. Geophys. Geosyst. 2, 2000GC000124.
34. Siebert, C., Nägler, T. F., von Blanckenburg, F. and Kramers, J. D. (2003) Molybdenum isotope records as a potential new proxy for paleoceanography. Earth Planet. Sci. Lett. 211, 159-171.
35. Siebert, C., Kramers, J. D., Meisel, T., Morel, P. and Nägler, T. F. (2005) PGE, Re-Os, and Mo isotope systematics in Archean and early Proterozoic sedimentary systems as proxies for redox conditions of the early Earth. Geochim. Cosmochim. Acta 69, 1787-1801.
36. Siebert, C., McManus, J., Bice, A., Poulson, R. and Berelson, W. M. (2006) Molybdenum isotope signatures in continental margin marine sediments. Earth Planet. Sci. Lett. 241, 723-733.
37. Sohrin, Y. and Bruland, K. W. (2011) Global status of trace elements in the ocean. Trends Anal. Chem. 30, 1291-1307.
38. Sohrin, Y., Isshiki, K., Kuwamoto, T. and Nakayama, E. (1987) Tungsten in north Pacific waters. Mar. Chem. 22, 95-103.
39. Sohrin, Y., Matsui, M. and Nakayama, E. (1999) Contrasting behavior of tungsten and molybdenum in the Okinawa Trough, the East China Sea and the Yellow Sea. Geochim. Cosmochim. Acta 63, 3457-3466.
40. Tuit, C. and Ravizza, G. (2003) The marine distribution of molybdenum. Geochim. Cosmochim. Acta 67, A495.
41. Voegelin, A. R., Nägler, T. F., Samankassou, E. and Villa, I. M. (2009) Molybdenum isotopic composition of modern and Carboniferous carbonates. Chem. Geol. 265, 488-498.
42. Voegelin, A. R., Nägler, T. F., Beukes, N. J. and Lacassie, J. P. (2010) Molybdenum isotopes in late Archean carbonate rocks: Implications for early Earth oxygenation. Precam. Res. 182, 70-82.
43. Vorlicek, T. P. and Helz, G. R. (2002) Catalysis by mineral surfaces: Implications for Mo geochemistry in anoxic environments. Geochim. Cosmochim. Acta 66, 3679-3692.
44. Wang, D., Aller, R. C. and Sañudo-Wilhelmy, S. A. (2011) Redox speciation and early diagenetic behavior of dissolved molybdenum in sulfidic muds. Mar. Chem. 125, 101-107.
45. Wasylenki, L. E., Rolfe, B. A., Weeks, C. L., Spiro, T. G. and Anbar, A. D. (2008) Experimental investigation of the effects of temperature and ionic strength on Mo isotope fractionation during adsorption to manganese oxides. Geochim. Cosmochim. Acta 72, 5997-6005.
46. Wen, H., Carignan, J., Zhang, Y., Fan, H., Cloquet, C. and Liu, S. (2011) Molybdenum isotopic records across the Precambrian-Cambrian boundary. Geology 39, 775-778.
47. Wen, H. J., Zhang, Y. X., Fan, H. F. and Hu, R. Z. (2010) Mo isotopes in the Lower Cambrian formation of southern China and its implications on paleo-ocean environment. Chinese Sci. Bull. 54, 4756-4762.
48. Wille, M., Kramers, J. D., Nägler, T. F., Beukes, N. J., Schröder, S., Meisel, T., Lacassie, J. P. and Voegelin, A. R. (2007) Evidence for a gradual rise of oxygen between 2.6 and 2.5 Ga from Mo isotopes and Re-PGE signatures in shales. Geochim. Cosmochim. Acta 71, 2417-2435.
49. Young, E. D., Galy, A. and Nagahara, H. (2002) Kinetic and equilibrium mass-dependent isotope fractionation laws in nature and their geochemical and cosmochemical significance. Geochim. Cosmochim. Acta 66, 1095-1104.
50. 2 fixation. Geobiology 9, 94-106.
51. Zheng, Y., Anderson, R. F., Van Geen, A. and Kuwabara, J. (2000) Authigenic molybdenum formation in marine sediments: A link to pore water sulfide in the Santa Barbara Basin. Geochim. Cosmochim. Acta 64, 4165-4178.