Hydrogenation of styrene oxide to 2-phenyl ethanol over polyurea microencapsulated mono- and bimetallic nanocatalysts: Activity, selectivity, and kinetic modeling

Industrial and Engineering Chemistry Research

Volumn 52, Issue 11, 2013, Pages 4027-4039

  Yadav, Ganapati D ^a   Lawate, Yuvraj S ^a  

^a INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

BI-FUNCTIONAL; BIMETALLIC NANOCATALYSTS; EXPERIMENTAL DATUM; KINETIC MODELING; LANGMUIR-HINSHELWOOD-HOUGEN-WATSON; MECHANISTIC MODELS; NANOCATALYSTS; STYRENE OXIDE;

CATALYST SELECTIVITY; ETHANOL; HYDROGENATION; ORGANIC SOLVENTS; REACTION KINETICS; STYRENE;

PALLADIUM;

EID: 84875419454     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie302587j     Document Type: Article

References (25)

1. Theimer, E. T. Fragrance Chemistry; Academic Press: New York, 1982; p. 271.
2. Bauer, K.; Garbe, D.; Surburg, H. Common Fragrance and Flavor Materials; VCH Publishers: New York, 1990.
3. Mookherjee, B. D.; Wilson, R. A. Essential Oils. Kirk-Othmer Encyclopedia of Chemical Technology, 4 th ed., John Wiley and Sons: New York, 1996; Vol. 17, pp 644-645.
4. Rode, C. V.; Telkar, M. M.; Jaganathan, R.; Chaudhari, R. V. Reaction kinetics of the selective liquid phase hydrogenation of styrene oxide to β-phenethyl alcohol J. Mol. Catal. A: Chem. 2003, 200, 279-290
5. Rode, C. V.; Hiyoshi, N.; Mine, E.; Shirai, M. Activity and selectivity behavior of 1,2-epoxyethylbenzene hydrogenation in carbon dioxide solvent Ind. Eng. Chem. Res. 2009, 48, 9457-9460
6. Fujitsu, H.; Shirahama, S.; Matsumura, E.; Takeshita, K.; Mochida, D. Catalytic Hydrogenation of Styrene Oxide with Cationic Rhodium Complexes J. Org. Chem. 1981, 46, 2287-2290
7. Yadav, V. G.; Chandalia, S. B. Synthesis of phenethyl alcohol by catalytic hydrogenation of styrene oxide Org. Process Res. Dev. 1998, 2, 294
8. Kirm, I.; Medina, F.; Sueiras, J. E.; Salagre, P.; Cesteros, Y. Hydrogenation of styrene oxide in the presence of supported platinum catalysts to produce 2-phenylethqanol J. Mol. Catal. A: Chem. 2007, 261, 98-103
9. Kirm, I.; Medina, F.; RodrIguez, X.; Cesteros, Y.; Salagre, P.; Sueiras, J. E. Preparation of 2-phenylethanol by selective hydrogenation, J. Mol. Catal. A: Chem 2005, 239, 215-221
10. Zaccheria, F.; Psaro, R.; Ravasio, N.; Sordelli, L.; Santoro, F. Mono- and bifunctional catalysts for styrene oxide isomerization or hydrogenation Catal. Lett. 2011, 141, 587-591
11. Kumbhar, P. S.; Kharkar, M. R.; Yadav, G. D.; Rajadhyaksha, R. A. Geometric and electronic effects in silica supported bimetallic Ni-Cu and Ni-Fe catalysts for liquid phase hydrogenation of acetophenone and benzonitrile J. Chem. Soc., Chem. Commun. 1992, 584-586
12. Yadav, G. D.; Goel, P. K. Experimental and theoretical analysis of selective hydrogenation of p -nitroanisole to p -anisidine over Pd/C: Kinetics and catalyst deactivation Clean Tech. Environ. Policy 2002, 4, 227-234
13. Yadav, G. D.; Goel, P. K. Stereoselective hydrogenation of p-tert -butylphenol over supported rhodium catalyst J. Mol. Catal A: Chem. 2002, 184, 281-288
14. Yadav, G. D.; Kharkar, M. R. Liquid phase hydrogenation of unsaturated nitriles: Activities and selectivities of bimetallic nickel-copper and nickel-iron supported on silica Appl. Catal. A: Gen. 1995, 126, 115-123
15. Akiyama, R.; Kobayashi, S. Microencapsulated palladium catalysts. Allylic substitution and Suzuki coupling using a recoverable and reusable polymer-supported palladium catalyst Angew. Chem., Int. Ed. 2001, 40, 3469-3471
16. Akiyama, R.; Kobayashi, S. Microencapsulated and related catalysts for organic chemistry and organic synthesis Chem. Rev. 2009, 109, 594-642
17. Pears, D. A.; Smith, S. C. Polyurea-encapsulated palladium catalysts: The development and application of a new and versatile immobilized-homogeneous- catalyst technology Aldrich. Acta 2005, 38, 25-35
18. Hong, K.; Park, S. Polyurea microcapsules with different structures: Preparation and properties J. Appl. Polym. Sci. 2000, 78, 894-898
19. Shah, H. S. Synthesis and Applications of Novel Catalysts. M. Chem. Eng. Thesis, University of Mumbai, Mumbai, India, 2007.
20. Lawate, Y. S., Development of Atom Economical Green Processes, Master of Chemical Engineering Thesis, University of Mumbai, Mumbai, India, 2008.
21. Bosco, J. P.; Humbert, M. P.; Chen, J. G., Design of bimetallic catalysts: From model surfaces to supports. Design of Heterogeneous Catalysts: New Approaches Based on Synthesis, Characterization and Modeling; Ozkan, U. S., Ed.; Wiley-VCH: New York, 2009.
22. Yadav, S. K.; Khilar, K. C.; Suresh, A. K. Microencapsulation in Polyurea Shell: Kinetics and Film Structure, AIChE J. 1996, 42, 2616-2626
23. Yadav, G. D.; Lawate, Y. S. Selective hydrogenation of styrene oxide to 2-phenyl ethanol over polyurea supported Pd-Cu catalyst in supercritical carbon dioxide J. Supercrit. Fluids 2011, 59, 78-86
24. Fernandez GarcIa, M.; Anderson, J. A.; Haller, G. L. Small organic molecules on transition metal surfaces and Monte Carlo simulations of bimetallic surface alloys J. Phys. Chem. 1996, 100, 16247-16254
25. Nam, S.-E.; Seong, Y.-K.; Lee, J. W.; Lee, K.-H. Preparation of highly stable palladium alloy composite membranes for hydrogen separation Desalination 2009, 236, 51-55