Probing molecular interactions of ionic liquid in industrially important solvents by means of conductometric and spectroscopic approach

Thermochimica Acta

Volumn 559, Issue , 2013, Pages 46-51

  Roy, Mahendra Nath ^a   Dewan, Rajani ^a   Ekka, Deepak ^a   Banik, Ishani ^a  

^a UNIVERSITY OF NORTH BENGAL   (India)

Author keywords

Diffusion coefficient; Ion solvation; Ionic liquid; Ionic mobility; Limiting molar conductance; Stretching frequency

Indexed keywords

ION-DIPOLE INTERACTIONS; ION-SOLVATION; IONIC MOBILITY; LIMITING MOLAR CONDUCTANCES; LIMITING MOLAR CONDUCTIVITY; N ,N-DIMETHYLFORMAMIDE; QUALITATIVE AND QUANTITATIVE ANALYSIS; STRETCHING FREQUENCY;

ASSOCIATION REACTIONS; DIFFUSION; INFRARED IMAGING; IONIC LIQUIDS; IONS; MOLECULAR INTERACTIONS; MOLECULAR STRUCTURE; ORGANIC SOLVENTS;

SOLVENTS;

EID: 84875342446     PISSN: 00406031     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tca.2013.02.022     Document Type: Article

References (23)

1. R.R. Dogonadze, E. Kalman, A.A. Kornyshev, and J. Ulstrup The Chemical Physics of Solvation, Part B, Spectroscopy Solvation 1986 Elsevier Amsterdam
2. A. Sinha, G. Ghosh, and M.N. Roy Conductance and FTIR spectroscopic study of sodium tetraphenylborate in pure 1,3-dioxolane and isoamyl alcohol and their binary mixtures J. Phys. Chem. Liq. 48 2010 62 78
3. A. Sinha, A. Bhattacharjee, and M.N. Roy Ion-solvent interactions in acrylonitrile solutions of some tetraalkylammonium halides using FTIR spectroscopy J. Disp. Sci. Technol. 30 2009 1003 1007
4. D.D. Perrin, and W.L.F. Armarego Purification of Laboratory Chemicals third ed. 1988 Pergamon Press Oxford
5. B. Sinha, V.K. Dakua, and M.N. Roy Apparent molar volumes and viscosity B-coefficients of some amino acids in aqueous tetramethylammonium iodide solutions at 298.15 K J. Chem. Eng. Data 52 2007 1768 1772
6. J.A. Dean Lange's Handbook of Chemistry 11th ed. 1973 McGraw-Hill Book Company New York
7. A. Chatterjee, and B. Das Electrical conductances of tetrabutylammonium bromide, sodium tetraphenylborate, and sodium bromide in methanol (1) + Water (2) mixtures at (298.15, 308.15, and 318.15) K J. Chem. Eng. Data 5 1 2006 1352 1355
8. D. Ekka, and M.N. Roy Conductance, a contrivance to explore ion association and solvation behavior of an ionic liquid (tetrabutylphosphonium tetrafluoroborate) in acetonitrile, tetrahydrofuran, 1,3-dioxolane, and their binaries J. Phys. Chem. B 1 16 2012 11687 11694
9. A. Bhattacharya, and M.N. Roy Ion association and solvation behavior of tetraalkylammonium iodides in binary mixtures of dichloromethane + N,N-dimethylformamideprobed by a conductometric study Phys. Chem. Chem. Phys. 12 2010 14534 14542
10. J.E. Lind Jr., J.J. Zwolenik, and R.M. Fuoss Calibration of conductance cells at 25(with aqueous solutions of potassium chloride J. Am. Chem. Soc. 81 1959 1557 1559
11. R.M. Fuoss Conductance-concentration function for the paired ion model J. Phys. Chem. 82 1978 2427 2440
12. B. Per Ionic association and ion-solvent interactions the conductance of lithium bromide in acetone-water mixtures at 15-35 °C Acta Chem Scand. 31 A 1977 869 876
13. D.S. Gill, and M.S. Chauhan Preferential solvation of ions in mixed solvents Z. Phys. Chem. NF 140 1984 139 148
14. J. Barthel, M.B. Rogac, and R. Neueder Conductivity of sodium chloride in water + 1,4-dioxane mixtures at temperatures from 5 to 35 °C I. dilute solutions J. Solut. Chem. 28 1999 1071 1086
15. D. Das Gupta, S. Das, and D.K. Hazra Conductance studies of tetra-alkylammonium bromides in 2-methoxyethanol at 25 °C J. Chem. Soc. Faraday Trans. 1 84 1988 1057 1063
16. J.M. Chakraborty, and B. Das Electrical conductances and viscosities of tetrabutylammonium thiocyanate in acetonitrile in the temperature range 25-45 °C Z. Phys. Chem. 218 2004 219 230
17. R.M. Fuoss, and E. Hirsch Single ion conductances in non-aqueous solvents J. Am. Chem. Soc. 82 1960 1013 1017
18. A.K. Covington, and T. Dickinson Physical chemistry of organic solvent systems 1973 Plenum New York
19. R.A. Robinson, and R.H. Stokes Electrolyte Solutions 1959 Butterworth London Ch 6, p 130
20. R. Yandagni, and P. Kebarle P. solvation of negative ions by protic and aprotic solvents. Gas-phase solvation of halide ions by acetonitrile and water molecules J. Am. Chem. Soc. 94 1972 2940 2943
21. M. Pagliai Hydrogen bond dynamics in liquid methanol J. Chem. Phys. 119 2003 6655 6662
22. C. Desfrancois, V. Periquet, S. Carles, J.P. Schermann, and L. Adamowicz Neutral and negatively-charged formamide, N-methylformamide and dimethylformamide clusters Chem. Phys. 239 1998 475 483
23. O. Shun-Li, W. Nan-Nan, L. Jing-Yao, S. Cheng-Lin, L. Zuo-Wei, and G. Shu-Qin Investigation of hydrogen bonding in neat dimethyl sulfoxide and binary mixture (dimethyl sulfoxide + water) by concentration-dependent Raman study and ab initio calculation Chin. Phys. B. 19 2010 123101 123107