Stereoretentive chlorination of cyclic alcohols catalyzed by titanium(IV) tetrachloride: Evidence for a front side attack mechanism

Journal of Organic Chemistry

Volumn 78, Issue 5, 2013, Pages 2118-2127

  Mondal, Deboprosad ^a   Li, Song Ye ^a   Bellucci, Luca ^b   Laino, Teodoro ^c   Tafi, Andrea ^d   Guccione, Salvatore ^e   Lepore, Salvatore D ^a  

^a FLORIDA ATLANTIC UNIVERSITY   (United States)

^b CNR   (Italy)

^c IBM RESEARCH ZURICH   (Switzerland)

^d UNIVERSITY OF SIENA   (Italy)

^e UNIVERSITY OF CATANIA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINATION; CHLORINE COMPOUNDS; COMPUTATION THEORY; COMPUTATIONAL GEOMETRY; REACTION INTERMEDIATES;

CHLORINATION REACTIONS; COMPUTATIONAL APPROACH; CONFORMATIONAL ISOMERS; PYRAMIDAL GEOMETRIES; REACTION PATHWAYS; THIONYL CHLORIDES; TITANIUM CHLORIDE; TITANIUM TETRACHLORIDES;

TITANIUM COMPOUNDS;

ALCOHOL DERIVATIVE; CHELATE; CYCLIC ALCOHOL DERIVATIVE; HALOGEN; NUCLEOPHILE; TITANIUM TETRACHLORIDE; UNCLASSIFIED DRUG;

AB INITIO CALCULATION; AMIDATION; ARTICLE; BROMINATION; CATALYSIS; CHEMICAL REACTION; CHLORINATION; COMPLEX FORMATION; CONFORMATION; COVALENT BOND; NUCLEOPHILICITY; RACEMIC MIXTURE; REACTION ANALYSIS; STEREOCHEMISTRY; TRANS ISOMER;

EID: 84874627406     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo3023439     Document Type: Article

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