Role of poly(ethylene glycol) in surfactant-free emulsion polymerization of styrene and methyl methacrylate

Langmuir

Volumn 29, Issue 9, 2013, Pages 3024-3033

  Shan, Guorong ^a   Shi, Yiming ^a   Shang, Yue ^a  

^a ZHEJIANG UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS PHASE; AQUEOUS PHASIS; COPOLYMER PARTICLES; DRIVING FORCES; HIGH TEMPERATURE; METHYL METHACRYLATES; MONOMER PHASE; NANO SCALE; NUCLEATION AND GROWTH; SOLUBILITY CURVE; SURFACE TENSION MEASUREMENTS; SURFACTANT-FREE; SURFACTANT-FREE EMULSION POLYMERIZATION; TERNARY PHASE DIAGRAMS; TERNARY SOLUBILITY; VOLUME CONTRACTION;

ACRYLIC MONOMERS; COPOLYMERS; EMULSION POLYMERIZATION; ESTERS; MONOMERS; NANOTECHNOLOGY; POLYETHYLENE OXIDES; SOLUBILITY; STYRENE; SURFACE TENSION; ZETA POTENTIAL;

POLYETHYLENE GLYCOLS;

EID: 84874593700     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la304847a     Document Type: Article

References (39)

1. Tauer, K.; Deckwer, R.; Kühn, I.; Schellenberg, C. A Comprehensive Experimental Study of Surfactant-Free Emulsion Polymerization of Styrene Colloid Polym. Sci. 1999, 277, 607-626
2. Zhao, J.; Schaefer, D. W. Morphology of PEG-Stabilized Carbon Nanofibers in Water J. Phys. Chem. C 2008, 112, 15306-15310
3. Wu, M.; Dellacherie, E.; Durand, A.; Marie, E. Poly(n-butyl cyanoacrylate) Nanoparticles via Miniemulsion Polymerization. 2. PEG-Based Surfactants Colloids Surf., B 2009, 69, 147-151
4. Kiehlbauch, R. A.; Tsaur, S. L. Resin-Fortified Emulsion Polymers and Methods of Preparing the Same. U.S. Patent 4839413, 1989; 06-13.
5. Shi, Y. M.; Shan, G. R. Particle Size Evolution in Surfactant-Free Emulsion Copolymerization of Styrene and Methyl Methacrylate in Aqueous Solution of Poly(ethylene glycol) Acta Polym. Sin. 2012, 1, 19-24
6. Thickett, S. C.; Gilbert, R. G. Emulsion Polymerization: State of the Art in Kinetics and Mechanisms Polymer 2007, 48, 6965-6991
7. Smith, W. V.; Ewart, R. H. Kinetics for Emulsion Polymerization J. Chem. Phys. 1948, 16, 592-599
8. Priest, W. J. Particle Growth in the Aqueous Polymerization of Vinyl Acetate J. Phys. Chem. 1952, 56, 1077-1082
9. Fitch, R. M.; Tsai, C. H. In Polymer Colloids; Fitch, R. M., Ed.; Plenum: New York, 1971; pp 73-103.
10. Goodall, A. R.; Wilkinson, M. C.; Hearn, J. Mechanism of Emulsion Polymerization of Styrene in Soap-Free Systems J. Polym. Sci., Part A: Polym. Chem. 1977, 15, 2193-2218
11. Feeney, P. J.; Napper, D. H.; Gilbert, R. G. Coagulative Nucleation and Particle-Size Distributions in Emulsion Polymerization Macromolecules 1984, 17, 2520-2529
12. Feeney, P. J.; Napper, D. H.; Gilbert, R. G. Surfactant-Free Emulsion Polymerizations-Predictions of the Coagulative Nucleation Theory Macromolecules 1987, 20, 2922-2930
13. Barouch, E.; Matijevic, E. Double-Layer Interactions of Unequal Spheres. 1. The Effect of Electrostatic Attraction with Particles of Like Sign of Potential J. Chem. Soc., Faraday Trans. 1 1985, 81, 1797-1817
14. Barouch, E.; Matijevic, E.; Wright, T. H. Double-Layer Interactions of Unequal Spheres. 2. Numerical-Analysis of Electrostatic Interaction Energy J. Chem. Soc., Faraday Trans. 1 1985, 81, 1819-1832
15. Harris, J. M. Poly(Ethylene Glycol) Chemistry; Plenum: New York and London, 1992; pp 1-12.
16. Bailey, F. E.; Koleske, J. V. Alkylene Oxide and Their Copolymers; Marcel Dekker: New York, 1991.
17. Bailey, F. E.; Koleske, J. V. Poly(Ethylene Oxide); Academic: New York, 1976.
18. Inada, Y.; Takahashi, K.; Yoshimoto, T.; Ajima, A.; Matsushima, A.; Saito, Y. Application of Polyethylene Glycol-Modified Enzymes in Biotechnological Processes-Organic Solvent-Soluble Enzymes Trends Biotechnol. 1986, 4, 190-194
19. Saeki, S.; Kuwahara, N.; Nakata, M.; Kaneko, M. Upper and Lower Critical Solution Temperatures in Poly(ethyleneglycol) Solutions Polymer 1976, 17, 685-689
20. Sjöberg, Å.; Karlström, G. Temperature-Dependence of the Phase-Equilibria for the System Poly(Ethylene Glycol) Dextran Water-A Theoretical and Experimental-Study Macromolecules 1989, 22, 1325-1330
21. Andersson, M.; Karlström, G. Conformational Structure of 1,2-Dimethoxyethane in Water and Other Dipolar Solvents, Studied by Quantum Chemical, Reaction Field, and Statistical Mechanical Techniques J. Phys. Chem. 1985, 89, 4957-4962
22. Nagaoka, S.; Mori, Y.; Takiuchi, H.; Yokota, K.; Tanzawa, H.; Nishiumi, S. Polymers as Biomaterials; Plenum Press: New York, 1985.
23. Torza, S.; Mason, S. G. 3-Phase Interactions in Shear and Electrical Fields J. Colloid Interface Sci. 1970, 33, 67-83
24. Sundberg, D. C.; Casassa, A. P.; Pantazopoulos, J.; Muscato, M. R.; Kronberg, B.; Berg, J. Morphology Development of Polymeric Microparticles in Aqueous Dispersions. 1. Thermodynamic Considerations J. Appl. Polym. Sci. 1990, 41, 1425-1442
25. Chen, Y. C.; Dimonie, V.; El-Aasser, M. S. Interfacial Phenomena Controlling Particle Morphology of Composite Latexes J. Appl. Polym. Sci. 1991, 42, 1049-1063
26. González-Ortiz, L. J.; Asua, J. M. Development of Particle Morphology in Emulsion Polymerization. 1. Cluster Dynamics Macromolecules 1995, 28, 3135-3145
27. González-Ortiz, L. J.; Asua, J. M. Development of Particle Morphology in Emulsion Polymerization. 2. Cluster Dynamics in Reacting Systems Macromolecules 1996, 29, 383-389
28. González-Ortiz, L. J.; Asua, J. M. Development of Particle Morphology in Emulsion Polymerization. 3. Cluster Nucleation and Dynamics in Polymerizing Systems Macromolecules 1996, 29, 4520-4527
29. Myers, D. Surfaces, Interfaces, and Colloids: Principles and Applications; VCH Publishers: New York, 1991.
30. Vincent, B.; Edwards, J.; Emmett, S.; Jones, A. Depletion Flocculation in Dispersions of Sterically-Stabilized Particles (Soft Spheres) Colloids Surf. 1986, 18, 261-281
31. Ortega-Vinuesa, J. L.; Martín-Rodríguez, A.; Hidalgo-álvarez, R. Colloidal Stability of Polymer Colloids with Different Interfacial Properties: Mechanisms J. Colloid Interface Sci. 1996, 184, 259-267
32. Walstra, P. Principles of Emulsion Formation Chem. Eng. Sci. 1993, 48, 333-349
33. Williams, A.; Janssen, J. J. M.; Prins, A. Behaviour of Droplets in Simple Shear Flow in the Presence of a Protein Emulsifier Colloids Surf., A 1997, 125, 189-200
34. Bazhekov, I. B.; Anderson, P. D.; Meijer, H. E. H. Numerical Investigation of the Effect of Insoluble Surfactants on Drop Deformation and Breakup in Simple Shear Flow J. Colloid Interface Sci. 2006, 298, 369-394
35. Windhab, E. J.; Dressler, M.; Feigl, K.; Fischer, P.; Megias-Alguacil, D. Emulsion Processing-From Single-Drop Deformation to Design of Complex Processes and Products Chem. Eng. Sci. 2005, 60, 2101-2113
36. Fischer, P.; Erni, P. Emulsion Drops in External Flow Fields-The Role of Liquid Interfaces Curr. Opin. Colloid Interface Sci. 2007, 12, 196-205
37. Feigl, K.; Kaufmann, S. F. M.; Fischer, P.; Windhab, E. J. A Numerical Procedure for Calculating Droplet Deformation in Dispersing Flows and Experimental Verification Chem. Eng. Sci. 2003, 58, 2351-2363
38. Stone, H. A. Dynamics of Drop Deformation and Breakup in Viscous Fluids Annu. Rev. Fluid Mech. 1994, 26, 65-102
39. Bentley, B. J.; Leal, L. G. An Experimental Investigation of Drop Deformation and Breakup in Steady, Two-Dimensional Linear Flows J. Fluid Mech. 1986, 167, 241-283